• 제목/요약/키워드: diamond

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초경합금기판 위에 성장되는 다이아몬드 막의 특성 (Characteristics of Diamond Films Deposited on Cemented Tungsten Carbide Substrate)

  • 김봉준;박상현;박재윤
    • 대한전기학회논문지:전기물성ㆍ응용부문C
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    • 제53권7호
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    • pp.387-394
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    • 2004
  • Diamond films were deposited on the cemented tungsten carbide WC-Co cutting insert substrates by using both microwave plasma chemical vapor deposition(MWPCVD) and radio frequency plasma chemical vapor deposition (RFPCVD) from $CH_4$$-H_2$$-O_2$ gas mixture. Scanning electron microscopy and X-ray diffraction techniques were used to investigate the microstructure and phase analysis of the materials and Raman spectrometry was used to characterize the quality of the diamond coating. Diamond films deposited using MWPCVD from $CH_4$$-H_2$$-O_2$ gas mixture show a dense, uniform, well faceted and polycrystalline morphology. The compressive stress in the diamond film was estimated to be (1.0∼3.6)$\pm$0.9 GPa. Diamond films which were deposited on the WC-Co cutting insert substrates by RFPCVD from $CH_4$$-H_2$$-O_2$ gas mixture show relatively good adhesion, very uniform, dense and polycrystalline morphology.

붕소가 도핑된 다이아몬드전극을 이용한 오존발생기의 전기화학적 특성 (Eletrochemical Characteristics of Ozone Generator using Boron-doped Diamond Electrode)

  • 오원균;김규식;;;박수길
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2001년도 추계학술대회 논문집
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    • pp.585-588
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    • 2001
  • Thin, Boron-doped conducting diamond films are expected to be excellent electrodes for industrial electrolysis. Boron-doped conducting diamond films were used as anode for generating ozone gas by electrolysis of acidic solution. In this work, we have studied ozone generating system using Boron-doped Diamond electrode. Electrochemical cell and ozone generating system were designed for decreasing the temperature of the system, which was elevated during the reaction. by circulation of electrolyte in the system. In order to determine the ozone generation properties of diamond electrode, experimental conditions, electrolyte concentration, temperature, flow rate and reaction time were varied diversely. As a result, we could confirm that ozone gas was generated successfully and the performance of diamond electrode was stable while PbO$_2$ electrode was disintegrated. Actually we are found that ozone amount increased by lowering the temperature of electrolyte.

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PHOTOELECTRODEPOSITION OF COPPER ON BORON-DOPED DIAMOND FILMS: ITS APPLICATION TO CONDUCTIVE PATTERN FORMING ON DIAMOND AND DIAMOND PHOTOGRAPHIC PHENOMENON

  • Yoshihara, S.;Shinozaki, K.;Shirakashi, T.
    • 한국표면공학회지
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    • 제32권3호
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    • pp.244-248
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    • 1999
  • Photoelectrodeposition of copper on semiconductive B-doped diamond films was investigated. There are cleasr morphology differences between photodeposited copper and electrodeposited copper. Photoelecrodeposition proceeded as uniform 2-dimensional growth. On the other hand electrodeposition proceeded as scarce random deposition. By applying this effect we have succeeded in forming a conductive pattern on semiconductive B-doped diamond with the aid of a photo-mask. And it was suggested that the surface reforming caused by photoelectrochemical process could be easily detected by the following metal (copper) deosition method, which is demonstrated as 'Diamond photographic phenomenon'.

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가속기 백색광 X-Ray Topography를 이용한 CVD 단결정 다이아몬드 내부 전위 분석 (Dislocation Analysis of CVD Single Crystal Diamond Using Synchrotron White Beam X-Ray Topography)

  • 유영재;정성민;배시영
    • 한국전기전자재료학회논문지
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    • 제32권3호
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    • pp.192-195
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    • 2019
  • Single-crystal diamond obtained by chemical vapor deposition (CVD) exhibits great potential for use in next-generation power devices. Low defect density is required for the use of such power devices in high-power operations; however, plastic deformation and lattice strain increase the dislocation density during diamond growth by CVD. Therefore, characterization of the dislocations in CVD diamond is essential to ensure the growth of high-quality diamond. In this work, we analyze the characteristics of the dislocations in CVD diamond through synchrotron white beam X-ray topography. In estimate, many threading edge dislocations and five mixed dislocations were identified over the whole surface.

Chemical Vapour Deposited Diamond for Thermal and Optical Applications

  • Koidi, P.;Wild, C.;Woerner, E.;Muller-Sebert, M.;Funer, M.;Jehle, M.
    • The Korean Journal of Ceramics
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    • 제2권4호
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    • pp.177-180
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    • 1996
  • Considerable progress in the development of CVD techniques for the deposition of diamond films has been achieved recently. Despite the polycrystalline structure of this material, its physical properties are now approaching those of natural type IIa diamond crystals. This paper will given some insight into the current status of CVD diamond thechnology with emphasis on optical and thermal applications. The role of process gas impurities like nitrogen will be discussed.

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CVD 다이아몬드 코팅의 고체입자 Erosion 특성 (Solid Particle Erosion of CVD Diamond)

  • 김종훈;임대순
    • 한국윤활학회:학술대회논문집
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    • 한국윤활학회 1997년도 제25회 춘계학술대회
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    • pp.69-73
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    • 1997
  • Microwave Plasma assisted CVD (Chemical Vapor Deposition) and DC Plasma CVD were used to prepare thin and thick diamond film, respectively. Diamond coated silicon nitride and fiee standing diamond thick film were eroded by silicon carbide particles. The velocity of the solid particle was about 220m/sec. Phase transformation and the other crack formation were investigated by using Raman spectroscopy and microscopy.

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LINEAR EXTENSIONS OF DIAMOND POSETS

  • Ju, Hyeong-Kwan;Seo, Seunghyun
    • 호남수학학술지
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    • 제41권4호
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    • pp.863-870
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    • 2019
  • In this paper, we obtain the enumeration results on the number of linear extensions of diamond posets. We find the recurrence relations and exponential generating functions for the number of linear extensions of diamond posets. We also get some results for the volume of graph polytope associated with bipartite graphs which are underlying graphs of diamond posets.

인조보석 절단기술에 관한 연구 (A Study on the Cutting-off Technology for Synthetic Jewelry)

  • 서영일;최환;이종찬;이재건
    • 한국정밀공학회:학술대회논문집
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    • 한국정밀공학회 1995년도 춘계학술대회 논문집
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    • pp.23-27
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    • 1995
  • In sawing operation of synthetic jewelry, the performance of diamond cutter blade is very dependent on the blade variables. This investigation presents ecperimental results which show the effects of the blade variables such as types of diamond abrasives, grain size of diamond, concentration, and bond materials on the beavior of te blades. Based on the experimental results an optimum blade condition for the sawing of cubic zirconia was recommended.

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Tribological Properties of Sintered Diamonds with WC-Co Matrix

  • Umeda, Kazunori;Tanaka, Akihiro;Takatsu, Sokichi
    • The Korean Journal of Ceramics
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    • 제3권3호
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    • pp.169-172
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    • 1997
  • Sintered diamond/(WC-Co) composites were prepared by spark plasma sintering technique. Tribological properties were measured at temperatures from RT to $500^{\circ}C$ in sliding tests with alumina ball. They show coefficient of friction of 0.1 and below at RT and wear of the diamond composites is hardly detected. Effects of diamond grit size, diamond content and test temperature on the coefficient of friction and the wear are discussed. The wear scars were analyzed.

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