• Title/Summary/Keyword: derivatives$

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EFFECTS OF PHENOL DERIVATIVES ON BACTERIAL GROWTH (효소조중의 세균성장에 미치는 Phenol 유도분 영향 유도)

  • LEE Kyung-Hee;LEE Keun-Tai
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.11 no.4
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    • pp.213-217
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    • 1978
  • Henri-Michaelis-Menten model for predicting the behavior of culture of Brevibacterium flavum under carbon limiting condition has been evaluated on a chemostat growing in the presence of the phenol derivatives: guaiacol, o-vanillin and vanillin. It is found that Henri-Michaelis-Menten model could be applicable to the evaluation of the growth rate of cells in the phenol derivatives. The marked enhancing abilities of the cells treated by the phenol derivatives during fermentation were ascribed to the formation of charge-transfer complex between the phenol-derivatives and oxygen which supplies oxygen effectively to the fermentation system.

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Reactions of3-Aminopyazole Derivatives with Cyanothioacetamide and Its Derivatives:Synthesis and Reactions of Several New Pyrazole and Pyrazole[3,2-b]Pyrimidine Derivatives

  • Attaby, Fawzy-A.;Eldin, Sanaa-M.
    • Archives of Pharmacal Research
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    • v.20 no.4
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    • pp.330-337
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    • 1997
  • Thiocarboxamidocinnamonitrile derivatives 2 under bar a-f reacted with 3-aminopyrazole derivative 3 under bar a-c to give the pyrazole[3, 2-b]pyrimidine derivatives 6 under bar a-p. Compounds 6 under bar a-p were used as starting material for syntheses of several heterocylic coompounds. Dehydrogenation of 6 under bar gave pyrazole[3, 2-b]pyrimidines 10 under bar a-d while its reaction with diethyl oxalate gave 11 under bar. Reactions of 6 under bar with formic acid gave pyrazolopyrimidines 17 under bar a-j, and pyrazolopyrimidopyrimidines 18 under bar a-j.

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Determination of flutter derivatives by stochastic subspace identification technique

  • Qin, Xian-Rong;Gu, Ming
    • Wind and Structures
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    • v.7 no.3
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    • pp.173-186
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    • 2004
  • Flutter derivatives provide the basis of predicting the critical wind speed in flutter and buffeting analysis of long-span cable-supported bridges. In this paper, one popular stochastic system identification technique, covariance-driven Stochastic Subspace Identification(SSI in short), is firstly presented for estimation of the flutter derivatives of bridge decks from their random responses in turbulent flow. Secondly, wind tunnel tests of a streamlined thin plate model and a ${\Pi}$ type blunt bridge section model are conducted in turbulent flow and the flutter derivatives are determined by SSI. The flutter derivatives of the thin plate model identified by SSI are very comparable to those identified by the unifying least-square method and Theodorson's theoretical values. As to the ${\Pi}$ type section model, the effect of turbulence on aerodynamic damping seems to be somewhat notable, therefore perhaps the wind tunnel tests for flutter derivative estimation of those models with similar blunt sections should be conducted in turbulent flow.

Numerical Evaluation of 2nd Derivatives of the Potential in the Panel method for the Unsteady Potential Flow Problem (비정상 포텐셜 유동의 패널법 해석에서 포텐셜의 2차 미분값의 수치계산)

  • 양진호;전호환
    • Journal of Ocean Engineering and Technology
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    • v.14 no.3
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    • pp.41-45
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    • 2000
  • In solving the unsteady potential flow problem of the ship in waves with the panel method, in general one can consider the basic flow as the free stream or double body solution. For the double body solution, the body boundary condition has the 2nd derivatives of the velocity potential. Low order panel methods are known to suffer from the significant error in the 2nd derivatives computed at the body surface. This paper analyzes the numerical error in the 2nd derivatives for a 2-D cylinder and a 3-D sphere problem, and an extrapolation method to obtain the correct derivatives on the body surface is suggested.

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Perylene-based Pyrrolopyrone Derivatives as an n-Type Channel Materials

  • Kim, Hyung-Sun;Jung, Sung-Ouk;Kim, Yun-Hi;Kwon, Soon-Ki;Do, Lee-Mi;Yang, Yong-Suk;Lee, Jeong-Ik
    • 한국정보디스플레이학회:학술대회논문집
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    • 2003.07a
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    • pp.978-980
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    • 2003
  • Perylene tetracarboxylic anhydride derivatives have been well-known as an n-type channel material.$^1$ Here, we report perylene-based pyrrolopyrone derivatives as an n-type channel material. 1,8-naphthalene(l) and 1,2-phenylene(2)-based pyrrolopyrone derivatives were synthesized and characterized. Derivatives 1, 2 were soluble only protonic solvents with high acidity such as methane sulfonic acid and trifluoroacetic acid. Thin film transistors were fabricated by vacumn deposition and solution casting and electron mobility of the device were measured.

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Synthesis and Nonlinear Optical Properties of 1,3,5-Tricyano-2,4,6-tris[2-(thiophen-2-yl)vinyl]benzene Derivatives

  • Cho, Bong-Rae;Kim, Young-Hoon;Son, Kyung-Wha;Khalil, Chajara;Kim, Yong-Ho;Jeon, Seung-Joon
    • Bulletin of the Korean Chemical Society
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    • v.23 no.9
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    • pp.1253-1309
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    • 2002
  • 1,3,5-Tricyano-2,4,6-tris[2-(thiophen-2-yl)vinyl]benzene derivatives have been synthesized as a new type of octupolar nonlinear optical molecules and their linear and nonlinear optical properties were determined. The λmax values increa sed with the conjugation length and as the conjugation bridge was changed from phenyl to thienyl group. For phenyl and thiophene derivatives, the b value increased with conjugation length. In contrast, the $\beta$ values of the thiophene derivatives were much smaller than the corresponding phenyl derivatives.

Naphthazarin Derivatives (Ⅶ): Antitumor Action against ICR Mice Bearing Ascitic S-180 Cells

  • Song, Gyu-Yong;Kim, Yong;You, Young-Jae;Gho, Hoon;Ahn, Byung-Zun
    • Archives of Pharmacal Research
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    • v.24 no.1
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    • pp.35-38
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    • 2001
  • Various analogues of 5,8-dimethoxy-1,4-naphthoquinone (DMNQ) such as 2- or 6-(1-hydro-xyiminoalkyl)-DMNQs were prepared and evaluated for the antitumor action. (1-Hydroxyiminoalkyl)-DMNQ derivatives expressed greater antitumor action than (1 -hydroxyalkyl)- or acyl-DMNQ derivatives. Moreover, 6-(1-hydroxyiminoalkyl)-DMNQ derivatives expressed higher anti-tumor action than 2-sudstituted ones, suggestive of a steric effect. Some of 6-(1-propyloxyalkyl)-DMNQ derivatives with an alkyl group of butyl to octyl moiety showed T/C values of > 400 %.

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Correlations for Predicting Viscosity of Vegetable Oils and Its Derivatives for Compression Ignition Engines

  • No, Soo-Young
    • Journal of ILASS-Korea
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    • v.14 no.3
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    • pp.122-130
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    • 2009
  • Vegetable oil and its derivatives as an alternative diesel fuel have become more attractive recently because of its environmental benefits and the fact that they are made from renewable resources. Viscosity is the most significant property to affect the utilization of vegetable oil and its derivatives in the compression ignition engines. This paper presents the existing correlations for predicting the viscosity of vegetable oil and its derivatives for compression ignition engines. According to the parameter considered in the correlations, the empirical correlations can be divided into six groups: correlations as a function of temperature, of proportion, of composition, of temperature and composition, of temperature and proportion, and of fuel properties. Out of physical properties of fuel, there exist in the literature several parameters for giving the influence on kinematic viscosity such as density, specific gravity, the ratio of iodine value over the saponification value, higher heating value, flash point and pressure. The study for the verification of applicability of existing correlations to non-edible vegetable oil and its derivatives is required.

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Synthesis and Antioxidant Activities of 1, 2-bis(aminoacyl) hydrazine derivatives (1, 2-bis(aminoacyl)hydrazine 유도체들의 합성과 항산화 효과)

  • Kang, Shin-Won;Lee, Sang-Un;Shin, Hong-Dae
    • Journal of the Korean Applied Science and Technology
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    • v.3 no.1
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    • pp.43-47
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    • 1986
  • 1.2-bis(aminoacyl)hydrazine derivatives and dipeptides were synthesized by conventional peptide synthesis procedures. Their antioxidant activity were inverstigated by over-storage test using corn oil as substrte. 1.2-bis (aminoacyl) hydrazine derivatives and dipetides containing hydrophobic side chain amino acid showed higher antioxidant activity. A free N-terminal amino group was also found to be important for the appearance of antioxidant activity. 1.2-bis (aminoacyl) hydrazine derivatives showed higher antioxidant activity than dipeptides. Antimicrobial activites of dipeptides and 1.2-bis (aminoacyl) hydrazine derivatives were also examined by the paper disc method. All of these compounds had shown no antimicrobial activity.

A Study on Anti-Stress Activities of Cholic Acid Derivatives (담츱산류의 항스트레스 효능에 관한 연구)

  • 조태순;이종찬;조성익;이선미
    • Biomolecules & Therapeutics
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    • v.6 no.3
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    • pp.232-241
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    • 1998
  • This study was done to investigate whether cholic acid derivatives have anti-stress activity in various stress models. Two cholic acid derivatives, ursodeoxycholic acid (UDCA) and tauroursodeoxycholic acid (WDCA), were used. physical, psychological, chemical and environmental stress models were performed. Adrenal weight, serum glucose levels and ALP activity were elevated in restraint stress model, but this elevation was prevented by UDCA treatment. Moreover, UDCA and TUDCA inhibited exploratory and spontaneous movements in oscillation stress model. In alcohol-induced stress model, TUDCA improved rotarod performance. UDCA and TUDCA significantly reduced the involution of lymphoid organs and the increment of WBC counts in cold stress model. These findings suggest that choric acid derivatives have antistress effects in various stress models.

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