• Title/Summary/Keyword: deposition bed

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Decomposition of Formaldehyde Using TiO$_2$ Photocatalyst Beads by Circulating Fluidized Bed Chemical Vapor Deposition (CFB-CVD법으로 제조된 TiO$_2$ 광촉매 비드를 이용한 포름알데히드의 분해)

  • Kim, Kyoung-Hwan;Kim, Yu-Bong;Lee, Seung-Young;Park, Jae-Hyeon;Lim, Jin-Young;Jung, Sang-Chul
    • Journal of Korean Society of Environmental Engineers
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    • v.30 no.7
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    • pp.688-693
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    • 2008
  • TiO$_2$ photocatalyst films deposited beads were prepared by circulating fluidized bed chemical vapor deposition(CFB-CVD) using TTIP(Titanium Tetra Iso-Propoxyde). Photocatalytic activities of Photocatalyst beads were evaluated by decomposition rate of formaldehyde in aqueous solution using a photo-reactor. From the result of photocatalytic degradation of formaldehyde, decomposition rate were shown gradually increased according to the increase of UV intensity, circulating fluid velocity and addition amount of H$_2$O$_2$. However the decomposition rate of formaldehyde were decreased according to the increase of initial concentration and pH value.

Effect of Deposition Temperature on Microstructure and Hardness of ZrC Coating Layers of TRISO-Coated Particles Fabricated by the FBCVD Method (유동층 화학기상증착법으로 제조된 TRISO 피복입자의 ZrC 층 미세구조와 경도에 미치는 증착온도의 영향)

  • Ko, Myung-Jin;Kim, Daejong;Kim, Weon-Ju;Cho, Moon Sung;Yoon, Soon Gil;Park, Ji Yeon
    • Journal of the Korean Ceramic Society
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    • v.50 no.1
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    • pp.37-42
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    • 2013
  • Tristructural-isotropic (TRISO)-coated particles were fabricated by a fluidized-bed chemical vapor deposition (FBCVD) method for use in a very high temperature gas-cooled reactor (VHTR). ZrC as a constituent layer of TRISO coating layers was deposited by a chloride process using $ZrCl_4$ and $CH_4$ source gases in a temperature range of $1400^{\circ}C$ and $1550^{\circ}C$. The change in the microstructure of ZrC depending on the deposition temperature and its effect on the hardness were evaluated. As the deposition temperature increased to $1500^{\circ}C$, the grain size of the ZrC increased and the hardness of the ZrC decreased according to the Hall-Petch relationship. However, at $1550^{\circ}C$, the ZrC layer was highly non-stoichiometric and carbon-rich and did not obey the Hall-Petch relationship in spite of the decrease of the grain size. A considerable amount of pyrolytic carbon at the grain boundaries of the ZrC as well as coarse granular pyrolytic carbon were locally distributed in the ZrC layer deposited at $1550^{\circ}C$. Therefore, the hardness decreased largely due to the formation of a large amount of pyrolytic carbon in the ZrC layer.

Influences of Vegetation Invasion on Channel Changes in the Deposition Area of Torrential Stream (계상퇴적지내의 식생침입이 유로변동에 미치는 영향)

  • Ma, Ho-Seop;Lee, Heon-Ho
    • Journal of the Korean Society of Environmental Restoration Technology
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    • v.3 no.3
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    • pp.12-19
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    • 2000
  • The purpose of this study is to evaluate the channel changes according to the temporal and spatial distribution of the deposition area by the vegetation invasion in Kyesung-river. The deposition area mainly occurred by landslide and debris flow from the headwater channel. And also the movement of subsequent downstream depends upon the site of deposits by a varity erosional processes. As the age of deposition area is older, it had a tendency to stable by plant invasion relatively. The vegetations grown in deposition area were very effective to estimate a historical deformation process of river-bed occurred by landslide. The vegetations around deposition area consisted of the same as tree species grown in forest area of circumference like Pinus densiflora, Styrax japonica, Quercus acutissima and Salix gracilistyla. If the torrential stream is flooding, the deposition area of 1 to 5 years can be change to the channel easily. Deposition area of 11 to 23 years had a high river-bed because it passed long time since deposited, and amount of sedimention is much more in wide than in narrow channel. It is consider that the change of channel had many influenced by the span of survial time, scale and movement frequency of deposition area after the vegetation invasion.

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Numerical analysis of lateral geomorphology changes by channel bed deposition and bank erosion at the river confluence section (합류부 구간에서의 하상퇴적과 하안침식에 의한 평면적 하도변화 수치모의)

  • Ji, Un;Jang, Eun Kyung
    • Journal of Korea Water Resources Association
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    • v.49 no.5
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    • pp.391-398
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    • 2016
  • The confluence section of rivers forms complex flow pattern due to inflow discharge variation at the mainstream and tributary. Due to complex flow characteristics, bed change and bank erosion at the local section produce lateral geomorphology changes in rivers. In this study, bankline change by bank erosion and bed change were simulated using CCHE2D of 2-dimensional numerical model for quantitative analysis of lateral changes in the confluence section of South Han River and Geumdang Stream. As a result, bankline at the left-side channel of the mainstream was largely changed in the downstream section of the confluence compared to the upstream section. Also, bank erosion in the tributary was hardly occurred and bankline at the left-side tributary and right-side main stream moved to riverside land due to decreased velocity and deposition.

A Prediction Model of Transverse Bed Slope in Meandering Rivers (사행하천(蛇行河川)의 횡방향(橫方向) 하상경사(河床傾斜)의 예측모형(豫測模型))

  • Hong, Chang Sun;Chung, Yong Tai
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.11 no.4
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    • pp.81-89
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    • 1991
  • An interesting property of meandering river patterns is that they slowly deform, as bank erosion on one side of a channel and deposition on the other side result in the location of the channel. In this study we used a sine-generated meander pattern proposed by Langbein and Leopold(1966) to develop a solution of a linear, second-order differential equation of transverse bed slope(bed topography) proposed by Odgaard(1986). A new model for transverse bed slope(bed topography), that accounts for the phase lag and the influence of the width to depth aspect ratio, was developed in this study and compared with results of field measurements.

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The Effect of Silicon-Alloying on the Characteristics of the Pyrolytic Carbonds Deposited in Tumbling Bed by CVD (Tumbling Bed에서 화학증착법에 의해 증착되는 열분해탄소의 특성에 미치는 Silicon-Alloying의 효과)

  • 윤영진;이재영
    • Journal of the Korean Ceramic Society
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    • v.20 no.2
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    • pp.166-172
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    • 1983
  • In this study the sillicon-alloyed isotropic pyrolytic carbon was deposited in the tumbling bed from the pyrolysis of propane and silicon tetrachloride and investigated whether the silicon-alloyed isotropic pyrolytic carbon deposited in this study was usable as bionaterial or not. The silicon-allyed isotropic pyrolytic carbon was varied by controlling the process variables such as propane con-concentration and the argon flow rate flowing in to the silicon tetrachloride bubbler at a fixed reaction bed tempera-ture of 120$0^{\circ}C$ a rotation of reaction tube of 40 rpm a bed particle weight of 7.5 g and a total flow rate of 21/min; the propane concentration was varied from 10 to 70 and the argon flow rate flowing into the silicon tetrachloride bubble from 0 to 1000 cc/min. The results show that the silicon-alloyed isotropic pyrolytic carbon was obtained at all conditions investigated, . And then the alloyed silicon content is rangion from 7 to 14.5 wt%. The density and deposition rate of deposited silicon-alloyed isotropic carbon increased axxording to silicon content and propane concentration. And the apparent crystal-size(Lc) of pyrolytic carbon is not changed with silicon content. The density and apparant crystallite size are respec-tively in the range of 1.94 to 2.06 and 20 to 25$\AA$ It is shown that the silicon-alloyed isotropic pyrolytic carbon ob-tained in this experiment is usable as biomaterial.

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Construction and Monitoring of Test bed in Urban Sediment Disaster Prevention Technology (도심지 토사재해 방어기술 테스트베드 구축 및 모니터링 연구)

  • Lee, Jung-min;Kim, Hyo-Jin;Lee, Yoon-Sang;Jin, Kyu-Nam
    • Land and Housing Review
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    • v.8 no.3
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    • pp.161-169
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    • 2017
  • In this study, sediment transfer and precipitation analysis of the test bed watershed was conducted through the model for the application and practical use of the urban sediment disaster prevention technology, and used this as an aid to design to secure reliability. In addition, conducted the test bed monitoring with the defense technology, analyzed the effect, and established the maintenance plan. Analyzed the change of soil deposition volume through arbitrary slope adjustment for the currently installed stormwater conduit of the test bed watershed. As a result, it is important to reduce the total sedimentation amount in the adjustment of the slope of the entire pipeline, but it is important that the sedimentation depth of each sediment does not rise to such a degree as to threaten the performance of the pipeline. Considering these matters, it is necessary to design the pipeline to prevent the clogging of the soil from the viewpoint of the reliability of the entire pipeline. The sediment disaster defense technology test bed is divided into a new city and an old city, and old city test bed is under construction. The result obtained through the monitoring of the test bed in the new city, sediment disasters such as debris can delay the time to reach the downtown area, and it is possible to secure the golden time, such as evacuation and rescue through the warning system. Also, the maintenance of the test bed application was suggested. Continuous and systematic monitoring is required for securing the reliability of element technology and successful commercialization.

Effect of Deposition Parameters on the Property of Silicon Carbide Layer in Coated Particle Nuclear Fuels (피복입자핵연료에서 증착조건이 탄화규소층의 특성에 미치는 영향)

  • Kim, Yeon-Ku;Kim, Weon-Ju;Yeo, SungHwan;Cho, Moon Sung
    • Journal of Powder Materials
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    • v.23 no.5
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    • pp.384-390
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    • 2016
  • Tri-isotropic (TRISO) coatings on zirconia surrogate beads are deposited using a fluidized-bed vapor deposition (FB-CVD) method. The silicon carbide layer is particularly important among the coated layers because it acts as a miniature pressure vessel and a diffusion barrier to gaseous and metallic fission products in the TRISO-coated particles. In this study, we obtain a nearly stoichiometric composition in the SiC layer coated at $1400^{\circ}C$, $1500^{\circ}C$, and $1400^{\circ}C$ with 20 vol.% methyltrichlorosilane (MTS), However, the composition of the SiC layer coated at $1300-1350^{\circ}C$ shows a difference from the stoichiometric ratio (1:1). The density decreases remarkably with decreasing SiC deposition temperature because of the nanosized pores. The high density of the SiC layer (${\geq}3.19g/cm^2$) easily obtained at $1500^{\circ}C$ and $1400^{\circ}C$ with 20 vol.% MTS did not change at an annealing temperature of $1900^{\circ}C$, simulating the reactor operating temperature. The evaluation of the mechanical properties is limited because of the inaccurate values of hardness and Young's modulus measured by the nano-indentation method.

An Experimental Study on Depositional Parameters of Cohesive Sediments in Semi-closed Bay (준 폐만 점착성 퇴적물의 퇴적매개변수 산정에 관한 실험적 연구)

  • Jung, Eui-Taek;Kim, Yong-Muk;Kim, Dong-Ho;Hwang, Kyu-Nam
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.24 no.3
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    • pp.159-165
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    • 2012
  • In this study, a series of deposition tests have been performed using an annular flume and depositional parameters of natural cohesive sediments have been estimated domestically for the first time. The natural cohesive sediments for deposition tests have been collected from Kwangyang Bay and total 18 deposition tests have been carried out on different bed shear stress respectively but with the same initial concentration. Test results for natural cohesive sediments of Kwangyang bay show that minimum bed shear stress ${\tau}_{bmin}$, standard deviation ${\sigma}_1$, and time scale parameter $({\tau}_b^*-1)_{50}$ are $0.11N/m^2$, 0.68 and 0.85, respectively. Through the comparison with results of previous studies for other sediments, the results of this study are shown to be good enough to verify.