• Journal of Korean Society of Environmental Engineers
• /
• v.30 no.10
• /
• pp.984-991
• /
• 2008

This paper reports experimental results, demonstrating the feasibility of horseradish peroxidase(HRP) and H$_2$O$_2$ to reduce phenol transport in saturated porous media. A laboratory-scale packed column reactor(ID: 4.1 cm, sand-bed height 12 cm) column was utilized to simulate injection of HRP and H$_2$O$_2$ into an aquifer contaminated with phenol. Effluent concentrations of phenol and polymerization products were monitored before and after enzyme addition under various experimental conditions(enzyme dose: 0$\sim$2 AU/mL, [ionic strength]: 5$\sim$100 mM, pH: 5$\sim$9). The concentration of phenol in the column effluent was found to decrease by nearly 90% in the presence of HRP(2 AU/mL) and H$_2$O$_2$ in the continuous flow system at pH 7 and ionic strength 20 mM. The influent phenol was converted in the system to insoluble precipitate, which deposited in pore spaces. The remains were discharged as soluble oligomers. About 8% of total pore volume in column system was decreased by deposition of polymer produced.

• Clean Technology
• /
• v.5 no.2
• /
• pp.63-68
• /
• 1999

The activities of Ni(20wt%)/$La_2O_3$, Ni(20wt%)/${\gamma}-Al_2O_3$, and Ni(20wt%)/$SiO_2$ catalyst for $CO_2$ reforming of $CH_4$ were investigated in a fixed bed flow reactor under atmospheric condition. Catalyst characterization using XRD, TEM, SEM, BET analysis were also conducted. The catalytic activity of Ni(20wt%)/$La_2O_3$ catalyst has relatively superior to that of Ni(20wt%)/${\gamma}-Al_2O_3$ and Ni(20wt%)/$SiO_2$ catalyst. The good activity of Ni(20wt%)/$La_2O_3$ catalyst seems to depend on reduced $Ni^{\circ}$ phases of NiO($\rightarrow$ Ni + O), $LaNiO_3$($\rightarrow$ $Ni+La_2O_3$), Ni crystalline phases, and decoration of Ni phases by lanthanum species is also an important factor. Ni(20wt%)/${\gamma}-Al_2O_3$ and Ni(20wt%)/$SiO_2$ catalyst due to surface acidity resulted in the deposition of wisker type and encapsulate carbon on the surface of catalyst, but Ni(20wt%)/$La_2O_3$ catalyst did not show carbon on the surface of catalyst up to 8.5hr reaction.

• Journal of Korean Society on Water Environment
• /
• v.32 no.2
• /
• pp.135-141
• /
• 2016

This study investigated changes of hydrology, soil characteristics, riparian vegetation communities, and geomorphology in sandbars before and after sand-mining to determine the effect of sand-mining at upstream of Guemgang and Bochungcheon streams in Korea. Sand-mining events affected the mining area. They supplied organic matters and nutrients during flood. Sediment deposition caused soil texture change and expansion of vegetation area. However, riverbeds were stabilized after the disturbance. According to the analyses of aerial photographs, the vegetation area was significantly expanded in both dam-regulated streams and dam-unregulated streams after sand-mining. Willow shrubs advanced in disturbed area at an average of 10 years after sand-mining. It took willows trees 10.6 years to become dominant communities. Therefore, it took a total of 20.6 years for new riparian forest to form in sandbar after sand-mining. Our results confirmed that stream flow condition were dependent on vegetation recruitment in dam-regulated streams and dam-unregulated streams. For willow recruitment in unregulated streams, calculation of water level below dimensionless bed shear stress is important because low water level variation is a limiting factor of vegetation recruitment.

• Journal of Drive and Control
• /
• v.16 no.3
• /
• pp.51-58
• /
• 2019

The objective of this study was to investigate a simulation technology for the AM field based on ANSYS Inc.. The introduction of metal 3D printing AM process, and the examining of the present status of AM process simulation software, and the AM process simulation processor were done in the previous study (part 1). This present study (part 2) examined the use of the AM process simulation processor, presented in Part 1, through direct execution of Topology Optimization, Ansys Workbench, Additive Print and Additive Science. Topology Optimization can optimize additive geometry to reduce mass while maintaining strength for AM products. This can reduce the amount of material required for additive and significantly reduce additive build time. Ansys Workbench and Additive Print simulate the build process in the AM process and optimize various process variables (printing parameters and supporter composition), which will enable the AM to predict the problems that may occur during the build process, and can also be used to predict and correct deformations in geometry. Additive Science can simulate the material to find the material characteristic before the AM process simulation or build-up. This can be done by combining specimen preparation, measurement, and simulation for material measurements to find the exact material characteristics. This study will enable the understanding of the general process of AM simulation more easily. Furthermore, it will be of great help to a reader who wants to experience and appreciate AM simulation for the first time.

• Journal of the Korean Society of Manufacturing Process Engineers
• /
• v.18 no.3
• /
• pp.33-40
• /
• 2019

FDM 3D printers have become widespread, and investment in the 3D printer industry is increasing. Therefore, many 3D printers are released and the functions of products are emphasized. However, to lower unit prices, open-type 3D printers are sold in kit form, and their performance is very low. If the 3D printer has many heat sources and is sealed, there is the possibility that the main accessories (the main board, power supply, and motor) will be damaged by trapped heat. At the same time, if the ambient temperature is low due to the properties of the material, the output quality deteriorates. In this study, we analyzed the temperature rise of the main accessories and the quality of the output by the heat bed when a chamber was added to an open-type 3D printer. We also compared the quality of the output due to the air flow with the temperature rise of the main accessories. Moreover, we found the optimal value. As a result of the quality analysis, it was finally confirmed that the case with the chamber at $95^{\circ}C$ was the best for the printing condition. In addition, in the absence of the chamber, the bending of the specimen was found to be large, and in the case of the chamber, the degree of bending was slightly decreased by 0.05 mm.

• Journal of the Korea Safety Management & Science
• /
• v.25 no.1
• /
• pp.7-14
• /
• 2023

We attempted to provide an overview of the laws and current state of the 3D printing industry in South Korea and around the world, using the annual industry surveys and the Wohler report. Additionally, we reviewed articles relating to the potential exposure to hazards associated with 3D printing using metal materials. In South Korea, there were 406 3D printing-related businesses, employing 2,365 workers, and the market size was estimated at 455.9 billion won in 2021. Globally, the average growth rate of the 3D printing industry market over the past 10 years was 27.4%, and the market size was estimated at $11.8 billion in 2019. The United States had the highest cumulative installation ratio of industrial 3D printers, followed by China, Japan, Germany, and South Korea. A total of 6,168 patents related to 3D printing were registered in the US between 2010 and 2019. Harmful factors during metal 3D printing was mainly evaluated in the powder bed fusion and direct energy deposition printing types, and there is a case of material extrusion type with metal additive filaments. The number, mass, size distribution, and chemical composition of particles were mainly evaluated. Particle concentration increases during the opening of the chamber or post-processing. However, operating the 3D printer in a ventilated chamber can reduce particle concentration to the background level. In order to have a safe and healthy environment for 3D printing, it is necessary to accumulate and apply knowledge through various studies.

• Journal of The Geomorphological Association of Korea
• /
• v.27 no.1
• /
• pp.33-45
• /
• 2020

A number of unconsolidated deposits, consisting of a layer of gravels and silt, are found in Dangjeong-ri, Seocheon-gun in the western coast. From below in the stratigraphic sequence, the gravel layer ranging up to a maximum thickness of about 2 meters is interpreted as being formed by fluvial processes of an old channel (Dangjeong S.), and the overlying silt or sandy silt layer of 2 to 3 thickness meters is assumed to be emerged paleo-tidal sediments which was deposited in low tidal-energy environments. As the results of rock surface IRSL datings, the depositional ages of gravels are confirmed as ca. 78,000 ~ 83,000 years BP, indicating that the layer was formed in response to a high-stand sea level of MIS 5a along the Dangjeongcheon estuary. It is presumed that the relative height of 4.5 meter between the altitude of the stream bed (9.5 m) and the altitude of the bedrock boundary in the gravel layer (14 m) indicates the uplift amount since deposition. Paleo-sedimentary environments and an altitude of paleo-shoreline in the study area will be discussed with additional age dating focused on the silt layer.

• Korean Journal of Environment and Ecology
• /
• v.22 no.6
• /
• pp.658-665
• /
• 2008

One of the characteristics of fluvial river channel with sand bed-material is the existence of movable sand bars not occupied with vegetation. However, sand bars at the Hahoe's reach of the Nakdong River showing a double-meandering channel has been changed into expanding vegetation area. Moreover, sand material, in recent years, has stopped moving to downstream in channel and the number and area of bare bars which did not occupied by vegetation have been decreased. In order to find out the mechanism, we carried out the channel characteristics surveys such as hydro-geomorphologic, soil physio-chemical and vegetation surveys were conducted twice on autumn season in 2005,2006. The results so far achieved showed that the reduced discharge of transported sediment and duration of dry season might be critical factors for the spread of luxuriant vegetation. The vegetation area was significantly expanded by floods exceeding the subsequent dominant flow discharge. Furthermore, the expansion of vegetation area was highly correlated with the supply of organic matter, nutrients and alteration of soil texture by sediment deposition during the flooding event.

• Journal of the Korean Society of Safety
• /
• v.32 no.4
• /
• pp.46-52
• /
• 2017

Sediment exchange in river has been affected by artificial changes such as dredging and abnormal climate changes like intense rainfall. Over last decades in Korea, there were many constructions, restoration or rehabilitation in rivers. Therefore, deposition and erosion become more actively occurred than before, which may threaten the river safety such as flood defense. For safety's sake, the dredging of river bed, which is considered as the most typical measure, has been increased to extend hydraulic conveyance compared with previous conditions. However, since it might change the sediment mechanism, there would be another risk at which unexpected side effects such as headward erosion could be occurred. Particularly, sedimentation at abrupt expansion region is able to lead to hydraulic characteristics like water elevation in the upstream region in the beginning of dredging, which, however, has been barely studied in this field. Therefore in this study, the relationship between sediment mechanism at dredging section and hydraulic characteristics in upstream region were presented through numerical simulations in the idealized abruptly widen channel using Delft3D. The ideal channel of 2,000 m length with each side angle of 45 degrees at abruptly widen expansion region was employed to consider the sediment angle of repose. The sensitivity analysis was performed on the dimensionless factors consisted of upstream and downstream depths($h_u$, $h_d$), width($w_u$, $w_d$), water level(H), flow rate(Q) and discharge of sediment($Q_s$). And the sedimentation amount at dredging and the upstream hydraulic characteristics were investigated through that analysis. It showed that $h_d/h_u$, $H/h_u$ and $w_d/w_u$ were more influential in sequence of effect on sedimentation amount, while $h_d/h_u$, $w_d/w_u$ and $H/h_u$ on upstream region. It means that $h_d/h_u$ was revealed as the most significant factors on sedimentation, also it would most highly affect the rising of water level upstream.

• Journal of the Korean Applied Science and Technology
• /
• v.37 no.4
• /
• pp.723-732
• /
• 2020

The spent RHDS (Residue HydroDeSulfurization) catalyst is deactivated mainly by deposition of various contaminants such as coke, sulfur and vanadium on the surface of catalyst. To eliminate those contaminants, the following remanufacturing process was conducted. The first, heavy oil on the surface of the spent RHDS catalyst was removed by kerosene and dehydrated. The second, the high temperature incineration was carried out to eliminate coke and sulfur components deposited on the surface of spent RHDS catalyst. The third, the excessive quantity of Vanadium deposited on the surface of catalyst was removed by leaching process as follows: ultrasonic agitation was carried out at 50℃, for 10 seconds with 0.5% and 1% oxalic acid solution. The purpose of this process is to find out regenerated RHDS catalyst can be used as SCR catalyst for NOx reduction by controlling the vanadium residual content of the regenerated RHDS catalyst through leaching process. The composition of regenerated RHDS catalyst was analyzed by XRF and the NOx reduction efficiency was also measured by continuous catalytic fixed bed reactor. As the result, regenerated catalyst, with 0.5% oxalic acid, ultrasonic agitation in 10 seconds, showed the most stable NOx reduction efficiency. Also, in comparison with commercial SCR catalyst, the NOx reduction performance of regenerated catalyst was similar to that of commercial SCR catalyst at the temperature 375℃ and higher whereas was lower than commercial SCR catalyst at the temperature range between 200~250℃. Therefore, it was confirmed that the regenerated catalyst as powder form wash coated on the surface of metal corrugated substrate can be used for commercial SCR catalyst.