• Title/Summary/Keyword: degree of degradation

Search Result 513, Processing Time 0.031 seconds

Effect of Surface Grinding on Low Temperature Degradation of 3Y-TZP (표면 연마가 3Y-TZP의 저온열화에 미치는 영향)

  • 김대준;이홍림;정형진
    • Journal of the Korean Ceramic Society
    • /
    • v.30 no.2
    • /
    • pp.164-168
    • /
    • 1993
  • Grinding of 3mol% Y-TZP enhanced the texturing of t-ZrO2, which is represented by the increased I(002)t/I(200)t peak intensity ratio, and an asymetric broadening of (111)t peak. The degree of texturing and asymetric broadening depended on a seversity of grinding. The asymetric (111)t peak broadening was resulted by the formation of r-ZrO2. When aged at 25$0^{\circ}C$ for 120h, r-ZrO2 transformed to t-ZrO2 due to the relief of stressed surface area and the amount of tlongrightarrowm transformation inversely varied with the I(002)t/I(200)t. The inverse dependence was interpreted by that the degree of texturing determines the magnitude of residual surface stress and the lattice relaxation of t-ZrO2, which causes the low temperature degradation, is retarded as the residual stress becomes greater.

  • PDF

The Evaluation of Partially Degraded Material Using Nonlinear Propagation Characteristics of Ultrasonic Wave (초음파 비선형 전파특성을 이용한 부분 열화 재료의 평가)

  • Kim, Kyung-Cho;Jhang, Kyung-Young;Hisashi, Yamawaki
    • Transactions of the Korean Society of Mechanical Engineers A
    • /
    • v.25 no.2
    • /
    • pp.214-219
    • /
    • 2001
  • In this paper, the nonlinear behavior of ultrasonic wave in partially degraded material is considered. For this aim, FDM(finite difference method) model for the nonlinear wave equation was developed with the restriction to the 1-D longitudinal wave motion and how the partial degradation in material contributes to the detected nonlinear parameter was analyzed quantitatively. In order to verify the rightness of this simulation method, the relation between the detected nonlinear parameter and the continuous distribution of degradation obtained from simulation was compared with experiment results and the simulation and experiment results showed similar tendency. It can be known from simulation result that the degree of degradation, the range of degradation and the continuous distribution of degradation have strong correlation with the detected nonlinear parameter. As it was possible in these simulations that only special part is assumed as degraded one, the quantitative evaluation of partially degraded material may be obtained by using this method.

Design of Degradation Test without Replacement Based on Tightened Critical Value (엄격한 고장판정기준을 적용한 비복원 열화시험 설계에 관한 연구)

  • Park Boo Hee;Lim Ho Kyung;Jang Joong Soon
    • Journal of Applied Reliability
    • /
    • v.5 no.1
    • /
    • pp.167-180
    • /
    • 2005
  • Design of a degradation test without replacement is considered based on tightened critical value to reduce the evaluation testing time. The sample size, number of inspections, and the critical values are determined to assure the same probability of acceptance when the testing time is reduced to some degree. Photo-diode balance of an optical pickup is analyzed as a case study.

  • PDF

Study of test method of tracking degradation for polymer insulation (폴리머 애자의 트래킹 열화 평가방법 연구)

  • 심대섭;박병락;박성균;소진중
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2000.11a
    • /
    • pp.391-394
    • /
    • 2000
  • EPDM/silicone blend was prepared with polyorganosiloxane compatibilizer for out-door polymer insulation used to shed. Each blend had various weight ratios, 100/0, 90/10, 70/30, 50/50, 30/70, 10/90, and 0/100 as EPDM to silicone, and electrical and tracking characteristics were studied with the method of IEC 60587. And also, tracking properties and contact angle related to UV-weathering period were studied to understand the degree of degradation of blend after 1000 h UV-weathering.

  • PDF

Study on the Physicochemical Properties of Crosslinked Poly(Styrene-Butadiene-Styrene) Block Copolymers Prepared by Radiation (방사선으로 제조된 가교 구조의 Poly(Styrene-Butadiene-Styrene) 블록 공중합체 특성에 관한 연구)

  • Lee, Sun-Young;Song, Ju-Myung;Sohn, Joon-Yong;Shin, Junhwa
    • Journal of Radiation Industry
    • /
    • v.6 no.2
    • /
    • pp.171-176
    • /
    • 2012
  • In this study, a crosslinked poly(styrene-butadiene-styrene) [SBS] block copolymers were prepared by using gamma ray irradiation method. The effects of various radiation doses on the degree of crosslinking, thermo property, and morphology of crosslinked SBS block copolymer were investigated. The degree of crosslinking of crosslinked SBS block copolymers were measured by gel-fraction and FT-IR. It was found that the degree of crosslinking of crosslinked SBS block copolymers increases with increase of the irradiation dose while the TGA result shows that the initial degradation temperature of irradiated SBS block copolymer was shifted to lower temperature with increasing irradiation dose. These results indicate that degradation reaction also occurs when SBS block copolymer is exposed to gamma ray irradiation for crosslinking reaction. The SAXS and FE-SEM results indicate that the phase separation of the styrene block and butadiene block was reduced with increasing irradiation dose.

Degradation Characteristics of Aqueous MEA Solution by Corrosion Products and Absorption Conditions (흡수 조건 및 부식 생성물에 의한 MEA 수용액의 변성 특성)

  • NAM, SUNGCHAN;SONG, YOONAH;BAEK, ILHYUN;YOON, YEOIL;YOU, JEONGKYUN;LEE, CHANGHA
    • Journal of Hydrogen and New Energy
    • /
    • v.27 no.3
    • /
    • pp.290-297
    • /
    • 2016
  • The absorbent loss due to degradation in $CO_2$ capture process using aqueous alkanol amine solution has adverse effect on the economics of overall process. The degradation causes absorbent loss, equipment corrosion, foaming, adhesive material producing and viscosity increase in operation. In this study, the degradation characteristics of $CO_2$ capture process using MEA (monoehtanolamine) under various conditions such as $O_2$ partial pressure, $CO_2$ loading and absorbent temperature. The effects of iron, which generated from the equipment corrosion, on absorbent degradation were studied using $Fe_2SO_4$ containing MEA solution. The produced gases were analyzed by FT-IR(Fourier Transform Infrared Spectrophotometer) and the specifically measured $NH_3$ concentration was used as a degradation degree of aqueous MEA solution. The experiments showed that the higher $CO_2$ loadings (${\alpha}$), $O_2$ fraction ($y_{O2}$) and reaction temperature enhanced the more degradation of aqueous MEA solution. Comparing other operation parameters, the reaction temperature most affected on the degradation. Therefore, it could be concluded that the above parameters affects on degradation should be considered for the selections of $CO_2$ absorbent and operating conditions.

On the Design of Block Lengths for Irregular LDPC Codes Based on the Maximum Variable Degree

  • Chung, Kyu-Hyuk
    • The Journal of Korean Institute of Communications and Information Sciences
    • /
    • v.35 no.11C
    • /
    • pp.907-910
    • /
    • 2010
  • This paper presents the design of block lengths for irregular low-density parity-check (LDPC) codes based on the maximum variable degree $d_{{\upsilon},max}$. To design a block length, the performance degradation of belief-propagation (BP) decoding performance from upper bounds on the maximum likelihood (ML) decoding performance is used as an important factor. Since for large block lengths, the performance of irregular LDPC codes is very close to the Shannon limit, we focus on moderate block lengths ($5{\times}10^2\;{\leq}\;N\;{\leq}\;4{\times}10^3$). Given degree distributions, the purpose of our paper is to find proper block lengths based on the maximum variable degree $d_{{\upsilon},max}$. We also present some simulation results which show how a block length can be optimized.

Degradation Degree Evaluation of Heat Resisting Steel by Electrochemical Technique Part 2 : Effect of Testing Conditions on Evaluation Value of Degradation Degree and Changes of Mechaical Properties (전기화학적 방법에 의한 내열강의 열화도측정 제2보 : 열화도측정치에 미치는 측정조건들의 영향과 기계적성질 변화에 대해서)

  • 정희돈;권영각;장래웅
    • Transactions of the Korean Society of Mechanical Engineers
    • /
    • v.17 no.2
    • /
    • pp.300-312
    • /
    • 1993
  • The material deterioration of service-exposed boiler tube steels in fossil power plant was evaluated by using the electrochemical technique namely, modified electrochemical potentiokinetic reactivation(EPR). It was focused that the passivation of Mo$_{6}$C carbide which governs the mechanical properties of Mo alloyed steels did not occur even in the passivity region of steel in sodium molybdate solution and the reactivation peak current (Ip) observed as the result of non-passivation indicating the precipitation of Mo$_{6}$C carbides. To obtain the optimal test conditions for the field test by using the specially designed electrochemical cell, the effects of scan rate, the surface roughness and the pH of electrolyte on Ip value were also investigated. Furthermore, the change of mechanical properties occurred during the long time exposure at high temperature was evlauated quantitatively by small punch(SP) tests and micro hardness test taking account of the metallurgical changes. It is known that reactivation peak current (Ip) has a good relationship with Larson-Miller Parameter(LMP) which represents the information about material deterioration occurred at high temperature environment. In addition it was possible to estimate the ductile-brittle transition temperature (DBTT) by means of the SP test. The Sp test could be, therefore, suggested as a reliable test method for evaluating the material degradation of boiler tube steels. From the good correaltion between the SP DBTT and Ip values shown in this study, it was knows that the change of mechanical properties could be evaluated non-destructively by measurring only Ip values.ues.

Effect of Environmental Conditions on the Biodegradation of Cellulose Fibers - Effect of Humidity in Soil - (환경 조건에 따른 셀룰로스계 섬유의 생분해성 - 토양 수분율을 중심으로 -)

  • Kang, Yun-Kyung;Park, Chung-Hee
    • Journal of the Korean Society of Clothing and Textiles
    • /
    • v.29 no.7 s.144
    • /
    • pp.1027-1036
    • /
    • 2005
  • Based on the correlation analysis result of preceding research, the biodegradabilities of cellulose fibers were closely related to the moisture regain of the samples, which reflects the hydrophilicity and internal structure of the fibers. In addition to this factor, it was expected that the biodegradation conditions influence the biodegradability of fibers. In this study, widely used cellulose fibers including cotton, rayon, and acetate were used. The biodegradabilities of cellulose fibers were measured by soilburial test, and then the degradation behaviors based on each condition were compared. Moreover, the effects of degradation conditions such as humidity of the soil were investigated. Changes in the internal structure of samples were also observed by X-ray analysis according to the soil burial time. It was shown that humidity of soil facilitated the degradation of cotton, rayon, and acetate fibers, showing higher degradation rate with higher humidity in soil. This effect was shown to be much greater in the fibers of high moisture regain such as cotton and rayon. In respect of microstructure change, crystallinities and their crystal size of fibers decreased remarkably in the soil of higher humidity. It was revealed that degradation of crystalline area was more dependent on the soil humidity than that of amorphous area.

Effect of Protease Inhibitors on Degradation of Recombinant Human Epidermal Growth Factor in Skin Tissue

  • Ryou, Hae-Won;Lee, Jang-Won;Kyung, Kyung-Ae;Park, Eun-Seok;Chi, Sang-Cheol
    • Archives of Pharmacal Research
    • /
    • v.20 no.1
    • /
    • pp.34-38
    • /
    • 1997
  • Recombinant human epidermal growth factor (rhEGF), a polypeptide of 53 amino acid residues, is subject to degradation by numerous enzymes, especially proteases, when it is applied on the skin for the treatment of open wound. Amastatin, aprotinin, bestatin, EDTA, EGTA, gabexate, gentamicin, leupeptin, and TPCK were investigated for the possible protease inhibitors, which may use to protect rhEGF from degradation by the enzymes in the skin. Skin homogenates containing protease inhibitors and rhEGF were incubated at $37^{\circ}C$ for 30 minutes. After the reaction was stopped with trifluoroacetic acid, the amount of rhEGF remaining in the sample was determined with an HPLC method. The percentages of rhEGF degraded, at the skin/PBS ratio of 0.25, in the mouse, rat, and human skin homogenate were 85%, 70%, and 46%, respectively. The degree of degradation of rhEGF in the cytosolic fraction was higher than that in the membrane fraction and these enzyme reactions were completed in 30 minutes. Bestatin, EGTA, and TPCK showed significant inhibitory effects on the degradation of rhEGF in the two fractions (p<0.05), while the other protease inhibitors had no significant inhibitory effects or, even resulted in deleterious effects. Therefore, the formulation containing one or several inhibitors among these effective inhibitors would be a promising topical preparation of rhEGF for the treatment of open wound.

  • PDF