• Title/Summary/Keyword: degree of Polymerization

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Dental Properties of Hydroxyapatite Filled Polymer Composite (수산화인회석이 충전된 고분자 복합체의 치과적 물성)

  • Kim Oh-Young;Seo Ki-Taek
    • Polymer(Korea)
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    • v.30 no.2
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    • pp.135-139
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    • 2006
  • To evaluate the dental restorative application of polymer composites filled with hydroxyapatite (HAP) which is an inorganic component of human bone material, dental properties of the polymer composites were investigated. A visible light system was utilized to activate the acrylate resin matrix of the composites. Maximum loading percentage of HAP in composite was 65 wt% and the depth of cure was 6.0 mm which can be applicable for dental restoration. With increasing the HAP content, degree of conversion of polymer composites was slightly decreased, however, polymerization shrinkage value was not varied. Diametral tensile strength value was enhanced with an increase of HAP content, however, there was no strict trend between flexural strength and HAP concentration. Anyhow, polymer composites prepared herein have superior mechanical properties sufficient specifications applicable to dental materials.

Effect of propyl gallate on the properties of regenerated cellulose fiber spun from NMMO dope system (Propyl gallate가 NMMO계에서 제조된 셀룰로오스 섬유의 물성에 미치는 영향)

  • Lee, Soo;Lee, Sang-Won;Lee, Hyang-Yeol
    • Journal of the Korean Applied Science and Technology
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    • v.27 no.4
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    • pp.508-514
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    • 2010
  • Regenerated cellulose fibers were prepared from three pulps containing different degree of polymerization(DP) and $\alpha$-cellulose contents by dry-jet wet spinning technique with cellulose dope in N-methylmorpholin N-oxide (NMMO). The effect of antioxidant, n-propyl gallate (PG) on the properties of different regenerated celluloses was studied using X-ray diffraction, copper number calculation, and viscometry. The degradaqtion of regenerated cellulose from pulp containing higher DP and lower $\alpha$-cellulose content was occurred more seriously. The tensile strength and initial modulus of regenerated cellulose fiber obtained from NMMO dope with PG were higher than those of fiber obtained from NMMO dope without PG. All fibers showed the round shape cross section and typical cellulose II crystalline structure.

Process for the Preparation of Conducting Polymer Composites (I) : Effect of the Porosity on the Conductivity (전도성 고분자 복합체 제조를 위한 신합성 연구 (I) : 다공성정도가 전도성 고분자 복합체의 전도도에 미치는 영향)

  • Son, Suk-Hye;Park, Young-Jun;Kim, Jung-Hyun
    • Applied Chemistry for Engineering
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    • v.7 no.2
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    • pp.393-400
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    • 1996
  • The conducting polymer composites were prepared by imbibing the porous particle with an $FeCl_3$ oxidant solution, drying the imbibed porous particle, and imbibing again with pyrrole solution for polymerization to take place in the pore. The conductivity of the porous composite particles, was higher than that of nonporous particles. Also, the conductivity of composite was increased with increasing specific surface area and pore specific volume of the host porous particles since the degree of formation of conducting polymer in the pore increased.

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The Properties of Amylose of Cow Pea Starch (동부 전분의 아밀로오스 특성)

  • Kweon, Mee-Ra;Ahn, Seung-Yo
    • Applied Biological Chemistry
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    • v.33 no.1
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    • pp.39-42
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    • 1990
  • The properties of amylose of cow pea starch were investigated. Amylose content of cow pea was 25.1 % and iodine binding capacity was 20.2 %. The ${\beta}-amylolysis$ limit of the amylose was 82.3%. The limiting viscosity number of the amylose fraction was 204 ml/g and the corresponding average degree of polymerization was 1,510 glucose units. The percent distribution of molecular weight of the amylose by gel chromatography was $1{\times}10^4$(0.7 %), $1{\times}10^4{\sim}4{\times}10^4$(4.1 %), $4{\times}10^4{\sim}5{\times}10^5$(44.6 %), $5{\times}10^5{\sim}4{\times}10^7$(49.6 % ).

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Analysis of Mugwort Oligosaccharides Utilized by Bifidobacteria (Bifidobacteria가 이용한 쑥의 올리고당 분석)

  • Lee, Seon-Hwa;Shin, Hyun-Kyung
    • Korean Journal of Food Science and Technology
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    • v.28 no.1
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    • pp.28-33
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    • 1996
  • The water extract of mugwort was analyzed to see its growth-promoting activity for bifidobacteria and lactobacilli. The growth of bifidobacteria appeared to be enhanced by carbon source in the water extract of mugwort. Bifidobacterium longum seemed to utilize preferentially monosaccharides and oligosaccharides with 2-5 DP (degree of polymerization). The mugwort oligosaccharides were separated by charcoal-celite column chromatography and purified by Bio-gel $P_2$ column chromatography. HPLC chromatograms of the hydrolyzates of oligosaccharides showed that they were mainly composed of galactose and glucose.

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Preparation and Properties of Electrically Conductive Clothing materials (전기전도성 의류소재의 제조 및 물성에 관한 연구)

  • 홍경희;오경화
    • Journal of the Korean Society of Clothing and Textiles
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    • v.23 no.4
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    • pp.584-592
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    • 1999
  • Highly conductive polyaniline(PAn)-nylon 6 composite fabric was prepared by immersing the nylon 6 fabric in 0.5M aniline+0.35M HCl aqueous solution at 4$0^{\circ}C$ for 2hours, Polymerization was then followed by mixing the prepared oxidant and dopant solution(0.5M(NH4)2S2O+0.35M HCl) to the diffusion bath at 5$^{\circ}C$ for 30 minutes. The conductivity of prepared PAn-nylon 6 composite fabrics reached as high as 0.5$\times$10-1S/cm. Their conductivity were significantly affected by the aniline and oxidant concentration. As compared to those of nylon 6 fabric heat of fusion melting point the degree of crystallinity and tensile strength of PAn-nylon 6 did not significantly changed by inclusion of PAn. In the aspect of serviceability wheras the fabric conductivity was significantly decreased after multiple washion no significant changes in the fabric conductivity were observed after abrading the composite fabric over 50 cycles. However we found that the fabric conductivity could be recovered by acid re-doping with HCl.

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Synfuel Production Technology : Catalyst for Fischer-Tropsch Synthesis (합성액화연료 생산 기술: Fischer-Tropsch 합성용 촉매)

  • Park, Jo-Yong
    • Journal of the Korean Applied Science and Technology
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    • v.30 no.4
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    • pp.726-739
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    • 2013
  • Fischer-Tropsch synthesis (FTS) converts synthesis gas (CO and $H_2$) into longer chain hydrocarbons by a surface polymerization reaction. Cobalt- or iron-based catalysts normally show excellent activity for syngas conversion to petroleum products leading to super clean diesel fuels. The catalytic activities of the catalysts in FTS depend on the number of active sites on the surface. The number of active site was determined by the active metal particle size, loading amount, reduction degree and support-active metal interaction. The investigation adopts new methodology in preparing FT catalyst, which contains the controlled synthesis of active metal. The main focus of this paper is to give an overview of the types of catalysts, also including their preparation and reduction; the types of FT reactors; and also including the reaction conditions.

Role of gas flow rate during etching of hard-mask layer to extreme ultra-violet resist in dual-frequency capacitively coupled plasmas

  • Gwon, Bong-Su;Lee, Jeong-Hun;Lee, Nae-Eung
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.08a
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    • pp.132-132
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    • 2010
  • In the nano-scale Si processing, patterning processes based on multilevel resist structures becoming more critical due to continuously decreasing resist thickness and feature size. In particular, highly selective etching of the first dielectric layer with resist patterns are great importance. In this work, process window for the infinitely high etch selectivity of silicon oxynitride (SiON) layers and silicon nitride (Si3N4) with EUV resist was investigated during etching of SiON/EUV resist and Si3N4/EUV resist in a CH2F2/N2/Ar dual-frequency superimposed capacitive coupled plasma (DFS-CCP) by varying the process parameters, such as the CH2F2 and N2 flow ratio and low-frequency source power (PLF). It was found that the CH2F2/N2 flow ratio was found to play a critical role in determining the process window for ultra high etch selectivity, due to the differences in change of the degree of polymerization on SiON, Si3N4, and EUV resist. Control of N2 flow ratio gave the possibility of obtaining the ultra high etch selectivity by keeping the steady-state hydrofluorocarbon layer thickness thin on the SiON and Si3N4 surface due to effective formation of HCN etch by-products and, in turn, in continuous SiON and Si3N4 etching, while the hydrofluorocarbon layer is deposited on the EUV resist surface.

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Altered Fine Structure of Amylopectin Is Induced by Exogenous Gibberellin During Rice Grain Ripening

  • Kim, Sang-Kuk;Park, Shin-Young;Lee, Sang-Chul;Lee, In-Jung
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.51 no.6
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    • pp.523-526
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    • 2006
  • When $GA_{4}$ was applied to heading stage, it was examined to understand the change of plant hormones and starch during grain filling and ripening. Exogenous gibberellin caused a dramatic decrease in endogenous ABA content. Endogenous $GA_{4}$ content in both superior and inferior part was more promoted in $GA_{4}-treated$ rice grain than in the control. $GA_{1}$ content of an inferior part was not detected in the control and $GA_{4}-treated$ rice otherwise $GA_{4}$ was detected in all grain parts. Ripened grain rate in $GA_{4}-treated$ rice grain was lower than that of the control plant. Amylopectin from $GA_{4}-treated$ grain contained more very short chains with degree of polymerization (DP) between 4 and 8 than amylopectin from the control plant. It suggests strongly that fine structure of rice endosperm may be changed by exogenously applied $GA_{4}$ in rice plants.

Analysis of Furanic Compounds Dissolved in Transformer Oil (변압기에 용존된 Furan계 물질 분석)

  • Kim, Jae-Hoon;Lee, Byung-Sung;Lee, Sei-Hyun;Koo, Kyung-Wan;Han, Sang-Ok
    • Proceedings of the KIEE Conference
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    • 2005.07c
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    • pp.1909-1911
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    • 2005
  • The electrical and chemical characteristics in transformer insulations are changed due to thermal stress. In the chemical property, as the Kraft paper ages, the cellulose polymer chains breakdown into shorter lengths with a corresponding decrease in both tensile strength and degree of polymerization(DP). Furthermore, cellulous chains breakdown is accompanied by an increase in the content of various furanic compounds within the dielectric liquid. It is known that furanic components in transformer oil come only from the decomposition of insulating paper rather than from the oil itself. Therefore the analysis of furan products provides a complementary technique to dissolved gas analysis for monitoring transformers when we evaluate the aging of insulating paper by the total concentration of carbon monoxide and carbon dioxide dissolved in oil only. In this paper the accelerated aging process of oil--paper samples have been investigated at a temperature up to $140^{\circ}C$ for 500 hours. The oil-paper insulation samples have been measured at intervals of 100 hours. For analysis we used high performance liquid chromatography(HPLC) in accordance with IEC 61198 method.

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