• Journal of Korea Technical Association of The Pulp and Paper Industry
• /
• v.30 no.4
• /
• pp.28-34
• /
• 1998

Polyvinyl acetate emulsion has been widely used as adhesives for wood and paper, paint additives and binders for fiber, leather, and other materials because it is an excellent adhesive with many advantages including low in toxicity risks and manufacturing cost. It is expected the consumption of polyvinyl acetate emulsion as adhesives will increase in cigarette industry as well as in paperboard coating industry. Recently the operation speed of the cigarette tip wrapper increased so substantially that improvement of the emulsion properties is required including good wet tack development, narrow and controlled particle size distribution, low viscosity, etc. In this study the effects of such polymerization conditions as the type and amount of emulsifier, internal or external plasticizing, and emulsification methods on the viscosity and particle size of polyvinyl acetate emulsions were examined. Results showed that polyvinyl alcohol with a high degree of hydrolysis and low molecular weight and nonionic surfactants are superior to anionic surfactant in improving adhesion and emulsion stability. They also tend to produce emulsions with smaller particle size. External plasticization with dipropylene glycol dibenzoate was more effective in improving flexibility than internal plasticization with butyl acrylate. Monomer emulsification under high shear was more effective in decreasing the particle size.

• The Korean Journal of Ecology
• /
• v.15 no.4
• /
• pp.329-335
• /
• 1992

Bionomics of diplopodes was studid near chongyongchi in the chiri mountains from sept. 1990 to dec. 1991 by surveying 10 sample sites at 12 occasions. During this period 13 species of diplopodes from 11 genera, 8 families, and 6 orders were collected. Species were more diversed under quercus mongolica followed by quercus serrata and pinus densiflora sp. epenerchodus koreanus bifidus, and e. k. koreanus were found in all sample sites and these 6 species have been reported to be distributed throughout south korea. yamasinaium sp., riukiaria semicirculalis, parafontaria koreanus, and sicotanus eurygaster were found only under quercus mongolica community and postulated to be related to diet meanwhile other enviromental factors such as temperature, soil ph, and altitude should be taken into consideration. Species diversity index was higher at altitude 700m followed by at 900m, 1, 000m, 800m, 600m, 500m, 1, 100m, 400m, 300m, and 1, 200m in discending order likely due to the enviromental factors such as climatic and edaphic affects, disturbance by human, and degree of floral diversity. Species similarity index was highest 0.78 between altitude 500m and 600m sample sites could be grouped into 3, namely first 300m, 400m, second 500m, 600m, 700m, 1, 000m, 800m, 900m, and third 1, 100m, 1, 200m.

• Transactions on Electrical and Electronic Materials
• /
• v.15 no.4
• /
• pp.175-181
• /
• 2014

In this paper, the simulation and modeling of a polyethylene/clay nanocomposite were undertaken to predict the nanocomposite's dielectric behavior and to help design a nanocomposite material with optimum electrical properties for electrotechnical or electronic applications. A 3-D simulation model using the finite elements method was employed in order to study the effective permittivity and electric field distribution of two-phase nanocomposite materials for ordered and random distributions of inclusions in a low-loss host matrix such as polyethylene. The influence of the dispersion of reinforcing particles, and of the permittivity and radius of the inclusions, was analysed. The simulation results were compared with alternative, known theoretical solutions obtained from classical models, and were found to be in good agreement. The numerical results also indicate that for fixed volume fractions of nanoparticles the effective permittivity of the mixture, for ordered and random distributions, does not vary with the degree of dispersion. The variation of the effective permittivity with the particle radius is shown, using numerical data, to agree with the analytical modules.

• IE interfaces
• /
• v.17 no.2
• /
• pp.233-241
• /
• 2004

The main subject to become a hub port is automation. The automated container terminal has already operated in advanced ports and it has been planned for the basic planning and operation design in domestic case. The key of automated container terminal is effective operation of both ATC(automated transfer crane) and AGV(automated guided vehicle) which is automated handling equipments. This is essential to productivity of automated container terminal. This study suggests the most optimal method of equipment operation in order to minimize loading time using each three types of effective ATC operation methods and AGV dispatching rules in automated container terminals. As the automated equipment operation causes unexpected deadlocks or interferences, it should be proceeded on event-based real time. Therefore we propose the most effective ATC operation methods and AGV dispatching rules in this paper. The various states occurred in real automated container terminals are simulated to evaluate these methods. This experiment will show the most robust automated equipment operation method on various parameters(the degree of yard re-marshaling, the number of containers and AGV)

• Journal of the Korean Magnetic Resonance Society
• /
• v.10 no.1
• /
• pp.115-125
• /
• 2006

Hippuryl-L-histidyl-L-leucine(HHL) is widely used as a substrate of angiotensin converting enzyme(ACE) cleaving the neurotransmitter angiotensin(I) to the octapeptide angiotensin(II). The structure of the substrate molecules should provide information regarding the geometric requirements of the ACE active site. For the purpose of determination of in vivo reaction, metallo(Cu, Zn)-HHL complexes were synthesized and the degree of complex formation were identified by MALDITOF, ESI mass spectrometric analysis. Tn addition, the pH-dependent species distribution curves were obtained by potentiometric titration. Nitrogen atoms of imidazole ring and oxygen atom of caboxylate groups in the peptide chain were observed to be participated in the metal complex formation. After purification of complexes further structural characterization were made by utilizing UV-Vis, electrochemical methods and NMR. Complete NMR signal assignments were carried out by using 2D-spectrum techniques COSY, TOCSY, NOESY, HETCOR. A complex that two imidazole and carboxylate groups are asymmetrically participating to coordination mode was predicted to the solution-state structure of $Cu(II)-HHL_2$ based on $^{13}C-NMR$ signal assignment and NOE information.

• Journal of Korean Society for Atmospheric Environment
• /
• v.16 no.2
• /
• pp.89-102
• /
• 2000

A total of 318 particulate sample sets consisting of both fine PM(FPM : dp$\leq$2.5 ${\mu}{\textrm}{m}$) and coarse PM(CPM : 2.5${\mu}{\textrm}{m}$${\mu}{\textrm}{m}$) was collected by a dichotomous sampler in Suwon area from December 1996 to November 1997. The concentration of seven inorganic elements such as pb. Cr, Cd, Cu, Zn Fe and Na were determined from each sample using an AAS. The purpose of the study was to extensively investigate environmental behaviors of particulate matters and to provide air quality management schemes applying various statistical approaches. The mean concentrations of PM10 Results of correlation analyses indicated the existence of strong correlations among inorganic elements PM10 FPM CPM and various meterological variables. Our study also examined the degree of uncertainties whether the particular elements can be assorted into the accumulation mode or the coarse mode in their size distribution. Furthermore the analysis of the pollution rose showed graphically the direction of potential sources of particulate matters. According to statistical analyses of our data quantitative differences appeared in the pollution patterns between weekdays and weekends.

• Tunnel and Underground Space
• /
• v.11 no.4
• /
• pp.311-318
• /
• 2001

RQD is used to evaluate the degree of fracture in the rock mass and is also used as input into rock mass classification scheme, such as RMR and Q-system. However there are some drawbacks of the RQD caused by anisotropy and calculation length. Thus it is important to understand the variation of RQD in 3-D space in order to evaluate the properties of rock mass. The main purpose of this study is to reveal the distribution of RQD in the equal-angle stereo net, to investigate the effects of scanline length and joint frequency and to inquire the effect on the selection of rock mass strength parameters in the numerical analysis. Analysis has been extended to field joint survey data using same method. The results can be applied to contribute for more accurate interpretation of the results of engineering geological survey for better design and construction work.

• Journal of Soil and Groundwater Environment
• /
• v.21 no.6
• /
• pp.101-113
• /
• 2016

To properly manage and remediate groundwater contaminated with chlorinated hydrocarbons such as trichloroethylene (TCE), it is necessary to assess natural attenuation processes of contaminants in the aquifer along with investigation of contamination history and aquifer characterization. This study evaluated natural attenuation processes of TCE at an industrial site in Korea by delineating hydrogeochemical characteristics along the flow path of contaminated groundwater, by calculating reaction rate constants for TCE and its degradation products, and by using geochemical and reactive transport modeling. The monitoring data showed that TCE tended to be transformed to cis-1,2-dichloroethene (cis-1,2-DCE) and further to vinyl chloride (VC) via microbial reductive dechlorination, although the degree was not too significant. According to our modeling results, the temporal and spatial distribution of the TCE plume suggested the dominant role of biodegradation in attenuation processes. This study can provide a useful method for assessing natural attenuation processes in the aquifer contaminated with chlorinated hydrocarbons and can be applied to other sites with similar hydrological, microbiological, and geochemical settings.

• Archives of Plastic Surgery
• /
• v.32 no.2
• /
• pp.250-254
• /
• 2005

Burns due to epileptic seizures are commonly deep and usually require operative treatment. The purpose of this study is to identify the characteristics of burned epileptic patients that could lead to the development of preventive programs to reduce the incidence of burn injuries. We analyzed epidemiological data for 34 patients acutely burned due to epileptic seizure admitted retrospectively. There were 15 male and 19 female subjects. The age distribution was from 6 years to 70 years with the mean age of 42.7 years. Seizures usually occurred while carrying out daily domestic chores. Scalding burns were the most common(38.2%) and most burns were above deep second degree(94.1%). The most common seizure type was generalized tonic-clonic, followed by absence and complex partial. The seizure mostly occurred in the morning because the therapeutic blood level of antiepileptic drugs was decreased extremely at that time by stopping drug arbitrarily or taking inadequately. So more frequent follow-ups at the neurology outpatient clinics for epileptics should be strictly reinforced to maintain the adequate therapeutic blood levels of antiepileptic drugs and fire protective implements should be prepared in the house.

• Journal of Korea Technical Association of The Pulp and Paper Industry
• /
• v.42 no.3
• /
• pp.67-73
• /
• 2010

Pine (Pinus densiflora) and aspen (Populus euramericana) wood meals were treated with ozone at various time schedule in acidic condition. The lignin contents and surface area of the ozone treated wood meals were determined and the enzymatic hydrolysis rate of ozonated wood meals was evaluated. The feasibility of enzymatic hydrolysis of the ozone treated wood meal was obviously influenced with the degree of delignification. After ozone treatment of wood meal for 10min, total pore volume were slightly increased in the surface of wood meal. When wood meals were treated with ozone longer than 10min, few change in the pore volume was observed. However, the area of over $50{\AA}$ of pore size is increased with ozonation time. As a conclusion, the rate of enzymatic hydrolysis of wood is more effective with the pore size distribution than the total pore volume.