• Title/Summary/Keyword: degraded material

Search Result 368, Processing Time 0.028 seconds

Remediation of PCE-contaminated Groundwater Using Permeable Reactive Barrier System with M0M-Bentonite (MOM-Bentonite 투수성반응벽체를 이용한 PCE로 오염된 지하수의 정화)

  • Chung, Sung-Lae;Lee, Dal-Heui
    • Journal of Soil and Groundwater Environment
    • /
    • v.17 no.4
    • /
    • pp.73-80
    • /
    • 2012
  • The objectives of this research were to study the applicability and limitations of permeable reactive barrier (PRB) for the removal of tetrachloroethylene (PCE) from the groundwater. PRB column tests were conducted using reactive material with Moringa Oleifera Mass - Bentonite (Mom-Bentonite). Most of the PCE in the groundwater was degraded and/or captured (sorpted) in the zone containing activated material (MOM-Bentonite). The removal rate of PCE from the groundwater was 90% and 75% after 30 days and 180 days, respectively. The effect of micro-organisms on the long-term permeability and reactivity of the barrier is not well understood. MOM-Bentonite PRB system in this research has the potential to be developed into an environmentally and economically acceptable technology for the in situ remediation of PCE-contaminated groundwater.

A Study on the High Frequency Ultrasonic Attenuation Characterization in Artificially Aging Degraded 2.25Cr-1Mo Steel (2.25Cr-1Mo 강 인공 열화재의 고주파수 초음파 감쇠특성에 관한 연구)

  • Park, Ik-Keun;Park, Un-Su;Kim, Chung-Seok;Kim, Hyun-Mook;Kwun, Sook-In;Byeon, Jai-Won
    • Journal of the Korean Society for Nondestructive Testing
    • /
    • v.21 no.4
    • /
    • pp.439-445
    • /
    • 2001
  • The destructive method is reliable and widely used lot the estimation of material degradation but, it have time-consuming and a great difficulty in preparing specimens from in-service industrial facilities. Therefore, the estimation of degraded structural materials used at high temperature by nondestructive evaluation such as electric resistance method, replica method, Barkhausen noise method, electro-chemical method and ultrasonic method are strongly desired. Ultrasonic nondestructive evaluation technique has been reported good to attain efficiency of measurement, high sensitivity of measurement, and rapidity and reliability of result interpretation. In this study, it was verified experimentally the feasibility of the evaluation of degraded 2.25Cr-1Mo steel specimens which were prepared by the isothermal aging heat treatment at $630^{\circ}C$ by high frequency longitudinal wave method investigating the change of attenuation coefficient by FFT analysis and wavelet transform. Because of carbide precipitation increase and spheroidization near grain boundary of microstructure to aging degradation, attenuation coefficient had a tendency to increase as degradation proceeded. It was identified possibly to evaluate degradation using the characteristics of high-frequency ultrasonics. Frequency dependence of ultrasonic attenuation coefficient to aging degradation appeared large, which made sure that attenuation coefficient is an important parameter for evaluation of aging degradation.

  • PDF

Analysis of Thermal Degradation Mechanism by Infrared High-speed Heating of CF-PEKK Composites in Hot Press Forming (핫프레스 공정 기반 CF-PEKK 복합재의 근적외선 고속가열에 의한 열적 열화 반응의 메커니즘 분석)

  • Lee, Kyo-Moon;Park, Soo-Jeong;Park, Ye-Rim;Park, Seong-Jae;Kim, Yun-Hae
    • Composites Research
    • /
    • v.35 no.2
    • /
    • pp.93-97
    • /
    • 2022
  • The application of infrared heating in the hot press forming of the thermoplastic composites is conducive to productivity with high-speed heating. However, high energy, high forming temperature, and high-speed heating derived from infrared heating can cause material degradation and deteriorate properties such as re-melting performance. Therefore, this study was conducted to optimize the process conditions of the hot press forming suitable for carbon fiber reinforced polyetherketoneketone(CF/PEKK) composites that are actively researched and developed as high-performance aviation materials. Specifically, the degradation mechanisms and properties that may occur in infrared high-speed heating were evaluated through morphological and thermal characteristics analysis and mechanical performance tests. The degradation mechanism was analyzed through morphological investigation of the crystal structure of PEKK. As a result, the size of the spherulite decreased as the degradation progressed, and finally, the spherulite disappeared. In thermal characteristics, the melting temperature, crystallization temperature and heat of crystallization tend to decrease as degradation progresses, and the crystal structure disappeared under long-term exposure at 460℃. In addition, the low bonding strength was observed on the degraded surface, and the bonding surfaces of PEKK did not melt intermittently. In conclusion, it was confirmed that the CF/PEKK composite material degraded at 420℃ in the infrared high-speed heating. Furthermore, the spherulite experienced morphological changes and the re-melting properties of thermoplastic materials were degraded.

Degradation Evaluation of Mechanical Properties for 12Cr Ferrite Heat Resisting Steel by Reversible Permeability (가역투자율에 의한 12Cr 페라이트 내열강의 역학적 물성의 열화평가)

  • Ryu, Kwon-Sang;Kim, Min-Gi;Nahm, Seung-Hoon;Kim, Chung-Seok
    • Journal of the Korean Society for Nondestructive Testing
    • /
    • v.30 no.5
    • /
    • pp.464-470
    • /
    • 2010
  • The integrity of the industrial equipment in use under high temperature and high pressure must be assessed by regularly measuring the degraded mechanical properties during service time. In order to nondestructively monitor the degraded mechanical properties of industrial equipment, a measuring method of the reversible permeability(RP) using surface type probe is presented. The method for measuring the RP is based on that RP is the differential value of hysteresis loop. The RP is exactly the foundation hatmonics induced in a detecting coil measured by lock-in amplifier tuned to a frequency of the alternating perturbing magnetic field. The peak of RP is measured around the coercive force. Steel material used in this work was 12Cr ferritic heat resisting steel. The eleven kinds of samples aged during different times under same temperature ($700^{\circ}C$) were prepared. Peak interval of reversible permeability(PIRP), Vickers hardness, and tensile strength measured for the aged samples decreased abruptly for short aging time (below 500 h), but the change became small at a long aging time. Vickers hardness and tensile strength linearly decreased as RIRP decreased, so the degraded mechanical properties of 12Cr ferritic heat resisting steel could be nondestructively evaluated by measuring RIRP.

Evaluation of Material Degradation Using Electrical Resistivity Method (전기비저항법을 이용한 재료열화 평가)

  • Seok, Chang-Seong;Kim, Dong-Jung;Bae, Bong-Guk
    • Transactions of the Korean Society of Mechanical Engineers A
    • /
    • v.24 no.12
    • /
    • pp.2995-3002
    • /
    • 2000
  • The remaining life estimation for the aged components in power plants as well as chemical plants are very important beacuse mechanical properties of the components are degraded with time of service exposure in high temperature. Since it is difficult to take specimens from the operating components to evaluate mechanical properties of components nondestructive techniques are needed to estimate the degradation. In this study, test materials with 4 different degradation levels were prepared by isothermal aging heat treatment at 630$\^{C}$. And the DC potential drop method and destructive methods such as tensile, K(sub)IC and hardness tests were used in order to evaluate the degradation of 1-Cr-1Mo-0.25V steels. The objective of this study is to investigate the possibility of the application of DCPD method to estimated the material degradation, and to analyse the relationship between the electrical relationship between the electrical resistivity and the degree material degradation.

미세조류의 Methane 발효특성

  • 강창민;최명락
    • Microbiology and Biotechnology Letters
    • /
    • v.24 no.5
    • /
    • pp.597-603
    • /
    • 1996
  • This study was carried out to examine degradation characteristics of microalgae Chlorella vulgaris in methane fermentation. We measured COD and VS reduction, gas and methane productivity, VFA (volatile fatty acid), respectively. Then we calculated material balance and hydrolysis rates in soluble and solid material. The substrate concentration was controlled from 14 gCOD$_{cr}$/l to 64 gCOD$_{cr}$/l in batch cultures, and HRT (hydraulic retention time) controlled from 2 days to 30 days in continuous experi- ments. The results were as follows. In batch culture, accumulated gas productivity increased with the increase of the substrate concentration. The SS and VSS was removed all about 30% increase of substrate concentration and the most of the degradable material removed during the first 10 days. The curve of gas and methane production rate straightly increased until substrate concentration is 26 gCOD$_{cr}$/l. In continuous culture experiments, the removal rates at HRT 10days were 20% for total COD and TOC, respectively. At longer HRT, there was no increase in the removal efficiency. At HRT 15 days, the removal rates were 30% for SS and VSS, respectively. Soluble organic materials were rapidly degraded, and so there was no accumulated. Soluble COD concentration was not increase regardless of HRT-increasing. That meaned the hydrolysis was one of the rate-limiting stage of methane fermentation. The first-order rate constants of hydrolysis were 0.23-0.28 day$^{-1}$ for VSS, and 0.07-0.08 day$^{-1}$ for COD.

  • PDF

Estimation of Strength and Pore Structure of Alkali-Activated Fire Protection Materials at High Temperature (고온에서의 알칼리 활성화 내화성 결합재의 강도 및 공극구조 평가)

  • Song, Hun;Kim, Young-Ho;Kim, Wan-Ki;So, Hyung-Suk
    • Journal of The Korean Digital Architecture Interior Association
    • /
    • v.12 no.4
    • /
    • pp.59-66
    • /
    • 2012
  • This study is interested in identifying the effectiveness of alkali-activated fire protection material compounds including the alkali-activator such as potassium hydroxide, sodium silicate and fly ash as the fire resistant finishing materials. Also, this paper is concerned with change in compressive strength and pore structure of the alkali-activated fire protection material at high temperatures. The testing methods of fire protection materials in high temperature properties are make use of TG-DSC and mercury intrusion porosimetry measurements. This study results show that compressive strength is rapidly degraded depending on a rise of heating temperature. Porosity showed a tendency to increase irrespective of specimen types. This is due to both the outbreak of collapse of gel comprising the cement and a micro crack by heating. However, alkali-activated fire protection material composed of potassium hydroxide, sodium silicate and fly ash has the thermal stability of the slight decrease of compressive strength and porosity at high temperature. These thermal stability is caused by the ceramic binding capacity induced by alkali activation reaction by the reason of the thermal analysis result not showing the decomposition of calcium hydrate.

Various Factors Influencing the Lifetime of Suspension-Type Porcelain Insulators for 154 kV Power Transmission Lines

  • Choi, In Hyuk;Park, Joon Young;Kim, Tae Gyun;Yoon, Yong Beum;Yi, Junsin
    • Transactions on Electrical and Electronic Materials
    • /
    • v.18 no.3
    • /
    • pp.151-154
    • /
    • 2017
  • In this article, we investigated the various influencing factors that degraded the lifetime of suspension insulators in 154 kV transmission lines, and showed the possible solutions to avoid such breakdowns. With respect to achieve safety, reliability and aesthetical considerations, the characteristics of transmission and distribution network power cables should be improved. Suspension insulators are particularly important to study, as they have developed to be the main component of transmission lines due to their ability to withstand the electrical conductivity of high-voltage power transmission. Suspension insulators are mostly made from glass, rubber and ceramic material due to their high resistivity. In Korea, porcelain suspension insulators are typically used in the transmission line system, as they are cheaper and more flexible compared to other types of insulators. This is effective from preventing very high and steep lightening impulse voltages from causing the breakdown of suspension insulators used in power lines. Other influential factors affect the lifetime of suspension insulators that we studied include temperature, water moisture, contamination, mechanical vibration and electrical stress.

Seismic Fragility Analysis of Reinforced Concrete Shear Walls Considering Material Deterioration (재료의 열화를 고려한 철근콘크리트 전단벽의 지진 취약도 분석)

  • Myung Kue, Lee;Jang Ho, Park
    • Journal of the Korean Society of Safety
    • /
    • v.37 no.6
    • /
    • pp.81-88
    • /
    • 2022
  • It is necessary to better understand the effect of age-related degradation on the performance of reinforced concrete shear walls in nuclear power plants in order to ensure their structural safety in the event of earthquakes. Therefore, this paper studies seismic fragility of the typical shear wall in nuclear power plants under earthquake excitation Reinforced concrete shear wall is composed of wall, horizontal and vertical flanges. Due to characteristics of its geometry, it is difficult to predict the ultimate behavior of shear wall under earthquake excitation. In this study, for more realistic numerical simulation, the Latin Hyper-Cube (LHC) simulation technique was used to generate uncertain variables for the material properties of concrete shear walls. The effects of crack, characteristics of inelastic behavior of concrete, and loss of cross section were considered in the nonlinear finite element analysis. The effects of aging-related deterioration were investigated on the performance of reinforced concrete shear walls through analysis of undegraded concrete shear walls and degraded concrete shear walls. The resulting seismic fragility curves present the change of performance of concrete shear wall due to age-related degradation.

Degradation Mechanism of MoxW1-xSi2 Heating Elements Fabricated by SHS Process (SHS 공정에 의해 제조된 MoxW1-xSi2 발열체의 열화메커니즘)

  • Lee, Dong-Won;Lee, Sang-Hun;Kim, Yong-Nam;Lee, Sung-Chul;Koo, Sang-Mo;Oh, Jong-Min
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • v.30 no.10
    • /
    • pp.631-636
    • /
    • 2017
  • The degradation mechanism of $Mo_xW_{1-x}Si_2$ ultrahigh-temperature heating elements fabricated by self-propagating high-temperature synthesiswas investigated. The $Mo_xW_{1-x}Si_2$ specimens (with and without post-annealing) were subjected to ADTs (accelerated degradation tests) at temperatures up to $1,700^{\circ}C$ at heating rates of 3, 4, 5, 7, and $14^{\circ}C/min$. The surface loads of all the specimen heaters were increased with the increase in the target temperature. For the $Mo_xW_{1-x}Si_2$ specimens without annealing, many pores and secondary-phase particles were observed in the microstructure; the surface load increased to $23.9W/cm^2$ at $1,700^{\circ}C$, while the bending strength drastically reduced to 242 MPa. In contrast, the $Mo_xW_{1-x}Si_2$ specimens after post-annealing retained $single-Mo_xW_{1-x}Si_2$ phases and showed superior durability after the ADT. Consequently, it is thought that the formation of microcracks and coarse secondary phases during the ADT are the main causes for the degraded performance of the $Mo_xW_{1-x}Si_2$ heating elements without post-annealing.