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Degradation of Chlorinated Hydrocarbons via a Light-Emitting Diode Derived Photocatalyst

  • Jo, Wan-Kuen;Lee, Joon Yeob
    • Environmental Engineering Research
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    • v.18 no.1
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    • pp.21-28
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    • 2013
  • In this study, the applicability of visible light-emitting-diodes (LEDs) to the photocatalytic degradation of indoor-level trichloroethylene (TCE) and perchloroethylene (PCE) over N-doped $TiO_2$ (N-$TiO_2$) was examined under a range of operational conditions. The N-$TiO_2$ photocatalyst was calcined at $650^{\circ}C$ (labeled N-650) showed the lowest degradation efficiencies for TCE and PCE, while the N-$TiO_2$ photocatalysts calcined at $350^{\circ}C$, $450^{\circ}C$, and $550^{\circ}C$ (labeled as N-350, N-450, and N-550, respectively) exhibited similar or slightly different degradation efficiencies to those of TCE and PCE. These results were supported by the X-ray diffraction patterns of N-350, N-450, N-550, and N-650. The respective average degradation efficiencies for TCE and PCE were 96% and 77% for the 8-W lamp/N-$TiO_2$ system, 32% and 20% for the violet LED/N-$TiO_2$ system, and ~0% and 4% for the blue LED/N-$TiO_2$ system. However, the normalized photocatalytic degradation efficiencies for TCE and PCE for the violet LED-irradiated N-$TiO_2$ system were higher than those from the 8-W fluorescent daylight lamp-irradiated N-$TiO_2$ system. Although the difference was not substantial, the degradation efficiencies exhibited a decreasing trend with increasing input concentrations. The degradation efficiencies for TCE and PCE decreased with increasing air flow rates. In general, the degradation efficiencies for both target compounds decreased as relative humidity increased. Consequently, it was indicated that violet LEDs can be utilized as energy-efficient light sources for the photocatalytic degradation of TCE and PCE, if operational conditions of N-$TiO_2$ photocatalytic system are optimized.

A Study on Improving the Utilization of Biotope Area Ratio System Considering the Plant Growth Conditions (작물 생장조건을 고려한 생태면적률 제도 개선 방향)

  • Lee, Gunwon;Jeong, Yunnam;Ji, Seongkyun;Kim, Seiyong
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.16 no.2
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    • pp.1490-1499
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    • 2015
  • The purpose of this study is to improve Biotope Area Ratio(BAR) systems used in the various fields. Recently, there has been increasing demand in urban agriculture as well as more residents cultivating farms on a small scale. However, there are few measures in terms of architecture and urban planning to respond to this trend. In this sense, this research is effective as it can respond to these demands by using BAR systems. Yet, the environmental indexes are not enough since BAR systems only take account of vegetation. Therefore, this study proposes an alternative way that includes the capacity factor of the plant growth by expanding the existing BAR systems. Thus, the study analyzes the complementary possibility of BAR systems, including elements of daylight, planting interval, area and soil depth with existing BAR elements.

SDN-Based Packet-Forwarding and Delay Minimization Algorithm for Efficient Utilization of Network Resources and Delay Minimization (네트워크 자원의 효율적인 사용과 지연을 최소화하기 위한 SDN 기반 서비스별 패킷 전송 및 지연 최소화 알고리즘)

  • Son, Jaehyeok;Hong, ChoongSeon
    • KIISE Transactions on Computing Practices
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    • v.21 no.11
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    • pp.727-732
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    • 2015
  • These days, many researchers are working on Future Internet and a new networking paradigm called Software Defined Networking draws a great attention. In this paper, we redefine Software Defined Networking as Service Defined Networking which means that packets are categorized according to types of services. By using Service Defined Networking, we are not only dealing with the way to utilize the network resources efficiently but we also propose an algorithm to minimize the waiting time for packets to be delivered. This proposed algorithm can solve the delay problem, one of the most significant problems caused by network congestion. Also, since we are adopting Service Defined Networking, network resource utilization can be improved compared to the existing network.

Characteristic of Termite inhabits in South Korea and the control (한국 서식 흰개미의 특성과 방제)

  • Han, Sung-Hee;Lee, Kyu-Shik;Chung, Young-Jae
    • 보존과학연구
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    • s.19
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    • pp.133-158
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    • 1998
  • There are about 2,000 species of termite in the World, but one species of termite inhabits in the southern part of Korean peninsula. Termites are social insects that live in colonies. The colonies are composed of king, queen, soldiers and workers. Termite food consists of cellulose obtained from wood. Protozoa in their digestive tracts convert the cellulose into usable food. Korean termite is a subspecies of Reticulitermes speratus Kolbe, Rhinotermitidae. It's subterranean termite and the scientic name is R. speratus kyushensis Morimoto. The subterranean termite must nest in the soil in order to survival, and infest soft-wood which contact with the soil near the nest. There are several ways which subterranean termite infestations can be noticed. Atcertain times of the year during daylight hours, king and queen termites emerge from the colonies. The propose of these flight is to establish new colonies. The termite is a decomposer of biological ecosystem, but an invader in the preservation of cultural properties as like wood buildings. There are serveral control methods for the prevention of wood building from termite's damages. Those are biological control, ecological control, physical control and chemical control. Ecological and Physical control are the best methods in the new constructing wood-building. Fumigation which is a method of chemical control, is the best method for the building damaged by the termite. After the fumigation, we have totake wood & soil treatments for the building and nearby in order not to be reinvaded by the termites.

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Retouching Method for Watercolor Painting Effect Using Mean Shift Segmentation (Mean Shift Segmentation을 이용한 수채화 효과 생성 기법)

  • Lee, Sang-Geol;Kim, Cheol-Ki;Cha, Eui-Young
    • Journal of the Korea Society of Computer and Information
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    • v.15 no.9
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    • pp.25-33
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    • 2010
  • We propose a retouching method that converts a general photography to a watercolor painting image using bilateral filtering and mean shift segmentation which are mostly used in image processing. The first step is to weaken high frequency components of the image, while preserving the edge of image using the bilateral filtering. And after that we perform DoG(Difference of Gradient) edge extraction and mean shift segmentation respectively from the bilateral filtered image. The DoG edge extraction is performed using luminance component of the image whose RGB color space is transformed into CIELAB space. Experimental result shows that our method can be applied to various types of image and bring better result, especially against the photo taken in daylight.

Cleaning Fabricated Metal Thread: A Post-treatment Stability Assessment after Artificial Deterioration and the Application of Synthetic Soil

  • Park, Hae Jin;Hwang, Minsun;Chung, Yong Jae
    • Journal of Conservation Science
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    • v.35 no.1
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    • pp.19-31
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    • 2019
  • To study the cleaning effects and post-treatment stability assessment of various methods of cleaning textiles with metal thread, six naturally-soiled historical textiles with metal thread were investigated at the Metropolitan Museum of Art, New York. Prior to the cleaning of fabricated gold, silver, and copper thread that had been glued onto a paper substrate, the artificial deterioration was carried out in a controlled environment with light(UV and daylight), and temperature and humidity factors which would weaken and damage the samples. A synthetic soil mixture was applied to the samples to imitate soil found on the historic and archaeological textiles with metal thread; the cleaning effect and post-treatment assessment were investigated by use of three textile cleaning methods: mechanical cleaning, wet cleaning, and solvent cleaning. While investigating the naturally-soiled textiles with metal thread, it was determined that the soil colors and sizes of contaminating particles of each textile were different due to the diversity of original environmental factors and conditions. After cleaning with kneaded rubber, Stoddard solvent, n-decane or n-hexane, a bright, clean effect was apparent. Kneaded rubber was successful in picking up both large and small particles, but its stickiness caused some of the metal leaf to peel off. Stoddard solvent produced a good cleaning effect, but after use of n-hexane and n-decane in the cleaning process, a white layer of residue remained on the textile's surface. Wet cleaning was not effective and the rapid humidity changes between wet and dry conditions caused the edges of the paper substrate to lose their original shape.

The First Skyscraper Revisited

  • Ali, Mir M.;Moon, Kyoung Sun
    • International Journal of High-Rise Buildings
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    • v.11 no.1
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    • pp.1-14
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    • 2022
  • Debates on what is the first skyscraper have been ongoing from time to time since the construction of the Home Insurance Building in Chicago in 1885, which is generally recognized as the first built skyscraper. This paper attempts to verify this assertion through a detailed investigation after identifying the criteria that characterize a skyscraper. By considering and examining several competing buildings for the title of "first skyscraper" in terms of their levels of satisfying these criteria, the paper reconfirms that the Home Insurance Building in Chicago indeed qualifies as the first skyscraper and is the harbinger of future skyscrapers. By introducing technological and associated architectural innovations in this pioneering building, its designer William Le Baron Jenney paved the way for the construction of future skyscrapers. In traditional construction, heavy masonry walls especially at lower levels did not allow large window openings in exterior walls that would permit ample daylight. For the Home Insurance Building, originally built with 10 stories, Jenney created a metal-framed skeletal structure that carried the building's loads, making the building lighter and allowed for large windows permitting ample natural light to the building's interior. The exterior iron columns were encased in relatively small masonry piers mainly for fireproofing, weather-protection and façade aesthetics. Relying on the structural framing on the building's perimeter, the exterior masonry thus turned into a rudimentary "curtain wall" system, heralding the use of curtain wall construction in future skyscrapers. This building's innovative structural system led to what is known as the "Chicago Skeleton," and eventually produced remarkable skyscrapers all over the world.

Evaluation of applicability of pan coefficient estimation method by multiple linear regression analysis (다변량 선형회귀분석을 이용한 증발접시계수 산정방법 적용성 검토)

  • Rim, Chang-Soo
    • Journal of Korea Water Resources Association
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    • v.55 no.3
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    • pp.229-243
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    • 2022
  • The effects of monthly meteorological data measured at 11 stations in South Korea on pan coefficient were analyzed to develop the four types of multiple linear regression models for estimating pan coefficients. To evaluate the applicability of developed models, the models were compared with six previous models. Pan coefficients were most affected by air temperature for January, February, March, July, November and December, and by solar radiation for other months. On the whole, for 12 months of the year, the effects of wind speed and relative humidity on pan coefficient were less significant, compared with those of air temperature and solar radiation. For all meteorological stations and months, the model developed by applying 5 independent variables (wind speed, relative humidity, air temperature, ratio of sunshine duration and daylight duration, and solar radiation) for each station was the most effective for evaporation estimation. The model validation results indicate that the multiple linear regression models can be applied to some particular stations and months.

Functional graphene sheets-TiO2 nanocomposites and their photocatalytic performance for wastewater treatment

  • R. Aitbelale;A. Timesli;A. Sahibed-dine
    • Advances in nano research
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    • v.15 no.4
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    • pp.295-304
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    • 2023
  • In this paper, a powerful photocatalyst based on carbon nanocomposite is developed in order to obtain a new material applicable in water treatment and especially for the discoloration of effluents used in the textile industry. For that, TiO2-graphene nanocomposites have been successfully synthesized by a mixture of Functionalized Graphene Sheet (FGS) and tetrachlorotitanium complexes to form FGS-TiO2 nanocomposite. In the presence of an anionic surfactant, we used a new chemical process to functionalize graphene sheets in order to make them an excellent medium for blocking and preventing the aggregation of TiO2 nanoparticles. The components of these nanocomposites are characterized by means of X-ray diffraction (XRD), Fourier Transform Infrared Spectroscopy (FT-IR), Scanning Electron Microscopy (SEM) and Transmission Electron Microscopy (TEM), which confirms the successful formation of the FGS-TiO2 nanocomposite. It was found that the TiO2 nanoparticles were dispersed uniformly on the graphene plane which possesses better charge separation capability than pure TiO2. The FGS-TiO2 nanocomposites exhibited higher photocatalytic activity compared to pure TiO2 for the removal of three dyes: such as Methylene Blue (MB), Bromophenol Blue (BB) and Alizarin Red-S (AR) in water. The removal process was fast and more efficient with FGS-TiO2 nanocomposite in daylight (in the absence of UV irradiation) compared to pure TiO2 nanoparticles without and under UV in all pH range.

Survey the Occurrences and Establishment of Environment-friendly Control System of Ricania shanthungensis in Jeonnam Province (전남지역 갈색날개매미충 발생현황과 친환경 방제)

  • Choi, Duck-Soo;Ma, Kyung-Cheol;Kim, Hyo-Jeong;Lee, Jin-Hee;Oh, Sang-A;Kim, Seon-Gon
    • Korean Journal of Organic Agriculture
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    • v.26 no.3
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    • pp.439-452
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    • 2018
  • This study was carried out to establish of environment-friendly control system and to survey the occurrence status of Ricania shanthungensis in Jeonnam province from 2016 to 2017. R. shanthungensis occurred at 1,344 ha in 61 towns of 15 cities in Gwangju and Jeonnam province. At four sites in the stationary area, the densities of eggmass and pupae were lower in 2017 than in 2016, the hatching rate decreased, and the first hatching time, emergence of adults, and the start of spawning tended to be slower. Telenomus sp., an egg parasitoid of R. shanthungensis, was found in most areas. Sunchon had the highest rate of 46.1%, followed by Muan 40.6, Goksung 29.2, Gurye 25.8, and Gwangju 17, respectively. The optimum spraying time for the control of R. shanthungensis was early March. The spraying material and the dilution multiples are 10 times of the machine oil at environmental friendly cultivation and 500 times of the chlorpriphosphate wp. at normal cultivation. When sprayed these materials, 95% of egg prohibited to hatch. There was more than 80% of the insecticidal effects on the organic materials of the machine oil emulsion, the Sophora root extrect + microbial extract agent, and the castor emulsion. For adults, Sophora root extrect + microbial extract, neem extract, and machine oil were better. Four kinds of chemical pesticides such as dinotefuran wp were effective for nymph and adult control. We have developed an adult catching device using the most preferred daylight color and behavioral habits of R. shanthungensis. The capture device consisted of two daylight compact lamps (30W and 20W), a yellow plate, and a catcher using water, and caught about 700 individuals a day. Based on the above results, we have established a system for controlling and life cycle of R. shanthungensis in Jeonnam province.