• Title/Summary/Keyword: dP/dt

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Preparation of Metal Hydrides Using Chemical Synthesis and Hydriding Kinetics (화학적 합성법에 의한 금속수소화물의 제조 및 수소화 속도론적 연구)

  • Lee, Yun Sung;Oh, Jae Wan;Moon, Sung Sik;Nahm, Kee Suk
    • Applied Chemistry for Engineering
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    • v.9 no.2
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    • pp.255-260
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    • 1998
  • Metal hydrides, $LaNi_5$ and $LaNi_{4.5}Al_{0.5}$, were prepared using chemical synthetic method, and their physical properties were examined using various analytic techniques such as TGA, XRD, SEM and EDX. The activation of the chemically prepared $LaNi_5$ and $LaNi_{4.5}Al_{0.5}$ was achieved by two hydriding/dehydriding cycles only. The miasurements of P-C-T curves revealed that 6 and 5.5 hydrogen atoms were stored in LaNi5and $LaNi_{4.5}Al_{0.5}$, respectively. The hydriding reaction rated for $LaNi_{4.5}Al_{0.5}$ were measured by the method of initial rates. It was found that the shrinking unreacted core model could be applied for the analysis of hydriding kinetics of $LaNi_5$. The rate controlling step of this reaction was the dissociative chemisorption of hydrogen molecules on the surface of $LaNi_5$. The activation energy was $9.506kcal/mol-H_2$. The rates measured in the temperature range from 273 to 343K and in pressure difference ($P_o-P_{eq}$) range form 0.25 to 0.66atm could be expressed as the following equation ; $\frac{dX}{dt}=4.636(P_o-P_{eq})$ exp($\frac{-9506}{RT}$).

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Fabrication of 5,000V, 4-Inch Light Triggered Thyristor using Boron Diffusion Process and its Characterization (Boron 확산공정을 이용한 5,000V, 4인치 광 사이리스터의 제작 및 특성 평가)

  • Park, Kun-Sik;Cho, Doohyung;Won, Jongil;Lee, Byungha;Bae, Youngseok;Koo, Insu
    • The Transactions of the Korean Institute of Power Electronics
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    • v.24 no.6
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    • pp.411-418
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    • 2019
  • Light-triggered thyristors (LTTs) are essential components in high-power applications, such as HVDC transmission and several pulsed-power applications. Generally, LTT fabrication includes a deep diffusion of aluminum as a p-type dopant to form a uniform p-base region, which needs careful concern for contamination and additional facilities in silicon semiconductor manufacturing factories. We fabricated 4-inch 5,000 V LTTs with boron implantation and diffusion process as a p-type dopant. The LTT contains a main cathode region, edge termination designed with a variation of lateral doping, breakover diode, integrated resistor, photosensitive area, and dV/dt protection region. The doping concentration of each region was adjusted with different doses of boron ion implantation. The fabricated LTTs showed good light triggering characteristics for a light pulse of 905 nm and a blocking voltage (VDRM) of 6,500 V. They drove an average on-state current (ITAVM) of 2,270 A, peak nonrepetitive surge current (ITSM) of 61 kA, critical rate of rise of on-state current (di/dt) of 1,010 A/㎲, and limiting load integral (I2T) of 17 MA2s without damage to the device.

Effects of Some Environmental Factors on the Germination of Seeds in Ambrosia artemisiifolia var. elatior (몇가지 환경요인이 돼지풀의 종자발아에 미치는 영향)

  • 김종홍;김원희;차승희
    • The Korean Journal of Ecology
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    • v.25 no.2
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    • pp.93-100
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    • 2002
  • In order to analyze the life cycle of A. artemisiifolia var. elation dormancy and some environmental factors inducing germination of the seeds were examined. The results were as follows : Dormancy of fertile seeds was broken in part within a month after seed collection in case of adequate moisture and alternating temperature was also effective in breaking dormancy. The temperature range, which allow germination was 12℃ ∼ 32℃. Optimum temperature for germination was 24℃. The seed of A. artemisiifolia var. elatior was light-independent. The difference of storage period appeared to have no particular effect on the viability of seeds at any time during the 9-month storage period. In the increasing temperature(IT) regime, A artemisiifolia var. elatior seeds started to germinate at 16℃, showing the higher temperature the greater germination rate, the final germination percentage was 99.34%. On the other hand, in the decresing temperature(DT) regime, seeds began to germinate at 20℃ with the 1.34% germination. An induced dormancy occurred at 12℃ making the 5.34% fecal germination in the DT regime. Low temperature was more effective to break dormancy than higher temperature Seeds of A. artemisiifolia var. elatior seems to be germinated in mid to late autumn or germination delayed until following spring. The above results suggest these variation of germination response in diverse environmental factors seems to be a physiological strategy to maintain their existence and to reproduce in the extreme thermal variation.

Device Feature and Application Status for Light Triggering Thyristor(LTT) in HVDC Transmission (HVDC 송전용 광구동 사이리스터(LTT)를 위한 소자특성 및 응용의 요구)

  • Zhang, C.L.;Kim, S.C.;Kim, E.D.;Kim, H.W.;Seo, K.S.;Bhang, W.;Cheong, K.Y.;Kim, N.K.;Luo, J.Q.;Bai, J.B.;Wang, X.B.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.07a
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    • pp.397-400
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    • 2004
  • The design concept for 8kV light triggering thyristor(LTT) with integrated BOD was discussed here in detail. The trade-off between light triggering input source againsthigh dV/dt limitation has been treated via grooved P-base for gate design. The main application point used for high voltage DC transmission(HVDC) was represented.

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Effect of ischemic preconditioning on left ventricular function after cardiac arrest in isoated rat heart (적출 쥐 심장에서 허혈성 전조건화가 심정지후 좌심실 기능에 미치는 영향)

  • 조대윤
    • Journal of Chest Surgery
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    • v.27 no.7
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    • pp.563-570
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    • 1994
  • Effect of ischemic preconditioning on left ventricular function after cardiac arrest in isolated rat heart.Ischemic preconditioning reduces infarct size caused by sustained ischemia. However, the effects of preconditioning on post ischemic cardiac function are not well-known. The objective of the present study was to determine whether preconditioning would improve the recovery of left ventricular functions after cardiac arrest in isolated rat heart model.Isolated rat hearts were allowed to equilibrate for 20 minutes and were then subjected to either 5 minutes of global, normothermic transient ischemia [Group 2 and 4] or not [Group 3]. A stabilization period of perfusion lasting 5 minutes after the termination of transient ischemia was followed by a standard global, normothermic 20 minute-ischemia and 35-minute reperfusion challenge [Group 3 and 4]. These following results were odtained.1. The recovery of left ventricular developed pressures showed no significant differences between Group 3 and Group 4 at 50 [P>0.3] and 85 minute [P>0.2].2. Heart rates showed no significant differences throughout all the course of experiment and between groups [P>0.5].3. The recovery of left ventricular maximum dP/dt showed no significant differences between Group 3 and Group 4 at 50 [P>0.1] and 85 minute [P>0.2].4. The recovery of pressure-rate products showed no significant differences between Group3 and Group 4 at 50 [P>0.5] and 85 minute [P>0.1].These results suggest that ischemic preconditioning does not provide significant benefit for the postischemic left ventricular functions in isolated rat hearts.

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Relative Genetic Effects of Duroc and Taoyuan Breeds on the Economic Traits of Their Hybrids

  • Yen, N.T.;Tai, C.;Cheng, Y.S.;Huang, M.C.
    • Asian-Australasian Journal of Animal Sciences
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    • v.14 no.4
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    • pp.447-454
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    • 2001
  • For determining the relative genetic effects of Duroc (D) and Taoyuan (T) breeds on the economic traits of their hybrids, 72 litters of pigs, from four mating types, namely TT (T♂$\times$T♀), DD (D♂$\times$D♀) and D-T hybrids (TD, T♂$\times$D♀ and DT, D♂$\times$T♀) were used in this study. The various crossbreeding parameters were estimated by comparisons among mating types using linear contrasts of least-square analysis. The results of reproductive traits analysis showed that T breed had contributed superior genetic effects on the total number of piglets at birth (TBN) (p<0.10) and number of live piglets at 21 days (LP21) (p<0.05) to the D-T hybrids. Estimates of maternal genetic effects showed that the T females were superior in TBN (p<0.05), but inferior in average birth weight (ABW) and average litter birth weight (LBW) (p<0.01) to the D females. Direct heterosis effects were significant for LBW, LP21 and LWT21 (p<0.01). Least-squares analysis of other economic traits showed that T breed had relative negative effects on all growth traits, withers height (WH), body type index (BTI), average backfat thickness (ABF), carcass length (LENG), loin eye area (longissimus) (LEARA), and lean percentage (LEAN) of D-T hybrids (p<0.05). Estimates of direct genetic effects showed that the D breed was superior to the T breed in all growth and carcass traits except the average backfat (BF). Estimates of maternal genetic effects showed that average body weight at 180 days (WT180) of progenies from T sows were lighter than from D sows. Progenies from D females had larger and leaner carcass than those from T females. Direct heterosis effects were significant for average daily weight gains from 150 to 180 days ($ADG_{150-180}$) (p<0.05) and for average body weights at 150 (WT150), and 180 days (WT180), average daily weight gains from birth to 150 and 180 days ($ADG_{150}$ and $ADG_{180}$, respectively), WH, body length (BL), ABF, BTI, and LENG (p<0.01). The results showed that D-T hybrids tended to have superior TBN and LP21 than D breed, and to be superior in all growth and most conformation and carcass traits to the T breed.

SOLVABILITY OF A THIRD ORDER NONLINEAR NEUTRAL DELAY DIFFERENTIAL EQUATION

  • Liu, Zeqing;Wang, Wei;Park, Jong Seo;Kang, Shin Min
    • Journal of the Chungcheong Mathematical Society
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    • v.23 no.3
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    • pp.443-452
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    • 2010
  • This work deals with the existence of uncountably many bounded positive solutions for the third order nonlinear neutral delay differential equation $$\frac{d^3}{dt^3}[x(t)+p(t)x(t-{\tau})]+f(t,x(t-{{\tau}_1}),{\ldots},x(t-{{\tau}_k}))=0,\;t{\geq}t_0$$ where ${\tau}>0$, ${\tau}_i{\in}{\mathbb{R}^+}$ for $i{\in}\{1,2,{\ldots},k\}$, $p{\in}C([t_0,+{\infty}),{\mathbb{R}^+})$ and $f{\in}C([t_0,+{\infty}){\times}{\mathbb{R}^k},{\mathbb{R}})$.

Characteristics of Dust Explosion in Dioctyl Terephthalic Acid Manufacturing Process (디옥틸테레프탈산 제조공정에서 분진폭발 특성에 관한 연구)

  • Lee, Chang Jin;Kim, Lae Hyun
    • Korean Chemical Engineering Research
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    • v.57 no.6
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    • pp.790-803
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    • 2019
  • The dioctyl terephthalic acid (DOTP) process produces plastic plasticizers by esterification of terephthalic acid with powder in the form of octanol. In this study, the dust explosion characteristics of terephthalic acid directly injected into the manhole in the form of powder in the presence of flammable solvent or vapor in the reactor of this process were investigated. Dust particle size and particle size distribution dust characteristics were investigated, and pyrolysis characteristics of dust were investigated to estimate fire and explosion characteristics and ignition temperature. Also, the minimum ignition energy experiment was performed to evaluate the explosion sensitivity. As a result, the average particle size of terephthalic acid powder was $143.433{\mu}m$. From the thermal analysis carried out under these particle size and particle size distribution conditions, the ignition temperature of the dust was about $253^{\circ}C$. The lower explosive limit (LEL) of the terephthalic acid was determined to be $50g/m^3$. The minimum ignition energy (MIE) for explosion sensitivity is (10 < MIE < 300) mJ, and the estimated minimum ignition energy (Es) based on the ignition probability is 210 mJ. The maximum explosion pressure ($P_{max}$) and the maximum explosion pressure rise rate $({\frac{dP}{dt}})_{max}$ of terephthalic acid dust were 7.1 bar and 511 bar/s, respectively. The dust explosion index (Kst) was 139 mbar/s, corresponding to the dust explosion grade St 1.

Highly Efficient Biotransformation of Notoginsenoside R1 into Ginsenoside Rg1 by Dictyoglomus thermophilum β-xylosidase Xln-DT

  • Li, Qi;Wang, Lei;Fang, Xianying;Zhao, Linguo
    • Journal of Microbiology and Biotechnology
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    • v.32 no.4
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    • pp.447-457
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    • 2022
  • Notoginsenoside R1 and ginsenoside Rg1 are the main active ingredients of Panax notoginseng, exhibiting anti-fatigue, anti-tumor, anti-inflammatory, and other activities. In a previous study, a GH39 β-xylosidase Xln-DT was responsible for the bioconversion of saponin, a natural active substance with a xylose group, with high selectivity for cleaving the outer xylose moiety of notoginsenoside R1 at the C-6 position, producing ginsenoside Rg1 with potent anti-fatigue activity. The optimal bioconversion temperature, pH, and enzyme dosage were obtained by optimizing the transformation conditions. Under optimal conditions (pH 6.0, 75℃, enzyme dosage 1.0 U/ml), 1.0 g/l of notoginsenoside R1 was converted into 0.86 g/l of ginsenoside Rg1 within 30 min, with a molar conversion rate of approximately 100%. Furthermore, the in vivo anti-fatigue activity of notoginsenoside R1 and ginsenoside Rg1 were compared using a suitable rat model. Compared with the control group, the forced swimming time to exhaustion was prolonged in mice by 17.3% in the Rg1 high group (20 mg/kg·d). Additionally, the levels of hepatic glycogen (69.9-83.3% increase) and muscle glycogen (36.9-93.6% increase) were increased. In the Rg1 group, hemoglobin levels were also distinctly increased by treatment concentrations. Our findings indicate that treatment with ginsenoside Rg1 enhances the anti-fatigue effects. In this study, we reveal a GH39 β-xylosidase displaying excellent hydrolytic activity to produce ginsenoside Rg1 in the pharmaceutical and food industries.

New techniques for estimating the shut-in pressure in hydro-fracturing pressure-time curves

  • Choi Sung O.
    • 한국지구물리탐사학회:학술대회논문집
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    • 2003.11a
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    • pp.272-280
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    • 2003
  • A definite shut-in pressure in hydraulic fracturing techniques is needed for obtaining the correct information on the in-situ stress regimes in rock masses. The relation between the behaviour of hydraulically induced fractures and the condition of remote stress is considered to be major reasons of an ambiguous shut-in pressure in hydraulic fracturing pressure-time history curves. This paper describes the results of a series of numerical analyses carried out using UDEC(Universal Distinct Element Code, Itasca), which is based on the discrete element method, to compare several methods for determining the shut-in pressure during hydraulic fracturing. The fully coupling of hydraulic and mechanical analysis was applied, and the effects of four different discontinuity geometries in numerical modelling have been investigated for this purpose. The effects of different remote stress regimes and different physical properties on hydraulic fracture propagation have been also analyzed. Several methods for obtaining shut-in pressure from the ambiguous shut-in curves have been applied to all the numerical models. The graphical intersection methods, such as (P vs. t) method, (P vs. log(t)) method, (log(P) vs. log(t)) method, give smaller values of the shut-in pressure than the statistical method, (dP/dt vs. P). Care should be taken in selecting a method for shut-in pressure, because there can be existed a stress anomaly around the wellbore and fracturing from the wellbore by a constant flow rate may have a more complicate mechanism.

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