• Title/Summary/Keyword: d-Spacing

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Preparation of Exfoliated PCL/Clay Nanocomposite and Its Characterization (박리형 PCL/Clay 나노복합재료 제조와 특성)

  • 유성구;박대연;배광수;서길수
    • Polymer(Korea)
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    • v.25 no.3
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    • pp.421-426
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    • 2001
  • 11-Aminododecanoic acid, to insert the functional group of -COOH reacted with the end group of poly($\varepsilon$-caprolactone) diol, and cetyltrimethylammonium bromide (CTMA), to increase the d-spacing of Montmorillonite (MMT), were intercalated into $Na^+;_-$MMT. The modified MMT was reacted with poly(${varepsilon}-caprolactone$) diol ($M_n{=2000$) in THF solution at $80^{\circ}C$ for 4 hrs. After reaction, poly(${varepsilon}-caprolactone$) ($M_n{=80000$) was mixed into the solution for 12 hrs. To prepare the PCL/clay nanocomposite film this solution was cast into the silicon mold at $60^{\circ}C$ in vacuum oven for 6 hrs. From the results of XRD and TEM, it was found that the exfoliated PCL/clay nanocomposite were prepared. The effects of the amount of MMT on the mechanical properties and thermal properties of PCL/clay nanocomposites have been investigated by tensile tester and DSC. Because the MMT was dispersed homogeneously in PCL matrix, the Young's modulus of the nanocomposite were found to be excellent. However, MMT dispersed in PCL matrix had almost no effect on the tensile strength of the composites. The crystallization temperature of PCL increased in proportion to 3 wt% MMT in the PCL matrix.

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Fourier Domain Optical Coherence Tomography for Retinal Imaging with 800-nm Swept Source: Real-time Resampling in k-domain

  • Lee, Sang-Won;Song, Hyun-Woo;Kim, Bong-Kyu;Jung, Moon-Youn;Kim, Seung-Hwan;Cho, Jae-Du;Kim, Chang-Seok
    • Journal of the Optical Society of Korea
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    • v.15 no.3
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    • pp.293-299
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    • 2011
  • In this study, we demonstrated Fourier-domain/swept-source optical coherence tomography (FD/SS-OCT) at a center wavelength of 800 nm for in vivo human retinal imaging. A wavelength-swept source was constructed with a semiconductor optical amplifier, a fiber Fabry-Perot tunable filter, isolators, and a fiber coupler in a ring cavity. Our swept source produced a laser output with a tuning range of 42 nm (779 to 821 nm) and an average power of 3.9 mW. The wavelength-swept speed in this configuration with bidirectionality is 2,000 axial scans per second. In addition, we suggested a modified zero-crossing method to achieve equal sample spacing in the wavenumber (k) domain and to increase the image depth range. FD/SS-OCT has a sensitivity of ~89.7 dB and an axial resolution of 10.4 ${\mu}m$ in air. When a retinal image with 2,000 A-lines/frame is obtained, an acquisition speed of 2.0 fps is achieved.

Organic/inorganic Hybrid Electrolytes for the Application of Direct Methanol Fuel Cell (DMFC) - Preparation and Properties of Sulfonated SEBS (SSEBS)-clay Hybrid Membranes - (직접메탄올 연료전지용 유무기 하이브리드 전해질 - 술폰화된 SEBS (SSEBS)-clay 하이브리드 막의 제조 및 물성 -)

  • Nam Sang Yong;Park Byung-Kil;Kong Sung-Ho;Kim Young Jin
    • Membrane Journal
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    • v.15 no.2
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    • pp.165-174
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    • 2005
  • Sulfonated poly(styrene-ethylene-butadiene-styrene) (SSEBS)-clay hybrid membranes were prepared by solution method. In the preparation of hybrid membrane, the amount of clay content was fixed to 5 phr and montmorillonite (MMT) was fully exfoliated by the SEBS and it was confirmed by X-ray diffraction method. D-spacing of the characteristic peak from MMT plate in WAXD was fully diminished. Gas permeability, mechanical properties and thermal properties of the SSEBS-clay hybrid membranes were investigated. Gas permeability through the SSEBS-clay hybrid membranes decreased due to increased tortuosity made by exfoliation of clay in SEBS.

Nonlinear analysis of reinforced concrete beams strengthened with polymer composites

  • Pendhari, S.S.;Kant, T.;Desai, Y.M.
    • Structural Engineering and Mechanics
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    • v.24 no.1
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    • pp.1-18
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    • 2006
  • Strengthening of existing old structures has traditionally been accomplished by using conventional materials and techniques, viz., externally bonded steel plates, steel or concrete jackets, etc. Alternatively, fibre reinforced polymer composite (FRPC) products started being used to overcome problems associated with conventional materials in the mid 1950s because of their favourable engineering properties. Effectiveness of FRPC materials has been demonstrated through extensive experimental research throughout the world in the last two decades. However there is a need to use refined analytical tools to simulate response of strengthened system. In this paper, an attempt has been made to develop a numerical model of strengthened reinforced concrete (RC) beams with FRPC laminates. Material models for RC beams strengthened with FRPC laminates are described and verified through a nonlinear finite element (FE) commercial code, with the help of available experimental data. Three dimensional (3D) FE analysis has been performed by assuming perfect bonding between concrete and FRPC laminate. A parametric study has also been performed to examine effects of various parameters like fibre type, stirrup's spacing, etc. on the strengthening system. Through numerical simulation, it has been shown that it is possible to predict accurately the flexural response of RC beams strengthened with FRPC laminates by selecting an appropriate material constitutive model. Comparisons are made between the available experimental results in literature and FE analysis results obtained by the present investigators using load-deflection and load-strain plots as well as ultimate load of the strengthened beams. Furthermore, evaluation of crack patterns from FE analysis and experimental failure modes are discussed at the end.

THE FORMATION MECHANISM OF GROWN-IN DEFECTS IN CZ SILICON CRYSTALS BASED ON THERMAL GRADIENTS MEASURED BY THERMOCOUPLES NEAR GROWTH INTERFACES

  • Abe, Takao
    • Proceedings of the Korea Association of Crystal Growth Conference
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    • 1999.06a
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    • pp.187-207
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    • 1999
  • The thermal distributions near the growth interface of 150mm CZ crystals were measured by three thermocouples installed at the center, middle (half radius) and edge (10m from surface) of the crystals. The results show that larger growth rates produced smaller thermal gradients. This contradicts the widely used heat flux balance equation. Using this fact, it si confirmed in CZ crystals that the type of point defects created is determined by the value of the thermal gradient (G) near the interface during growth, as already reported for FZ crystals. Although depending on the growth systems the effective lengths of the thermal gradient for defect generation are varied, were defined the effective length as 10mm from the interface in this experiment. If the G is roughly smaller than 20C/cm, vacancy rich CZ crystals are produced. If G is larger than 25C/cm, the species of point defects changes dramatically from vacancies to interstitial. The experimental results which FZ and CZ crystals are detached from the melt show that growth interfaces are filled with vacancy. We propose that large G produces shrunk lattice spacing and in order to relax such lattice excess interstitial are necessary. Such interstitial recombine with vacancies which were generated at the growth interface, next occupy interstitial sites and residuals aggregate themselves to make stacking faults and dislocation loops during cooling. The shape of the growth interface is also determined by the distributions of G across the interface. That is, the small G and the large G in the center induce concave and convex interfaces to the melt, respectively.

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Numerical Investigation of the Effect of Spacing in Coaxial Propeller Multi-Copter in Hovering (멀티콥터용 동축반전 프로펠러 상하 간격에 따른 제자리 비행 공력 특성에 대한 수치적 연구)

  • Sim, Min-Cheol;Lee, Kyung-Tae;Kim, Hae-Dong
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.48 no.2
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    • pp.89-97
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    • 2020
  • In this study, a numerical analysis was performed on 26 inch single and coaxial propeller using the ANSYS Fluent 19.0 Solver to analyse the effect of the distance between coaxial propellers as one of the design parameter. The Moving Reference Frame (MRF) method was used for single propeller, while the sliding mesh method was used for a coaxial propeller to analyse the flow field varying with azimuth angle. The thrust and power are decreased as the upper and lower propeller approaching each other. As H/D is increased, interference between the propellers is decreased. According to the flow field variable contour of the coaxial propeller, it appears that the change in aerodynamic performance is due to the loading effect and the tip vortex wake effect.

NUMERICAL STUDY OF TURBINE BLADE COOLING TECHNIQUES (터빈 블레이드 냉각시스템에 관한 수치해석적 연구)

  • Kim, K.Y.;Lee, K.D.;Moon, M.A.;Heo, M.W.;Kim, H.M.;Kim, J.H.;Husain, A.
    • 한국전산유체공학회:학술대회논문집
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    • 2010.05a
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    • pp.530-533
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    • 2010
  • This paper presents numerical analysis and design optimization of various turbine blade cooling techniques with three-dimensional Reynolds-averaged Navier-Stokes(RANS) analysis. The fluid flow and heat transfer have been performed using ANSYS-CFX 11.0. A fan-shaped hole for film-cooling has been carried out to improve film-cooling effectiveness with the radial basis neural network method. The injection angle of hole, lateral expansion angle of hole and ratio of length-to-diameter of the hole are chosen as design variables and spatially averaged film-cooling effectiveness is considered as an objective function which is to be maximized. The impingement jet cooling has been performed to investigate heat transfer characteristic with geometry variables. Distance between jet nozzle exit and impingement plate, inclination of nozzle and aspect ratio of nozzle hole are considered as geometry variables. The area averaged Nusselt number is evaluated each geometry variables. A rotating rectangular channel with staggered array pin-fins has been investigated to increase heat transfer performance ad to decrease friction loss using KRG modeling. Two non-dimensional variables, the ratio of the eight diameter of the pin-fins and ratio of the spacing between the pin-fins to diameter of the pin-fins selected as design variables. A rotating rectangular channel with staggered dimples on opposite walls are formulated numerically to enhance heat transfer performance. The ratio of the dimple depth and dimple diameter are selected as geometry variables.

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Shaft Group Efficiency of Friction Pile Groups in Deep Soft Clay (대심도 마찰무리말뚝의 주면 무리효율 분석)

  • Paek, Jin-Yeol;Cho, Jae-Yeon;Jeong, Sang-Seom;Hwang, Taik-Jean
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.32 no.2C
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    • pp.49-60
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    • 2012
  • In this study, the behaviors of friction pile groups are investigated using 3D finite element (FE) analysis. The emphasis was quantifying on the shear load transfer (f-w) characteristics of pile groups and the shaft group effects. A framework for determining the f-w curve is proposed based on both theoretical analysis and field load test database. Through comparisons with case histories and FE results, it is shown that the proposed f-w curve is capable of predicting the behavior of a friction pile in deep soft clay. Additionally, a numerical analysis that takes into account the group efficiency factors were performed for major parameter on group pile-soil interaction, such as the pile spacing, pile arrangement, soil condition, and location of pile cap. Based on these results, the shaft group efficiency factors were also proposed.

Impact of the Aerodynamic Characteristics of Twin Buildings on Wind Responses (트윈 빌딩의 공력 특성이 풍응답에 미치는 영향 평가)

  • Kim, Bub-Ryur
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.33 no.1
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    • pp.1-7
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    • 2020
  • The wind responses of twin buildings are determined by the characteristics of wind loads and the dynamic characteristics of the structural systems of the buildings. In this study, the characteristics of wind pressure that influence wind responses were identified for two different spacings between the twin buildings using a wind tunnel test and the proper orthogonal decomposition (POD) method. Structural dynamic characteristics were also identified using 3D structural system modeling. The double modal transformation method was utilized to evaluate the characteristics of wind pressure for across-wind and along-wind conditions and the effect of the dynamic characteristics of each structure on the wind responses. The channeling and vortex effects were identified through the POD method. Across-wind loads were significantly affected by the spacings between the twin buildings, whereas along-wind loads were minimally affected. Similarly, while using the double modal transformation method, a significant difference was noticed in case of the cross-participation coefficients in the across-wind direction condition for the different spacings between the buildings; however, the along-wind direction condition showed negligible difference. Therefore, the spacing between the two buildings plays a more important role in across-wind responses compared to along-wind responses.

Topographic Analysis Using Wavelet-Based Digital Filters in the KR5 area, NE Equatorial Pacific (웨이브렛 디지털 필터를 이용한 북동태평양 KR5 지역의 지형 분석방법)

  • Jung, Mee-Sook;Lee, Tae-Gook;Kim, Hyun-Sub;Ko, Young-Tak;Park, Cheong-Kee;Kim, Ki-Hyune
    • Journal of the Korean Geophysical Society
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    • v.9 no.4
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    • pp.311-320
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    • 2006
  • Digital filters designed using wavelet theory are applied to bathymetry data acquired from KR5 area of Korea Deepsea Mining Area. The filters used in this study are the linear B-spline wavelet filter and derivative of a Cubic B-spline filter. With proper tuning of the digital filters, we can identify the location and orientation of the abyssal hill and abyssal trough in bathymetry. These features obtained from the digital filters are well correlated with bathymetric image. This quantitative information, which can be used to understand the underlying geophysical processes, can be further processed to obtain the spacing, orientation and distribution of the abyssal hill. This wavelet analysis of bathymetry provides good data to select the mining site.

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