• 제목/요약/키워드: cycling system

검색결과 284건 처리시간 0.026초

리튬이온전지의 사이클 수명 모델링 (Modeling to Estimate the Cycle Life of a Lithium-ion Battery)

  • 이재우;이동철;신치범;이소연;오승미;우중제;장일찬
    • Korean Chemical Engineering Research
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    • 제59권3호
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    • pp.393-398
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    • 2021
  • 리튬이온전지의 성능을 최적화하기 위해서는 여러 열화 요소들을 고려한 성능 예측 모델링 기술이 필요하다. 본 연구에서는 리튬이온전지의 사이클 노화로 인한 방전 거동 및 사이클 수명 변화를 수학적으로 모델링하였다. 모델링의 신뢰성을 검증하기 위해 0.25C로 사이클 시험을 진행했으며, 30 사이클 간격으로 진행한 RPT (Reference performance test)를 통해 전기적 거동을 파악하였다. 기존의 리튬이온전지의 사이클 수명 예측 모델에 BOL (Beginning of life)에서 일어나는 현상 중 하나인 Break-in 메커니즘을 반영하여 수명예측 정확도를 개선시켰다. 모델에 근거하여 예측된 사이클 수명 변화는 실제 시험 결과와 잘 일치하였다.

LC-MS/MS-based Quantification of Ten Neurotransmitters in Rat Limbic System and Serum: Application to Chronic Unpredictable Mild Stress-Induced Depression Rats

  • Mingyan Ma;Qiangxiang Chen;Wen Cao;Yubo Zhou;Aijuan Yan;Yanru Zhu
    • Mass Spectrometry Letters
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    • 제14권3호
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    • pp.91-103
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    • 2023
  • As one of the most common mood disorders, numerous studies have shown depression is the main risk factor for non-suicidal self-harm. The pathogenesis of depression is complex, and a comprehensive and rapid measurement of monoamine neurotransmitters and their metabolites will be very helpful in understanding the pathogenesis of depression. Therefore, a rapid and sensitive underivatized liquid chromatography-tandem mass spectrometry method was developed and validated for the simultaneous monitoring of the levels of ten neurotransmitters and their metabolites in rat serum and limbic system and successfully applied to quantify the changes of neurotransmitter levels in chronic unpredictable mild stress-induced rats. The analytes studied were mainly involved in tyrosine metabolism, tryptophan metabolism, and glutamate cycling pathways, which are important in the pathogenesis of depression. It had been verified the method was sensitive and effective, with satisfactory linearity, and met the requirements of biological sample determination. Levels of neurotransmitters in rat serum, hippocampus, amygdala, prefrontal cortex, striatum, and hypothalamus were determined via the method. The results showed serotonin, dopamine, norepinephrine, and their metabolites were decreased, glutamine was increased, and glutamate was disturbed in chronic unpredictable mild stress-induced depression rats. This method provides a new approach to studying the pathogenesis of depression and other neurological disorders.

대형 배양장치에서 기능그룹에 기초한 식물플랑크톤 천이 특성 (Characteristics of Phytoplankton Succession Based on the Functional Group in the Enclosed Culture System)

  • 이경락;노성유;이재윤;윤성애;이재학;신유나;이수웅;류덕희;이재관
    • 생태와환경
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    • 제50권4호
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    • pp.441-451
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    • 2017
  • 2016년 8월 19일부터 12월 31일까지 현장원수와 퇴적물이 주입된 현장 배양장치 실험을 통해 환경요인의 영향에 따른 식물플랑크톤 기능그룹(phytoplankton functional group, PFG)의 천이 특성을 연구하였다. 본 연구에서 확인된 식물플랑크톤은 총 27속 50종이었으며, 분류군별로는 녹조류 30종, 규조류 11종, 남조류 7종, 편모조류 2종으로 나타났다. 실험구에서 총 25속 47종(녹조류 30종, 규조류 9종, 남조류 6종, 편모조류 2종), 대조구에서 총 23속 45종(녹조류 26종, 규조류 10종, 남조류 7종, 편모조류 2종)의 식물플랑크톤이 각각 확인되었다. 식물플랑크톤 기능그룹(PFG)은 총 19개(B, C, D, F, G, H1, J, K, Lo, M, MP, N, P, S1, $T_B$, $W_0$, X1, X2, Y)로 확인되었으며, 실험구와 대조구에서는 H1을 제외하고 18개의 PFG가 모두 출현하였다. 생체 부피(biovolume)에 기초했을 때 $W_0$, J 및 M 그룹은 원수만 주입된 대조구와 비교하여 원수와 퇴적물이 주입된 실험구에서 영양염의 내부순환(internal cycling)의 영향으로 더 높은 생체부피를 보이면서 뚜렷한 천이 양상을 나타내었다. PCA 분석 결과에 기초할 때 PFG의 천이 양상은 영양염, 수온 및 조도 등의 주요 환경인자들과의 상관성에 따라 뚜렷한 차이를 나타내었다. 결론적으로 본 연구에서 PFG를 적용하여 주어진 환경조건에서 식물플랑크톤 적응 및 천이(성장) 특성을 확인할 수 있었으며, PFG는 향후 국내 수계의 식물플랑크톤 천이를 이해하기 위한 새로운 방법이 될 수 있을 것으로 생각된다.

논의 휴한기 이용형태와 토양화학성이 토양세균의 탄소원 이용에 미치는 영향 (Effect of Agricultural Practice and Soil Chemical Properties on Community-level Physiological Profiles (CLPP) of Soil Bacteria in Rice Fields During the Non-growing Season)

  • 어진우;김명현;송영주
    • 한국환경농학회지
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    • 제38권4호
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    • pp.219-224
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    • 2019
  • BACKGROUND: Soil bacteria play important roles in organic matter decomposition and nutrient cycling during the non-growing season. The purpose of this study was to investigate the effects of soil management and chemical properties on the utilization of carbon sources by soil bacteria in paddy fields. METHODS AND RESULTS: The Biolog EcoPlate was used for analyzing community-level carbon substrate utilization profiles of soil bacteria. Soils were collected from the following three types of areas: plain, interface and mountain areas, which were tested to investigate the topology effect. The results of canonical correspondence analysis and Kendall rank correlation analysis showed that soil C/N ratio and NH4+ influenced utilization of carbon sources by bacteria. The utilization of carbohydrates and complex carbon sources were positively correlated with NH4+ concentration. Cultivated paddy fields were compared with adjacent abandoned fields to investigate the impact of cultivation cessation. The level of utilization of putrescine was lower in abandoned fields than in cultivated fields. Monoculture fields were compared with double cropping fields cultivated with barley to investigate the impact of winter crop cultivation. Cropping system altered bacterial use of carbon sources, as reflected by the enhanced utilization of 2-hydroxy benzoic acid under monoculture conditions. CONCLUSION: These results show that soil use intensity and topological characteristics have a minimal impact on soil bacterial functioning in relation to carbon substrate utilization. Moreover, soil chemical properties were found to be important factors determining the physiological profile of the soil bacterial community in paddy fields.

조사시험용 압력용기의 조립 및 시험 (The Assembly and Test of Pressure Vessel for Irradiation)

  • 박국남;이종민;윤영중;전형길;안성호;이기홍;김영기;케네디
    • 대한기계학회논문집A
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    • 제33권2호
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    • pp.179-184
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    • 2009
  • The Fuel Test Loop(FTL) which is capable of an irradiation testing under a similar operating condition to those of PWR(Pressurized Water Reactor) and CANDU(CANadian Deuterium Uranium reactor) nuclear power plants has been developed and installed in HANARO, KAERI(Korea Atomic Energy Research Institute). It consists of In-Pile Section(IPS) and Out-of Pile System(OPS). The IPS, which is located inside the pool is divided into 3-parts; the in-pool pipes, the IVA(IPS Vessel Assembly) and the support structures. The test fuel is loaded inside a double wall, inner pressure vessel and outer pressure vessel, to keep the functionality of the reactor coolant pressure boundary. The IVA is manufactured by local company and the functional test and verification were done through pressure drop, vibration, hydraulic and leakage tests. The brazing technique for the instrument lines has been checked for its functionality and performance. An IVA has been manufactured by local technique and have finally tested under high temperature and high pressure. The IVA and piping did not experience leakage, as we have checked the piping, flanges, assembly parts. We have obtained good data during the three cycle test which includes a pressure test, pressure and temperature cycling, and constant temperature.

실리콘 슬러지로부터 리튬전지(電池) 음극용(陰極用) Si-SiC-CuO-C 복합물의 합성(合成) (Synthesis of Si-SiC-CuO-C Composite from Silicon Sludge as an Anode of Lithium Battery)

  • 정구진;장희동;이철경
    • 자원리싸이클링
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    • 제19권4호
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    • pp.51-57
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    • 2010
  • 실리콘 웨이퍼공정에서 발생하는 실리콘 슬러지로부터 리싸이클링 공정으로 Si-SiC 혼합물을 분리 회수한 다음 기계적 합성법으로 Si-SiC-CuO-C 복합물을 제조하였으며, 리튬전지 음극물질로서의 가능성을 조사하였다. 실리콘 슬러지의 주요 불순물은 절삭유, 금속불순물 및 SiC를 들 수 있다. 오일세정-자력선별-산세척으로 절삭유와 금속불순물을 제거한 다음 고에너지 밀링법으로 Si-SiC-CuO-C 복합물을 합성하였다. 복합물의 충방전 용량과 사이클 특성을 조사한 결과, 수명에 따른 용량 유지 특성이 향상된 우수한 결과를 얻을 수 있었다. 복합물을 구성하는 SiC와 CuO 관련 물질은 실리콘의 부피팽창으로 인한 기계적 파괴 현상을 억제하는 요소로 작용하는 것으로 추정되며, 반면에 Fe 등과 같은 불순물은 전극의 충방전 용량을 감소시키는 요인으로서 전극물질 합성 전에 10 ppm 이내로 제거되어야 하는 것으로 판단된다.

C2H2/H2/SF6 기체들의 싸이클릭 유량 변조를 통한 탄소 나노 필라멘트 직경크기 조절 (Controlling the Diameter Size of Carbon Nanofilaments by the Cyclic on/off Modulation of C2H2/H2/SF6 Flow in a Thermal Chemical Vapor Deposition System)

  • 김광덕;김성훈
    • 한국진공학회지
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    • 제18권6호
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    • pp.481-487
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    • 2009
  • 탄소나노필라멘트의 직경크기를 조절하기 위하여 증착 반응초기에 $SF_6$를 증착원료기체($C_2H_2$, $H_2$)에 주입하였다. 증착 원료 기체와 $SF_6$를 열화학기상증착시스템에서 시간에 따라 싸이클릭 유량 변조시켰다. 싸이클릭 유량 변조 프로세스와 기판의 온도에 따라 기판위에 증착된 탄소나노필라멘트들의 특성을 조사하였다. 싸이클릭 에칭기간에 $SF_6$를 투입하자 탄소나노필라멘트의 직경크기는 급격히 감소하였다. 이러한 탄소나노필라멘트 직경의 크기 감소 원인은 $SF_6$ 기체의 주입에 따른 에칭능력 향상에 기인하는 것으로 이해되었다.

Menadione의 대사체인 Menadione-Glutathione Conjugate(MEN-SG)가 흰쥐 혈소판에 미치는 세포독성의 평가 및 MEN-SG의 안정성에 관한 연구 (Evaluation of Cytotoxicity to Rat Platelets by Menadione-Glutathione Conjugate and its Stability in Biological Assay System)

  • 서동철;정선화;이주영;김미정;정진호
    • Toxicological Research
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    • 제11권2호
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    • pp.295-302
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    • 1995
  • Menadione-ghitathione conjugate (MEN-SG), a metabolite of menadione, is known to be a redoxcycler in rat hepatocyte subcellular fraction. Therefore, it was assumed that MEN-SG could exert cytotoxlclty to ral platelets, another target tissue of menadione. We first synthesized MEN-SG, the identity of which was verified by mass, $^1{H}$-NMR and UV-visible spectra. In addition, the stability of MEN-SG was investigated in biological assay system. MEN-SG was degraded in a time-dependent manner in DMSO which had been used as a vehicle and thus, tris-HCl buffer was used as a vehicle of MEN-SG despite the low solubility in it. Perchloric acid as well as platelets itself did not affect the stability of MEN-SG. Our next attempt was the evaluation of cytotoxicity of MEN-SG in rat platelets. MEN-SG did not induce cytotoxicity to rat platelets measured by two different methods, LDH release and turbidity changes. The extents of oxygen consumption by MEN-SG in intact platelets were significantly lower than those by menadione, though it had been observed that oxygen consumptions by menadione and MENSG were similar in subcellular fractioas of platelets. These results suggest that MEN-SG is not toxic to rat platelets despite its redox cycling capacity and glutathione conjugation reaction of menadione could be regarded as a detoxification process.

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누운 자세에서의 자전거 운동 시 하지 근활성도 분석 (Analysis of Lower-Limbs Muscle Activity during Cycle Exercise in Spine Position)

  • 신선혜;유미;조광수;정호춘;홍정표;홍철운;권대규
    • 재활복지공학회논문지
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    • 제9권4호
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    • pp.331-337
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    • 2015
  • 본 연구에서는 입원 또는 재활 초기단계에 환자가 이동하지 않고 침대에 누운 상태에서 자전거 운동이 가능한 하지 재활 훈련 시스템을 개발하였으며, 정상 성인을 대상으로 침대에 누운 자세에서 다양한 조건에서의 자전거 운동 시의 하지 근 활성도를 비교 분석하고자 하였다. 피험자는 근 골격계나 신경근육계 병력이 없는 20대~60대 사이의 건강한 성인 남녀 42명을 대상으로 하였으며, 운동 모드, 부하, 속도에 따른 자전거 운동 시 오른쪽 하지의 대퇴직근, 대퇴이두근, 전경골근, 내측 비복근, 가자미근의 근 활성도를 측정하였다. 그 결과, 부하를 1과 5단계로 제공하였을 때보다 10단계로 제공하였을 때 내측 비복근의 근활성이 높아짐을 보였다. 또한, 속도가 증가할수록 내측 비복근을 제외한 모든 근육에서 근활성도가 감소하는 결과를 보였다. 즉, 운동 조건에 따라 크게 활성화되는 근육들이 각기 달랐으며, 이러한 결과는 침상에 누워 재활훈련이 가능한 자전거 시스템 개발을 위한 기초 자료로써 활용될 것이다.

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상아질접착제와 열순환에 따른 유동성 레진의 전단결합강도 비교 연구 (A COMPARATIVE STUDY OF SHEAR BOND STRENGTH OF FLOWABLE RESIN ASSOCIATED WITH DENTIN ADHESIVE SYSTEMS WITH THERMOCYCLING EFFECT)

  • 남기영
    • 대한치과보철학회지
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    • 제44권4호
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    • pp.383-393
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    • 2006
  • Statement of problem : Limited research on flowable resin has been undertaken on its application directly on dentin associated with the adhesive systems. Purpose : This study was to evaluate the shear bond strengh and fracture aspect of flowable resin on human dentin with various types of dentin bonding adhesives with thermo cycling effect. Materials and methods: Filtek-Flow(3M ESPE, USA) was used as flowable resin and Eighty human molars were randomly divided into 4 groups : three dentin bonding adhesives (Scotchbond-Multipurpose : 3-step contentional system, One-Step : One-bottle system. Prompt L-Pop : All-in-one, self-etching primer) and 32% etching treatment without bonding adhesive as a control group. For evaluating their durability of bonding, each group was subdivided : storaging in the water at 37$^{\circ}C$(24 hours) and thermocycling (0$^{\circ}C$-55$^{\circ}C$, 30 seconds intervals, 1000 cycle). Shear bond strength tests were performed and resin-dentin interface and fracture mode were observed. Results were analysed by one-way ANOVA and Scheffe's multiple range test. Results and Conclusion : 1. At 0 cycle, the mean shear bond strength of One-Step exhibited the highest value of all groups(p<0.05), and there were no significant differences between Prompt L-Pop and Scotchbond-Multipurpose, Scotchbond-Multipurpose and control(p>0.05). After 1000 thermocycling, One-Step exhibited higher value than other groups(p<0.05), and there were no significant differences among other groups (p>0.05). 2. The shear bond strength of each group was significantly decreased after thermocycling except Scotchbond-Multipurpose (p>0.05). 3. The most common failure mode was adhesive type and mixed type, next in order.