• 제목/요약/키워드: cycling system

검색결과 285건 처리시간 0.023초

활성화 및 에어로졸 공정에 의한 다공성 그래핀 볼 제조 및 슈퍼커패시터 응용 (Synthesis of Porous Graphene Balls by the Activation and Aerosol Process for Supercapacitors Application)

  • 이총민;장한권;장희동
    • 한국입자에어로졸학회지
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    • 제15권4호
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    • pp.183-190
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    • 2019
  • Here, we introduce porous graphene balls (PGB) showing superior electrochemical properties as supercapacitor electrode materials. PGB was fabricated via activation of graphene oxides (GO) by H2O2 and aerosol spray drying in series. Effect of activation on the morphology, specific surface area, pore volume, and electrochemical properties were investigated. As-prepared PGB showed spherical morphology containing pores, which lead to the effective prevention of restacking in graphene sheets. It also exhibited a large surface area, unique porous structures, and high electrical conductivity. The electrochemical properties of the PGB as electrode materials of supercapacitor are investigated by using aqueous KOH under symmetric two-electrode system. The highest specific capacitance of PGB was 279 F/g at 0.1 A/g. In addition, the high rate capability (93.8% retention) and long-term cycling stability (92.2%) of the PGB were found due to the facilitated ion mobility between the porous graphene layers.

An Experimental Analysis of the Ripple Current Applied Variable Frequency Characteristic in a Polymer Electrolyte Membrane Fuel Cell

  • Kim, Jong-Hoon;Jang, Min-Ho;Choe, Jun-Seok;Kim, Do-Young;Tak, Yong-Sug;Cho, Bo-Hyung
    • Journal of Power Electronics
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    • 제11권1호
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    • pp.82-89
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    • 2011
  • Differences in the frequency characteristic applied to a ripple current may shorten fuel cell life span and worsen the fuel efficiency. Therefore, this paper presents an experimental analysis of the ripple current applied variable frequency characteristic in a polymer electrolyte membrane fuel cell (PEMFC). This paper provides the first attempt to examine the impact of ripple current through immediate measurements on a single cell test. After cycling for hours at three frequencies, each polarization and impedance curve is obtained and compared with those of a fuel cell. Through experimental results, it can be absolutely concluded that low frequency ripple current leads to long-term degradation of a fuel cell. Three different PEMFC failures such as membrane dehydration, flooding and carbon monoxide (CO) poisoning that lead to an increase in the impedance magnitude at low frequencies are simply introduced.

원소의 지구화학적 거동에 미치는 박테리아의 영향 : 지구미생물학의 최근 연구 동향 (Bacterial Effects on Geochemical Behavior of Elements : An Overview on Recent Geomicrobiological Issues)

  • 이종운;전효택
    • 자원환경지질
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    • 제33권5호
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    • pp.353-365
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    • 2000
  • After their first appearance on Earth, bacteria have exerted significant influence on geochemical behavior of elements. Numerous evidence of their control on geochemistry through geologic history has been observed in a variety of natural environments. They have mediated weathering rate, formation of secondary minerals, redox transformation of metals and metalloids, and thus global cycling of elements. Such ability of bacteria receives so considerable attention from microbiologists, mineralogists, geologists, soil scientists, limnologists, oceanographers, and atmospheric scientists as well as geochemists that a new and interdisciplinary field of research called 'geomicrobiology' is currently expanding. Some recent subjects of geomicrobiology which are studied extensively are as follows: 1) Functional groups distributed on bacterial cell walls adsorb dissolved cations onto cell surfaces by electrostatic surface complexation, which is followed by hydrous mineral formation. 2) Dissimilatory metal reducing bacteria conserve energy to support growth by oxidation of organic matter coupled to reduction of some oxidized metals and/or metalloids. They can be effectively used in remediating environments contaminated with U, As, Se, and Cr. 3) Bacteria increase the rate of mineral dissolution by excreting proton and ligands such as organic acids into aqueous system. 4) Thorough investigation on the effects of biofilm on geochemical processes is needed, because most bacteria are adsorbed on solid substrates and form biofilms in natural settings.

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휴대형 심전계 장치의 RR 간격의 정확도 개선을 위한 보간법 개발 (Interpolation Technique to Improve the Accuracy of RR-interval in Portable ECG Device)

  • 이은미;홍주현;차은종;이태수
    • 대한의용생체공학회:의공학회지
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    • 제31권4호
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    • pp.316-320
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    • 2010
  • HRV(Heart rate variability) analysis parameter is widely used as an index to evaluate the autonomic nervous system and cardiac function. For reliable HRV analysis, we need to acquire the accurate ECG signals. Most of commercially available portable ECG devices have low sampling rate because of low power consumption and small size issues, which make it difficult to measure RR-interval accurately. This study is to improve the accuracy of RR-interval by developing R-wave interpolation technique, based on the morphological characteristics of the QRS complex. When the developed method was applied to ECG obtained at 200 Hz and the results were compared with 1000 Hz reference device, the error range decreased by 1.33 times in sitting and by 2.38 times in cycling exercise. Therefore, the proposed interpolation technique is thought to be useful to improve the accuracy of R-R interval in the portable ECG device with low sampling rate.

Alternative Sample Preparation Method for Large-Area Cross-Section View Observation of Lithium Ion Battery

  • Kim, Ji-Young;Jeong, Young Woo;Cho, Hye Young;Chang, Hye Jung
    • Applied Microscopy
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    • 제47권2호
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    • pp.77-83
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    • 2017
  • Drastic development of ubiquitous devices requires more advanced batteries with high specific capacitance and high rate capability. Large-area microstructure characterization across the stacks of cathode, electrolyte and anode might reveal the origin of the instability or degradation of batteries upon cycling charge. In this study, sample preparation methods to observe the cross-section view of the electrodes for battery in SEM and several imaging tips are reviewed. For an accurate evaluation of the microstructure, ion milling which flats the surface uniformly is recommended. Pros and cons of cross-section polishing (CP) with Ar ion and focused ion beam (FIB) with Ga ion were compared. Additionally, a modified but new cross-section milling technique utilizing precision ion polishing system (PIPS) which can be an alternative method of CP is developed. This simple approach will make the researchers have more chances to prepare decent large-area cross-section electrode for batteries.

불화 처리된 AB$_2$계 수소저장합금의 전극특성에 관한 연구 (A Study on the Electrode Charcteristics of the Fluornated AB$_2$ Type Hydrogen Storage Alloys)

  • 박호영;이명호;조원일;조병래;이성래;주재백;윤경석
    • 한국표면공학회지
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    • 제30권4호
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    • pp.262-271
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    • 1997
  • Nickel-matal hydride(Ni-MH) batteries are receiving attention as non-pollunting. high performance rehargeable energy stoage system. The performance of Ni-Mh is significantly influenced by the hydrogen storage alloy materiels used as an anode material. Recently, having discharge capacities higher than the $AB_5$-type hydrogen storage alloys, the Zr-based $AB_2$-Type hydrogen storage alloys has remaining problems regarding cycle life and self-dischareg. These problems need to be solved by improvements in the alloy design and/or surface treatment. This work investiggates the effects the effects of surface property by fluorination on $Zr_{0.7}Ti_{0.3}V_{0.4}Mn_{0.4}Ni{1.2}$ composittion $AB_2$-Type hydrogen storage alloys. EPMA, SEM and AES techniques were used for surface analysis, and the crystal structure was characterized by constant current cycling test and potential sweep methods. Fluorination was found to be effective when La-was incorporated into the alloy, and has unique morphology, higher reactivity, and at the same time formed a protective film. Through, fluorination, the cycle life of an electrode was found to increase significantly, charge/discharge characteristics of the electrode the potential difference between the charge/discharge plateau, i.e polarization(overpotential)were improved.

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자동 쓰레기 집하 시설에 사용되는 1회사용 종량제 봉투 인식 장치 설계에 관한 연구 (A study on the recognition system design of one-time use of a standard plastic garbage bag at automaticat garbage facility)

  • 김계국;서창옥
    • 한국컴퓨터정보학회:학술대회논문집
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    • 한국컴퓨터정보학회 2012년도 제45차 동계학술발표논문집 20권1호
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    • pp.41-43
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    • 2012
  • 현대 사회는 환경에 대한 관심을 많이 가지고 있다. 특히 먹거리가 풍부해지면서 음식물 쓰레기량이 더욱 늘고 있다. 이를 처리하기 위해 전 세계적으로 많은 고민을 하고 있다. 국내에서는 이를 줄이기 위해 쓰레기 종량제 봉투를 사용하여, 쓰레기를 정해진 량만큼 버리도록 하고 있어 연간 배출되는 쓰레기량을 줄이고 있다. 그런데 주민들이, 쓰레기 봉투를 다시 사용 하는 사례가 많아지고 있다. 본 연구의 목적은 종량제 봉투의 재사용을 방지하는 알고리즘을 제안하는데 있다.

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초음파를 이용한 금속기지 복합재료의 열충격 손상 평가 (Evaluation of Thermal Shock Damage of Metal Matrix Composite Using Ultasonics)

  • 강문필;이민래;이준현
    • 대한기계학회논문집A
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    • 제29권11호
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    • pp.1480-1487
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    • 2005
  • Metal matrix composites(MMCs) have been rapidly becoming one of the strongest candidates for structural materials fur many high temperature application. However, among the various high temperature environments in which metal matrix composites was applied, thermal shock is known to cause significant degradation in most MMC system. Due to the appreciable difference in coefficient of thermal expansion(CTE) between reinforcement and metal matrix, internal stresses are generated following temperature changes. Infernal stresses affect degradation of mechanical properties of MMC by causing microscopic damage in interface and matrix during thermal cycling. Therefore, the nondestructive evaluation on thermal shock damage behavior of SiC/A16061 composite has been carried out using ultrasonics. For this study, SiC fiber reinforced metal matrix composite specimens fabricated by a squeeze casting technique were thermally cycled in the temperature range 298$\~$673 K up to 1000cyc1es. Three point bending test was conducted to investigate the efffct of thermal shock damage on mechanical properties. The relationship between thermal shock damage behavior and the propagation characteristics of surface wave and SH-ultrasonic wave was discussed by considering the result of SEM observation of fracture surface.

국내 원전 RCS 분기배관에 대한 열피로 선정기준 (Thermal Cycling Screening Criteria to RCS Branch Lines in Domestic Nuclear Power Plant)

  • 박정순;최영환;임국희;김선혜
    • 한국압력기기공학회 논문집
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    • 제6권2호
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    • pp.54-60
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    • 2010
  • Piping failures due to thermal fatigue have been widely reported in normally stagnant non-isolable reactor coolant branch lines. Since the thermal fatigue due to thermal stratification was not considered in the piping fatigue design in old NPPs, it is important to evaluate the effect of thermal stratification on the integrity of branch lines. In this study, geometrical screening criteria for Up-horizontal branch lines in MRP-132 were applied to SI(Safety Injection) lines of KSNP 2-loop and WH 3-loop. Some computational fluid dynamic(CFD) analyses on the Reactor Coolant System(RCS) branch lines were also performed to develop the regulatory guidelines for screening criteria. As a result of applying MRP-132 screening criteria, KSNP 2-loop and WH 3-loop SI lines are determined to need further detailed evaluation. Results of CFD analyses show that both valve isolation and amount of leakage through valve can be used as technical bases for the screening criteria on the thermal fatigue analysis.

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가열-냉각 사출성형 방식을 적용한 집광형 프레넬렌즈 (Heat & Cool Injection Molded Fresnel Lens Solar Concentrators)

  • 정병호;민완기;이강연
    • 전기학회논문지P
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    • 제63권4호
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    • pp.283-289
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    • 2014
  • A Fresnel lens is an optical component which can be used as a cost-effective, lightweight alternative to conventional continuous surface optics. Fresnel lens solar concentrators continue to fulfill a market requirement as a system component in high volume cost effective Concentrating Photovoltaic (CPV) electricity generation. The basic principles of the fresnel lens are reviewed and some practical examples are described. To investigate the performance space of the Fresnel lens, a fast simulation method which is a hybrid between raytracing and analytical computation is employed to generate a cache of simulation data. Injection molders are warming up to the idea of cycling their tool surface temperature during the molding cycle rather than keeping it constant. Heat and cool process are now also finding that raising the mold wall temperature above the resin's glass-transition or crystalline melting temperature during the filling stage and product performance in applications from automotive to packaging to optics. This paper deals with the suitability of Fresnel lenses of imaging and non-imaging designs for solar energy concentration. The concentration fresnel lens confirmed machinability and optical transmittance and roughness measure through manufactured the prototype.