• 한국재료학회:학술대회논문집
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• 한국재료학회 2010년도 춘계학술발표대회
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• pp.37.2-37.2
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• 2010

Recently $Li_{1.2}Ni_{0.2}Mn_{0.6}O_2$ has been consistently examined and investigated by scientists because of its high lithium storage capacity, which exceeds beyond the conventional theoretical capacity based on conventional chemical concepts. Consequently, $Li_{1.2}Ni_{0.2}Mn_{0.6}O_2$ is considered as one of the most promising cathode candidates for next generation in Li rechargeable batteries. Yet the mechanism and the origin of the overcapacity have not been clarified. Previously, many authors have demonstrated simultaneous oxygen evolution during the first delithiation. However, it may only explain the high capacity of the first charge process, and not of the subsequent cycles. In this work, we report a clarified interpretation of the structural evolution of $Li_{1.2}Ni_{0.2}Mn_{0.6}O_2$, which is the key element in understanding its anomalously high capacity. We identify how the structural evolution of $Li_{1.2}Ni_{0.2}Mn_{0.6}O_2$ occurs upon the electrochemical cycling through careful study of electrochemical profiles, ex-situ X-ray diffraction (XRD), HR-TEM, Raman spectroscopy, and first principles calculation. Moreover, we successfully separated the structural change at subsequent cycles (mainly cation rearrangement) from the first charge process (mainly oxygen evolution with Li extraction) by intentionally synthesizing sample with large particle size. Consequently, the intermediate states of structural evolution could be well resolved. All observations made through various tools lead to the result that spinel-like cation arrangement and lithium environment are created and embedded in layered framework during repeated electrochemical cycling.

• 한국항해항만학회지
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• 제36권1호
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• pp.69-74
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• 2012

오늘날 글로벌 수 출입 공급망 내에서 항만 하역작업의 효율성은 아주 중요하다. 해상운송에서는 컨테이너화와 더불어 늘어나는 화물량을 극복하기 위해서 초대형선의 운항이 일반화 되고 있다. 따라서 컨테이너 터미널의 관리자들은 안벽작업의 효율성을 극대화하기 위하여 더블 사이클과 듀얼 사이클 방법을 시도하고 있다. 또한, 야드 트랙터의 할당의 효율성을 높이기 위해서 야드 트랙터 풀링 방법이 제시되었다. 본 논문에서는 기존의 풀링 방법들과 듀얼 사이클을 고려한 풀링 방법의 비교를 통해서 듀얼 사이클의 효율성을 분석하였다. YT 할당 모형은 시뮬레이션 분석 소프트웨어인 Arena를 이용하여 수립되었다. 실험결과 듀얼 사이클이 많은 것이 항상 크레인 생산성을 높이는 것은 아닌 것으로 분석되었다.

• 한국해양학회지:바다
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• 제26권2호
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• pp.145-166
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• 2021

지난 수십년 간 퇴적물 트랩은 해양 유기물과 관련된 생물학적 입자들의 수직적 이동인 생물학적 탄소 펌프(BCP: Biological Carbon Pump)를 이해하는 데 중요한 도구들 중 하나로 사용되어 왔다. 이 논문에서는 퇴적물 트랩을 이용한 해양 심층의 탄소 순환 연구 방법과 여러 해역에서의 연구 현황, 그리고 그 중요성에 대하여 고찰하였다. 한편 최근의 연구 중 몇몇은 심층으로 이동된 침강 입자유기탄소(POC: Particulate Organic Carbon)가 이전에 알려졌던 것 보다 더 복잡한 형태이고, 시공간적으로 다양한 기원을 가지고 있음을 밝혔다. 이 논문에서는 특히 침강 입자 중 재부유 퇴적물에 관해 연구한 최신 논문들을 정리하였다. 유기 추적자로 사용한 방사성탄소동위원소(¹⁴C)와 무기적 추적자(Al)를 해양 입자유기탄소 순환을 이해하고 재부유 퇴적물의 중요성을 파악하는 데 있어 어떻게 활용할 수 있을지 기술하였으며, 특히MICADAS (Mini radioCarbon Dating Systems)를 이용한 방사성탄소동위원소 연구의 중요성을 강조하였다.

• 대한전기학회:학술대회논문집
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• 대한전기학회 1998년도 하계학술대회 논문집 D
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• pp.1511-1513
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• 1998

The purpose of this study is to research and develop PEO/PVDF electrolytes and $LiMn_2O_4$ composite cathode for all-solid state lithium rechargeable battery. We investigated AC impedance response and charge/discharge cycling of $LiMn_2O_4$/SPE/Li cells. The cell resistance was decreased so much initial charge process from 0% SOC to 100% SOC. The radius of semicircle of $LiMn_2O_4$/SPE/Li cell was so much from initial state to 20th cycling. The discharge capacity of the $LiMn_2O_4$ composite cathode was 144mAh/g based on $LiMn_2O_4$.

• 대한전기학회:학술대회논문집
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• 대한전기학회 1996년도 하계학술대회 논문집 C
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• pp.1685-1687
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• 1996

Recently, conducting polymer has been much attracted as novel materials because of its electronic behavior and functional application by doping process. In this paper, we electrochemically synthesized polyaniline films under potential sweep conditions, which exhibit high electric conductivity about 200 S/cm. Specific energy of 600 Wh/kg and Ah efficiency 98% were achieved during the charge/discharge cycling using liquid electrolyte system. On the other hand, consequences of the cycling were 260 Wh/kg and 95% Ah efficiency using polyethylene oxide(PEO) based solid-state electrolyte system.

• Journal of Electrochemical Science and Technology
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• 제7권3호
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• pp.206-213
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• 2016

Transition metal oxide-based electrodes for lithium ion batteries have recently attracted much attention because of their high theoretical capacity. Here we report the electrochemical behavior of cobalt oxide nanorods as anodes, prepared by a template-free, one-step electrochemical deposition of cobalt nanorods, followed by an oxidation process. The as-deposited cobalt has a slightly convex columnar structure, and controlled thermal oxidation produces cobalt oxides of different Co/O ratios, while the original shape is largely preserved. As an anode in a rechargeable lithium battery, the Co/O ratio has a strong effect on initial capacity and cycling stability. In particular, the one-dimensional Co@Co_xO_y core shell structure obtained from a mild heat-treatment results in superior cycling stability.

• 한국항해항만학회지
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• 제33권2호
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• pp.127-134
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• 2009

If the research on double cycle is revitalized, crane productivity will be rapidly improved bemuse double cycle is an operational technique that can maximize equipments efficiency (Quay crane, RMG/RTG, Yard tractor). Unfortunately, it is very difficult for terminal operators to find out the starting point of double cycle bemuse the loading & unloading pattern and conditions are various. Therefore, terminal operators are apt to fail to find out the optimal starting point of double cycle to maximize its frequency. Experiencing the same mistakes in the process we made efforts to find out the optimal starting point, finally we found out the formula for it. And we verified its precision is perfect through a lot of testing. This paper on double cycling focused on making the formula to find out optimal starting point of double cycle to maximize its frequency. And it can be applied to various ships' stowages in common.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2007년도 제38회 하계학술대회
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• pp.975-976
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• 2007

Thermal and mechanical stresses, caused by repetitive start and stop and load fluctuation during long time operation, on winding stator bars are one of the main causes for electrical degradation of insulating materials. To understand the degradation process, we manufactured bar specimens with the same processes that make generator winding stator bars and the specimens were subjected to various degrees of thermal cycling. Measurements of the insulation properties, such as dissipation factor, tip-up and partial discharge, for un-aged specimens and for specimens aged by thermal cycling at 50, 100, 250, 500 and 1000 thermal cycles were performed. Finally all specimens were tested to obtain electrical breakdown voltages. In this paper we present the data and electrical degradation analysis results obtained during this program.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2013년도 제45회 하계 정기학술대회 초록집
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• pp.269-269
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• 2013

Redox cycling in between the two working electrodes in an electrochemical cell can lead a great signal enhancement. In this work, we report on a systematic examination of current amplification along with the decrease in the gap distance of a nanogap device which was fabricated by the combination of photo and chemical lithography [1]. The gap distance was controlled by the chemical lithographic process of surfacecatalyzed growth of metallic layer on pre-defined electrodes with wider initial gap. Enhancement of the redox current of ferri/ferrocyanide was observed upon gap distance reduction and the current is amplified about a thousand times in this redox system when the gap distance was decreased from 200 nm to 30 nm. The experimental results were discussed on the basis of the cyclic voltammetry (CV), atomic force microscopy (AFM) and scanning electron microscopy (SEM).

• Journal of Plant Biology
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• 제20권3호
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• pp.109-118
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• 1977

Seasonal distribution of N, P and K contents and their cycling were studied in Korean oak (Quercus acutissima) and Korean alder (Alnus sibirica) stands in central part of Korean peninsula. The amounts of three minerals were high in young leaves but gradually decreased with the process of leaf development in both stands. The amounts of minerals in the branches, trunks and roots were decreased in summer, however, they increased again in autumn. Seansonal changes of these minerals were not significant in the two stands. The amounts of phosphorus and potassium in plant and soil were higher in the oak stand than the alder one, but those of nitrogen were reversed. The amounts of minerals absorbed during one year were greater in the oak stand than in the alder one, but those returned into soil through mineralization of litter were less in the former than in the latter. The nutrient requirements of the oak stand were greater than the alders, but the cycling rate, the ratio of the amount of minerals absorbed to returned, was opposite.