• Title/Summary/Keyword: cyclic corrosion test

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Crevice Corrosion Evaluation of Cold Sprayed Copper (저온분사코팅구리의 틈새부식 특성 평가)

  • Lee, Min-Soo;Choi, Heui-Joo
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.8 no.3
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    • pp.247-260
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    • 2010
  • The developement of a HLW disposal canister is under way in KAERI using Cold Spray Coating technique. To estimate corrosion behavior of a cold sprayed copper, a creivice corrosion test was conducted at Southwest Research Institute(SWRI) in the United State. For the measurement of repassivation potential needed for crevice corrosion, three methods such as (1) ASTM G61-86 : Cyclic Potentiodynamic Polarization Measurements, (2) Potentiodynamic Polarization plus intermediate Potentiostatic Hold method, and (3) ASTM G192-08 (THE method) : Potentiodynamic- Galvanostatic-Potentiostatic Method, were introduced in this report. In the crevice corrosion test, the occurrence of corrosion at crevice area was optically determined and the repassivation potentials were checked for three kind of copper specimens in a simulated KURT underground water, using a crevice former dictated in ASTM G61-86. The applied electrochemical test techniques were cyclic polarization, potentiostatic polarization, and electrochemical impedance spectroscopy. As a result of crevice corrosion tests, every copper specimens including cold sprayed one did not show any corrosion figure on crevice areas. And the open-cell voltage, at which corrosion reaction initiates, was influenced by the purity of copper, but not their manufacturing method in this experiment. Therefore, it was convinced that there is no crevice corrosion for the cold sprayed copper in KURT underground environment.

The Study on the Acceleration Factor of Coastal Outdoor Corrosion test, Salt Spray Test and Accelerated Corrosion Test using 0.5wt% carbon steel (0.5wt% 탄소강을 이용한 해안 야외부식시험과 염수분무시험, 가속부식시험의 가속계수에 대한 연구)

  • Cho, E.Y.;Gwon, G.B.;Cho, D.H.;Kim, J.Y.
    • Corrosion Science and Technology
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    • v.12 no.5
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    • pp.209-214
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    • 2013
  • In the industry, accelerated corrosion test is used for the life time prediction. When anti-corrosion test proceeds in real environments, it is difficult that we predict and evaluate the corrosion life time because of the long test time such as 10 years or more time. Accelerated corrosion test and Salt spray test are able to test corrosion life time of products in the laboratory instead of outdoor corrosion test. Experimental procedure is selected for the corrosion standard specimen, exposure of the specimens, measurements of the mass loss and evaluating the mass loss data. As a result, the acceleration factor of the accelerated corrosion test to the outdoor corrosion test is 414.8. Therefore we can predict the corrosion life time of carbon steel during a short time period.

Effects of phosphate coating on some performance of painted Al alloy sheet (도장 알루미늄 합금판의 성능에 미치는 인산염피막의 영향)

  • 이규환;노병호
    • Journal of the Korean institute of surface engineering
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    • v.28 no.5
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    • pp.289-299
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    • 1995
  • The effects of phosphate coating have been studied on physical properties and corrosion resistance of painted aluminum alloy sheet for automobile body. The physical properties (surface roughness, paint adhesion, impact resistance and pencil hardness) and corrosion resistance(cyclic corrosion and filiform corrosion) were investigated. Phosphate coatings enhanced the physical properties of painted Al alloy sheet, especially paint adhesion after the 240hours water immersion test. Phosphate coating also markedly improved the resistance for cyclic corrosion and filiform corrosion of painted cold rolled steel and Zn-Ni plated steel sheet as well as painted Al alloy sheet. The corrosion resistance of painted Al sheets was varied with the concentration of free fluoride ion and metal additives like Ni and Mn in the phosphating bath. A maximum corrosion resistance was obtained at about 300ppm of fluoride ion and additives of Ni and Mn obviously increased the corrosion resistance of painted specimens.

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Corrosion Performance of Cu Bonded Grounding-Electrode by Accelerated Corrosion Test

  • Choi, Sun Kyu;Kim, Kyung Chul
    • Corrosion Science and Technology
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    • v.17 no.5
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    • pp.211-217
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    • 2018
  • Natural degradation of grounding-electrode in soil environment should be monitored for several decades to predict the lifetime of the grounding electrode for efficient application and management. However, long-term studies for such electrodes have many practical limitations. The conventional accelerated corrosion test is unsuitable for such studies because simulated soil corrosion process cannot represent the actual soil environment. A preliminary experiment of accelerated corrosion test was conducted using existing test standards. The accelerated corrosion test that reflects the actual soil environment has been developed to evaluate corrosion performances of grounding-electrodes in a short period. Several test conditions with different chamber temperatures and salt spray were used to imitate actual field conditions based on ASTM B162, ASTM B117, and ISO 14993 standards. Accelerated degradation specimens of copper-bonded electrodes were made by the facile method and their corrosion performances were investigated. Their corrosion rates were calculated to $0.042{\mu}m/day$, $0.316{\mu}m/day$, and $0.11{\mu}m/day$, respectively. These results indicate that accelerated deterioration of grounding materials can be determined in a short period by using cyclic test condition with salt spray temperature of $50^{\circ}C$.

Effect of Temperature on Electrochemical Characteristics of Stainless Steel in Green Death Solution Using Cyclic Potentiodynamic Polarization Test (순환동전위 분극실험을 이용한 스테인리스강의 그린데스용액에서 전기화학적 특성에 미치는 온도의 영향)

  • Hwang, Hyun-Kyu;Kim, Seong-Jong
    • Corrosion Science and Technology
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    • v.20 no.5
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    • pp.266-280
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    • 2021
  • Since 2020, the International Maritime Organization (IMO) has updated regulations on the sulfur content to be less than 0.5% in exhaust gas emitted from ships. Accordingly, the exhaust gas post-treatment device for ships, which is SOx/NOx reduction technology, was introduced. However, the exhaust gas post-treatment device is suffering corrosion because of the harsh corrosive environment formed by sulfate and chlorine oxide through the desulfurization process. In this investigation, cyclic potentiodynamic polarization (CPDP) experiment for UNS S31603 and UNS N08367 was performed in a green death solution that simulates the environment of a desulfurization device. The corrosion rate of UNS S31603 at the highest temperature was about 3 times higher than that of UNS N83067. Also, electron microscope scan revealed corrosion type UNS N83067 presents intergranular corrosion tendency. On the other hand, UNS S31603 was observed as general corrosion. The α values of UNS N08367 at 30 ℃ and 60 ℃ were higher than those of UNS S31603, thus UNS N08367 is considered to have a higher local damage tendency. Whereas, since the α value of UNS S31603 at 90 ℃ is larger than that of UNS N08367, UNS S31603 is considered to have a higher local damage trend.

Evaluation of Corrosion Protective System for Reinforced Concrete Structures Constructed With Sea Sand (해사 혼입된 콘크리트 구조물의 부식도 평가)

  • 김웅희;홍기섭;오승모;장지원;최응규;최완철
    • Proceedings of the Korea Concrete Institute Conference
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    • 1997.04a
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    • pp.203-209
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    • 1997
  • An experimental study to evaluate to evaluate corrosion protection systems was undertaken with 44 reinforced concrete slab specimens subjected to cyclic wet and dry saltwater exposure. Corrosion measurements included monitoring macrocell corrosion currents, which are genrerally accecpted in United States practice. Test results indicate that specimens containing 2 kg/$\textrm{m}^3$ of NaCl and exposed to wet(outdoor) and dry(indoor) conditions but not to saltwater show very low values of corrosion measurements regardless applying any corrosion protective systems. Corrosion currents of the specimens exposed at 10 percent of NaCl were higher than that of the specimen exposed at 5 percent of NaCl, so the density of the salt water had an influential effect on the test. For the specimens with water repellent membrane currents kept relatively low numerical values, but test specimens with surface corrosion inhibitor protective system showed high values of corrosion current. It would be expected that evaluation of the corrosion protective systems need long-term measurement.

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Square CFST columns under cyclic load and acid rain attack: Experiments

  • Yuan, Fang;Chen, Mengcheng;Huang, Hong
    • Steel and Composite Structures
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    • v.30 no.2
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    • pp.171-183
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    • 2019
  • As China's infrastructure continues to grow, concrete filled steel tubular (CFST) structures are attracting increasing interest for use in engineering applications in earthquake prone regions owing to their high section modulus, high strength, and good seismic performance. However, in a corrosive environment, the seismic resistance of the CFST columns may be affected to a certain extent. This study attempts to investigate the mechanical behaviours of square CFST members under both a cyclic load and an acid rain attack. First, the tensile mechanical properties of steel plates with various corrosion rates were tested. Second, a total of 12 columns with different corrosion rates were subjected to a reversed cyclic load and tested. Third, comparisons between the test results and the predicted ultimate strength by using four existing codes were carried out. It was found that the corrosion leads to an evident decrease in yield strength, elastic modulus, and tensile strain capacity of steel plates, and also to a noticeable deterioration in the ultimate strength, ductility, and energy dissipation of the CFST members. A larger axial force ratio leads to a more significant resulting deterioration of the seismic behaviour of the columns. In addition, the losses of both thickness and yield strength of an outer steel tube caused by corrosion should be taken into account when predicting the ultimate strength of corroded CFST columns.

Corrosion Resistance of SD460 Reinforcing Rod by Ceramic Coating (SD460 철근의 세라믹 코팅에 의한 내식성 향상연구)

  • Park, Ki Y.;Lee, Jong K.;Hong, Seok W.
    • Corrosion Science and Technology
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    • v.8 no.4
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    • pp.157-161
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    • 2009
  • The corrosion resistance of reinforcing bar was studied to endure the marine environment during shipment. The red rust on the surface did not damage the adherence in the concrete structures, especially in highly alkaline environment, but made the consumer doubt of the quality. The passivation process by alkalization of the quenching water in the tempcore process failed to endure the long shipping period. The ceramic coating by sol-gel process improved the corrosion resistance without damaging the mechanical properties and adherence between concrete and reinfiorcing bar. Optimal concentration of the coating solution and coating temperature were tested. No additional energy was necessary for the coating process by spraying during cooling process, resulting simplified process and low cost. Salt spray test, cyclic corrosion test and atmospheric test were employed to confirm the resistance. The corrosion rates were presented by rating number and polarization resistance. The coating layer was examined by FIB, XRD and SEM etc.

Evaluation of Corrosion Resistance according to Surface treatment of Installed Ammunition Case(ALDC12) (설치형 탄약 케이스의(ALDC12) 표면처리에 따른 부식 영향성 평가)

  • Jonghyeon Lee;Jonghyeon Lee;Sangbong Lee;Hyemin Park;Namyoung Yu
    • Journal of the Korea Institute of Military Science and Technology
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    • v.27 no.4
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    • pp.457-465
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    • 2024
  • The Remote Control Munition System is a anti-personnel munitions system to replace land mines that are hard to retrieve and can inflict damage on friendly forces and civilians. As operating environments and methods change, quality improvement is necessary to ensure appropriate durability. Therefore, corrosion resistance evaluation was performed according to the surface treatment of ALDC12, the main assembly material. We conduct the potentiodynamic polarization, cyclic corrosion test to perform analysis on corrosion behavior. Additionally, we try to observe the pitting on the surface through SEM analysis. In conclusion, among the three surface treatments, Anodizing surface treatment is judged to be the most suitable for corrosion durability in a field environment.