• Bulletin of the Korean Chemical Society
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• v.22 no.8
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• pp.816-820
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• 2001

A new copper hexacyanoferrate modified electrode was constructed by mechanical immobilization. The modified electrode was characterised by cyclic voltammetric experiments. Electrocatalytic oxidation of glutathione was effective at the modified electrode at a significantly reduced overpotential and at broader pH range. The modified electrode shows a stable and linear response in the concentration range of 9 ${\times}$10-5 to 9.9 ${\times}$10-4M with a correlation coefficient of 0.9995. The modified electrode exhibits excellent stability, reproducibility and rapid response and can be used in flow injection analysis for the determination of glutathione.

• Journal of Communications and Networks
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• v.15 no.3
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• pp.245-251
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• 2013

This paper addresses the issue of time-difference-of-arrival (TDOA) estimation for complex noncircular signals. First, under the wide-sense stationary assumption, we derive the maximum likelihood (ML) estimator and the Cramer-Rao lower bound for Gaussian noncircular signals in Gaussian circular noise. The ML estimator uses the second-order statistics information of a noncircular signal more comprehensively when compared with the cross-correlation (CC) and the conjugate CC estimators. Further, we present a scheme to modify the traditional signal-selective TDOA methods for noncircular signals on the basis of the cyclostationarity of man-made signals. This scheme simultaneously exploits the information contained in both the cyclic cross-correlation (CCC) and the conjugate CCC of a noncircular signal.

• Geomechanics and Engineering
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• v.14 no.4
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• pp.307-314
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• 2018

Strength of loess that experienced cyclic freeze and thaw is of great significance for evaluating stability of slopes and foundations in loess regions. This paper takes the frequently encountered loess in the Northwestern China as the study object and carried out three kinds of laboratory tests including freeze-thaw test, direct shear test and SEM test to investigate the strength behaviors of loess after cyclic freeze and thaw, and the correlation with meso-level changes in soil structure. Results show that for loess specimens at four dry densities, the cohesion decreases with freeze-thaw cycles until a residual value is reached and thus an exponential equation is proposed. Besides, little change in the angle of internal friction was observed as freeze-thaw proceeds. This may depend on the varying of soil structure, based on which a clue can be found from the surface morphology and mesoscopic scanning of loess specimens. Clearly we observed significant changes in surface morphology of loess and it tends to aggravate at higher water contents or more cycles of freeze and thaw. Moreover, freeze-thaw cycling leads to obvious changes in the meso-structure of loess including lowering the particle aggregates and increasing both the proportion of fine particles and porosity area ratio. A damage variable dependent on the ratio of porosity area is introduced based on the continuum damage mechanics and its correlation with cohesion is discussed.

• Earthquakes and Structures
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• v.8 no.3
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• pp.485-509
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• 2015

This paper presents the experimental results obtained by applying frequency-domain structural health monitoring techniques to assess the damage suffered on a special type of damper called Web Plastifying Damper (WPD). The WPD is a hysteretic type energy dissipator recently developed for the passive control of structures subjected to earthquakes. It consists of several I-section steel segments connected in parallel. The energy is dissipated through plastic deformations of the web of the I-sections, which constitute the dissipative parts of the damper. WPDs were subjected to successive histories of dynamically-imposed cyclic deformations of increasing magnitude with the shaking table of the University of Granada. To assess the damage to the web of the I-section steel segments after each history of loading, a new damage index called Area Index of Damage (AID) was obtained from simple vibration tests. The vibration signals were acquired by means of piezoelectric sensors attached on the I-sections, and non-parametric statistical methods were applied to calculate AID in terms of changes in frequency response functions. The damage index AID was correlated with another energy-based damage index -ID- which past research has proven to accurately characterize the level of mechanical damage. The ID is rooted in the decomposition of the load-displacement curve experienced by the damper into the so-called skeleton and Bauschinger parts. ID predicts the level of damage and the proximity to failure of the damper accurately, but it requires costly instrumentation. The experiments reported in this paper demonstrate a good correlation between AID and ID in a realistic seismic loading scenario consisting of dynamically applied arbitrary cyclic loads. Based on this correlation, it is possible to estimate ID indirectly from the AID, which calls for much simpler and less expensive instrumentation.

• Journal of the Earthquake Engineering Society of Korea
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• v.7 no.4
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• pp.51-61
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• 2003

This research is a park of a research program to develope a new design method for reinforced concrete bridge columns under axial load and cyclic lateral load. The objectives of this paper are to investigate the relationship between curvature ductility and displacement ductility and to propose a correlation equation for designing of reinforced concrete bridge columns under axial load and cyclic lateral load. Computer program NARCC was used for parametric study, which was proved to provide good and conservative analytical result especially for deformation capacity and ductility factor compared with test result. A total of 7,200 spirally reinforced concrete columns were selected considering the main variables such as section diameter, aspect ratio, concrete strength, yielding strength of longitudinal and confinement steel, longitudinal steel ratio, axial load ratio, and confinement steel ratio. A new equation between curvature ductility factor displacement ductility factor with the aspect ratio was proposed by investigation of 21,600 data produced from the selected column models by applying 3 different definitions of yield displacement.

• Structural Engineering and Mechanics
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• v.42 no.2
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• pp.153-174
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• 2012

Micromechanical facture models can be used to predict ductile fracture in steel structures. In order to calibrate the parameters in the micromechanical models for the largely used Q345 steel in China, uniaxial tensile tests, smooth notched tensile tests, cyclic notched bar tests, scanning electron microscope tests and finite element analyses were conducted in this paper. The test specimens were made from base metal, deposit metal and heat affected zone of Q345 steel to investigate crack initiation in welded steel connections. The calibrated parameters for the three different locations of Q345 steel were compared with that of the other seven varieties of structural steels. It indicates that the toughness index parameters in the stress modified critical strain (SMCS) model and the void growth model (VGM) are connected with ductility of the material but have no correlation with the yield strength, ultimate strength or the ratio of ultimate strength to yield strength. While the damage degraded parameters in the degraded significant plastic strain (DSPS) model and the cyclic void growth model (CVGM) and the characteristic length parameter are irrelevant with any properties of the material. The results of this paper can be applied to predict ductile fracture in welded steel connections.

• Structural Engineering and Mechanics
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• v.64 no.1
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• pp.11-21
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• 2017

It has been observed in the past that, the reinforced concrete (RC) bridge columns are very often subjected to torsional moment in addition to flexure and shear during seismic vibration. Ignoring torsion in the design can trigger unexpected shear failure of the columns (Farhey et al. 1993). Performance based seismic design is a popular design philosophy which calls for accurate prediction of the hysteresis behavior of structural elements to ensure safe and economical design under earthquake loading. However, very few investigations in the past focused on the development of analytical models to accurately predict the response of RC members under cyclic torsion. Previously developed hysteresis models are not readily applicable for torsional loading owing to significant pinching and stiffness degradation associated with torsion (Wang et al. 2014). The present study proposes an improved polygonal hysteresis model which can accurately predict the hysteretic behavior of RC circular and square columns under torsion. The primary curve is obtained from mechanics based softened truss model for torsion. The proposed model is validated with test data of two circular and two square columns. A good correlation is observed between the predicted and measured torque-twist behavior and dissipated energy.

• Proceedings of the KSME Conference
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• 2001.11a
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• pp.258-265
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• 2001

Turbine blade is subject to force of three type ; torsional force by torsion-mount, centrifugal force by rotation of rotor and cyclic bending force by steam pressure. Cyclic bending force of them is main factor on fatigue fracture. In the X-ray diffraction method, the change in the values related to plastic deformation and residual stress near the fracture surface mat be determined, and information of internal structure of material can be obtained. Therefore, to find a fracture mechanism of torsion-mounted blade in nuclear plant, based on the information from the fracture surface obtained by fatigue test, the correlation of X-ray parameter and fracture mechanics parameter was determined, and then the load applied to actual broken turbine blade parts was predicted. Failure analysis is performed by finite element method and Goodman diagram on torsion-mounted blade.

• Journal of the Korean Chemical Society
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• v.48 no.2
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• pp.151-155
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• 2004

The self-assembled mololayers(SAMs)were prepared with cysteine(cys) and subsequently coupled with dopamine(dopa) containing quinone functionality on the gold modified electrodes. The SAMs annealed in ethanol for 6 hours gave a better shaped cyclic voltammogram which had a 0.28 V of formal potential and same redox potential in 0.1M phosphate buffer(pH=7.10). The electrodes were employed to determine concentration of HADH with the result that calibration curve exhibited an excellent correlation(${\geq}$ 0.993) for the concentrations ranging up to 5.0${\times}10^{-4}$ M.

• Journal of the Korean Wood Science and Technology
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• v.43 no.5
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• pp.539-547
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• 2015

To investigate dimensional responses of wood under dynamic temperature condition, poplar (populous euramericana Cv.) specimens, 20 mm in radial (R) and tangential (T) directions with two thicknesses of 4 and 10 mm along the grain, were exposed to cyclic temperature changes in square wave between $25^{\circ}C$ and $40^{\circ}C$ at 60% relative humidity (RH) for three different cycling periods of 6 h, 12 h and 24 h. R and T dimensional changes measured during the cycling gave the following results: 1) Transverse dimensional changes of the specimens were generally square but at an opposite phase and lagged behind the imposed temperature changes. The phase lag was inversely correlated with cycling period, but positively related to specimen thickness, while the response amplitude was directly proportional to cycling period, but in a negative correlation with specimen thickness. 2) The specimens showed swelling hysteresis behavior. The heat shrinkage coefficient (HSC) became greater as cycling period increased or specimen thickness decreased. 3) Dimensional changes of the specimens produced deformation accumulation during repeated adsorption and desorption. The deformation accumulating ratio decreased with an increase in cycling period and specimen thickness. 4) Wood suffered 1.5 times as many dimensional changes per unit temperature variation as per unit humidity variation, and this deformation behaved even more seriously under static condition.