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Detection of Toxic Heavy Metal, Co(II) Trace via Voltammetry with Semiconductor Microelectrodes

  • Ly, Suw Young;Lee, Chang Hyun;Koo, Jae Mo
    • Toxicological Research
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    • v.33 no.2
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    • pp.135-140
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    • 2017
  • The cobalt (Co(II)) ion is a main component of alloys and considered to be carcinogenic, especially due to the carcinogenic and toxicological effects in the aquatic environment. The toxic trace of the Co(II) detection was conducted using the infrared photodiode electrode (IPDE) using a working electrode, via the cyclic and square-wave anodic stripping voltammetry. The results indicated a sensitive oxidation peak current of Co(II) on the IPDE. Under the optimal conditions, the common-type glassy carbon, the metal platinum, the carbon paste, and the carbon fiber microelectrode were compared with the IPDE in the electrolyte using the standard Co(II). The IPDE was found to be far superior to the others.

The Behaviors of Trace Metals (Fe, Mn, Co, Cu, Cd, Zn and Pb) in the Han River Estuary, Korea

  • Lee, Chang-Bok;Choi, Man-Sik
    • Journal of the korean society of oceanography
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    • v.36 no.3
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    • pp.59-71
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    • 2001
  • In order to investigate the temporal variability of dissolved and particulate trace metals in the Han River, water samples were collected intermittently at two sites for 3 years (August 91 to December 94). Surface seawaters covering the range of salinity were also collected at the estuarine region to evaluate the role of estuary for the riverine fluxes of trace metals within the estuary during October 95 and 96. During the study period, dissolved metal concentrations in riverwaters varied by a factor of 5-10 for Fe, Ni, Co and Cu and 50-100 for Mn, Cd and Pb depending upon the water level; high concentration during the low water and low concentration in high water period except for Fe. The concentration of dissolved Fe increased with increasing water discharge. These concentration-discharge relationships of the studied trace metals are explained by the successive dilution of waters from two different origins, which can be presumably identified as anthropogenic discharges and watershed flushing. Although estuarine waters at early mixing region were not collected due to the difficulty of sampling, mixing behaviors of metals were inferred from the concentration-salinity relationships through the laboratory mixing experiment and field sampling, and distribution coefficients between dissolved and labile particulate phases. It is suggested that the Han River estuary plays a role of accumulating Fe, Mn, Co and Pb from riverine sources due to high turbidity caused by strong tidal current, whereas this system serves as a source of dissolved Cd due to release caused by extended residence time of riverine particles.

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CALS System Development Methodology Using Document Trace Diagram and IDEF Model (Document Trace Diagram 과 IDEF 모델을 이용한 CALS 시스템 개발 방법론)

  • Kim, Soung-Hie;Cho, Sung-Sik;Lee, Jae-Kwang;Han, Chang-Hee;Yoon, Young-Suk
    • Asia pacific journal of information systems
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    • v.8 no.3
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    • pp.37-49
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    • 1998
  • The basic goal of CALS is to improve transactions and relationships among organizations through information sharing and integration. CALS is an information strategy which needs strong cooperation between organizations or between users and developers in design step. However, current design methodologies using IDEF models, that are considered to be standard for CALS system development, has some limitations. For example, it is difficult for system developers to communicate with counterparts by IDEF model since IDEF models are difficult for counterparts to understand. In this paper, we suggest a development methodology for GALS systems by complementing IDEF model with Document Trace Diagram, which we developed as a communication tool, The concept of Document Trace Diagram stems from the fact that most information exchanged within or between organizations is in the form of documents and most standard operating procedures of organizations are about processing the documents. It helps system developers identify functions and their ICOMs (Input, Control, Output, Mechanism) with ease and little communication cost. With this methodology, we have constructed the GALS prototype system for construction industry.

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Effect of Inorganic and Organic Trace Mineral Supplementation on the Performance, Carcass Characteristics, and Fecal Mineral Excretion of Phase-fed, Grow-finish Swine

  • Burkett, J.L.;Stalder, K.J.;Powers, W.J.;Bregendahl, K.;Pierce, J.L.;Baas, T.J.;Bailey, T.;Shafer, B.L.
    • Asian-Australasian Journal of Animal Sciences
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    • v.22 no.9
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    • pp.1279-1287
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    • 2009
  • Concentrated livestock production has led to soil nutrient accumulation concerns. To reduce the environmental impact, it is necessary to understand current recommended livestock feeding practices. Two experiments were conducted to compare the effects of trace mineral supplementation on performance, carcass composition, and fecal mineral excretion of phase-fed, grow-finish pigs. Crossbred pigs (Experiment 1 (Exp. 1), (n = 528); Experiment 2 (Exp. 2), (n = 560)) were housed in totally-slatted, confinement barns, blocked by weight, penned by sex, and randomly assigned to pens at approximately 18 kg BW. Treatments were allocated in a randomized complete block design (12 replicate pens per treatment) with 9 to 12 pigs per pen throughout the grow-finish period. In Exp. 1, the control diet (Io100) contained Cu as $CuSO_{4}$, Fe as $FeSO_{4}$, and Zn (of which 25% was ZnO and 75% was $ZnO_{4}$) at concentrations of 63 and 378 mg/kg, respectively. Treatment 2 (O100) contained supplemental Cu, Fe, and Zn from organic sources (Bioplex, Alltech Inc., Nicholasville, KY) at concentrations of 19, 131, and 91 mg/kg, respectively, which are the commercially recommended dietary inclusion levels for these organic trace minerals. Organic Cu, Fe, and Zn concentrations from O100 were reduced by 25% and 50% to form treatments 3 (O75) and 4 (O50-1), respectively. In Exp. 2, treatment 5 (Io25) contained 25% of the Cu, Fe, and Zn (inorganic sources) concentrations found in Io100. Treatment 6 (O50-2) was identical to the O50-1 diet from Exp. 1. Treatment 7 (O25) contained the experimental microminerals reduced by 75% from concentrations found in O100. Treatment 8 (O0) contained no trace mineral supplementation and served as a negative control for Exp. 2. In Exp. 1, tenth-rib backfat, loin muscle area and ADG did not differ (p>0.05) between treatments. Pigs fed the control diet (Io100) consumed less feed (p<0.01) compared to pigs fed diets containing organic trace minerals, thus, G:F was greater (p = 0.03). In Exp. 2, there were no differences among treatment means for loin muscle area, but pigs fed the reduced organic trace mineral diets consumed less (p<0.05) feed and tended (p = 0.10) to have less tenth-rib backfat compared to pigs fed the reduced inorganic trace mineral diet. Considering that performance and feed intake of pigs was not affected by lower dietary trace mineral inclusion, mineral excretion could be reduced during the grow-finish phase by reducing dietary trace mineral concentration.

Effects of dietary trace mineral levels on physiological responses, reproductive performance, litter performance, blood profiles, and milk composition in gestating sows

  • Hong Jun Kim;Xing Hao Jin;Sun Woo Kang;Yoo Yong Kim
    • Animal Bioscience
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    • v.36 no.12
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    • pp.1860-1868
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    • 2023
  • Objective: This study was conducted to evaluate the effects of optimal trace mineral levels on the physiological responses, reproductive performance, litter performance, blood profiles and milk composition in gestating sows. Methods: A total of 59 multiparous sows (Yorkshire×Landrace) with similar body weight (BW), backfat thickness (BF), and parity were assigned to one of four treatments with 14 or 15 sows per treatment using a completely randomized design. The treatments were 100% (M1), 300% (M3), 600% (M6), and 900% (M9) of the National Research Council (NRC) Nutrient Requirements of Swine. During lactation period, all the sows were fed the same commercial lactation diet. Results: No significant differences were observed in the BW, BF, reproductive performance, milk composition, or growth performance of the piglets. On day 70 of gestation, the serum zinc concentration showed a quadratic response to M6 treatment (quadratic, p<0.05). Moreover, as the dietary mineral levels increased, the zinc concentration increased linearly at 110 days of gestation (linear, p<0.05). Furthermore, copper and iron concentrations in the serum of sows at 24 h postpartum decreased linearly when high levels of dietary minerals were provided (linear, p<0.05). In the serum of piglets, serum zinc concentrations decreased linearly (linear, p<0.05), and iron concentration showed a quadratic response (quadratic, p<0.05) with an increase in trace mineral premix levels in gestation diets. Conclusion: The current trace mineral requirements of NRC (2012) are suitable for gestating sows, and the addition of dietary mineral levels in the gestating diet did not show any improvements during the gestation and lactation periods.

A Novel Integrated Generator Converter System for HVDC and Eddy Current of it's Solid Rotor Core (HVDC 송전을 위한 새로운 집적변환 발전기 계통과 그 회전자 중심의 와전류)

  • 이은웅;김일중;이민명
    • The Transactions of the Korean Institute of Electrical Engineers
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    • v.37 no.7
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    • pp.434-441
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    • 1988
  • This paper proposes a new invention of the integrated generator converter system for the HVDC transmission. And it analyses the general formula for eddy currents in the rotor iron using the double Fourier series in order to trace the smallest eddy current losses of the system which connects a new designed synchronous generator windings or conventional synchronous generator windings with the v Graetz bridges.

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A Study on High Power-Factor Control of Boost Type Rectifier Using Duty Cycle Pattern (듀티비 패턴을 이용한 승압형 정류기의 고역률 구현에 관한 연구)

  • Lee, Kyo-Beum;Lee, Kwang-Won
    • Proceedings of the KIEE Conference
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    • 1998.07f
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    • pp.1934-1936
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    • 1998
  • This paper proposes a new control scheme for enhanced power factor in the boost type AC/DC rectifier. The control scheme is to generate duty-cycle pattern without instantaneous measurement of the input line current. With a very simple controller structure the line current is forced to trace a sinusoid in phase with input voltage. The simulation results show the validity of the proposed control scheme.

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Comparison of Generation Amount and Operating Time for Fixed-concentrated Type and Single Axis Trace Type of Photovoltaic (고정식 및 단축식 태양광 발전의 발전량과 운전시간의 비교)

  • Song, Hwan-Kee;Lee, Kyung-Sup;Choi, Yong-Sung
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.28 no.11
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    • pp.743-747
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    • 2015
  • In this paper, the power generation efficiency of the 4 [kW] fixed-concentrated type photovoltaic power generation system and that of the 4 [kW] single axis trace type photovoltaic power generation system were compared. For that purpose, the two types of photovoltaic power generation systems have been in operation for 1 year on an experimental basis. The amounts of power generated by the two types during the months of January through December and the characteristics of their operating times during the same period have been compared and analyzed. For the study, the type with higher efficiency was selected and the following conclusions have been reached. It was shown that the amount of power generated and the average operation times during the spring months of March through May are higher that those of the summer months of June through August when more sunlight is available. The reason for this phenomenon is thought to be that as the temperatures of the solar panel surface and the surrounding environment go up, the electric current decreases.

Characteristics of Atmospheric Respirable Particulate Matters and Trace Elements within Industrial Complex and Residential Sites in an Industrial City (산업 도시의 산업단지 부지와 주거 지역의 대기 중 호흡성 분진과 구성 미량 원소의 특성)

  • Kim, Mo-Geun;Shin, Seung-Ho;Jo, Wan-Kuen
    • Environmental Analysis Health and Toxicology
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    • v.25 no.1
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    • pp.27-40
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    • 2010
  • The current study was designed to scientifically evaluate the atmospheric particulate pollution in residences relative to their proximity to a Korean major iron/metal industrial complex (IMIC). This objective was achieved by measuring the concentrations and elemental composition of particulate matter with aerodynamic diameters equal to or less than 10 ${\mu}m$(PM10) in industrial ambient air from IMIC and residential ambient air with relative proximities to IMIC. The trace metals were analyzed using an inductively coupled plasma-atomic emission spectroscopy (ICP-AES). The industrial mean values exceeded the Korean year/70-${\mu}g/m^3$ standard for PM10, whereas the residential mean values did not. However, the maximum residential values did exceed or were close to the Korean PM10 year standard. For individual elements, the ambient concentrations ranged widely from values in the order of a few $ng/m^3$ to thousands of $ng/m^3$. The residential mean mass concentrations in the PM10 measured in the present study were higher than or similar to those reported in earlier studies. This study suggests that residents in neighborhoods near the IMIC are exposedto elevated particulate levels compared to residents living further away from such a source.

Analysis of Zirconium and Nickel Based Alloys and Zirconium Oxides by Relative and Internal Monostandard Neutron Activation Analysis Methods

  • Shinde, Amol D.;Acharya, Raghunath;Reddy, Annareddy V.R.
    • Nuclear Engineering and Technology
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    • v.49 no.3
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    • pp.562-568
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    • 2017
  • Background: The chemical characterization of metallic alloys and oxides is conventionally carried out by wet chemical analytical methods and/or instrumental methods. Instrumental neutron activation analysis (INAA) is capable of analyzing samples nondestructively. As a part of a chemical quality control exercise, Zircaloys 2 and 4, nimonic alloy, and zirconium oxide samples were analyzed by two INAA methods. The samples of alloys and oxides were also analyzed by inductively coupled plasma optical emission spectroscopy (ICP-OES) and direct current Arc OES methods, respectively, for quality assurance purposes. The samples are important in various fields including nuclear technology. Methods: Samples were neutron irradiated using nuclear reactors, and the radioactive assay was carried out using high-resolution gamma-ray spectrometry. Major to trace mass fractions were determined using both relative and internal monostandard (IM) NAA methods as well as OES methods. Results: In the case of alloys, compositional analyses as well as concentrations of some trace elements were determined, whereas in the case of zirconium oxides, six trace elements were determined. For method validation, British Chemical Standard (BCS)-certified reference material 310/1 (a nimonic alloy) was analyzed using both relative INAA and IM-NAA methods. Conclusion: The results showed that IM-NAA and relative INAA methods can be used for nondestructive chemical quality control of alloys and oxide samples.