• Journal of the Korean Chemical Society
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• v.15 no.5
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• pp.223-228
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• 1971

In the electrolytic preparation of persulphate from sulphate solution, the current efficiency decrease with temperature increase at the platinum anode. But in case of electrodeposited lead peroxide anode, the current efficiency increase with temperature of the solution. The reason seems to be that the ozone formation is faster in platinum anode than in lead peroxide as temperature increase.

• Journal of the Korean Chemical Society
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• v.15 no.3
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• pp.127-132
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• 1971

To obtain the various kinds of inosose stereomers, the process of electrochemical oxidation is more effective than chemical oxidation of myo-inositol. So that myo-inositol aqueous solution was electrolyzed by platinum and lead peroxide anode to confirming the occurrence of electrochemical oxidation. The result is that myo-inosose-2 is producing with high yield comparatively by electrolytic oxidation of myo-inositol. Also we studied about the relation between the electrolytic current efficiency and electrolytic temperature and anodic current density. The current efficiency is rising with lowering of electrolytic temperature identically in both anode such as platinum and lead peroxide and also rising with increasing of anodic current density in platinum anode, but inversely in lead peroxide.

• 한국초전도학회:학술대회논문집
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• v.10
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• pp.236-240
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• 2000

Bi-2223 HTS current leads for a superconducting magnetic energy storage(SMES) magnet were designed and manufactured. The HTS leads composed of Bi-2223/AgAu tapes and stainless steel former were connected to conventional vapor-cooled copper leads. The heat input to the liquid helium through the HTS lead was 0.39 W/lead when the warm end part's temperature is 65 K. And, the critical current of the HTS leads was about 1.6 kA when the warm end part's temperature is 80 K. The measured those values are well consistent with computed values.

• Journal of Power Electronics
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• v.14 no.3
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• pp.541-548
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• 2014

This paper presents a simple lead angle adjustment method for brushless DC motors. The proposed method is based on the motor current dynamics analysis during the current commutation interval. With the proposed scheme, the phase current and phase back-EMF voltage are in phase and the BLDC motor and drive system have a high efficiency induced by the reduced copper and conduction losses. Experimental results are shown to validate the proposed method.

• Journal of the Korean Institute of Telematics and Electronics S
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• v.36S no.2
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• pp.120-130
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• 1999

In this paper, we show that the instantaneous phase current of the bifiler-wound hybrid stepping motor is dependent of lead angle and that the information of motor position is obtained from the instantaneous phase current at ${\pi}/2$ by the theoretical formular and its computer simulation results. From the facts, we design the microcontroller-based motor position sensorless controller of optimal lead angle, which generates the excitation pulses for the closed-loop drives. The controller is consist of microcontroller which has the function of A/D converter, programmable input/output timer, and the transfer table which has the values of optimal lead angle depending on motor velocity, and ROM which has the transfer table of the values of lead angle depending on velocity of motor and the values of instantaneous phase current at ${\pi}/2$. From the design of microcontroller-based controller, we minimize the external interface circuit and obtain flexibility by changing the contents of ROM transfer tables and the control software. We confirm that the designed controller drives the bifilar-wound hybrid stepping motor is the mode of optimal lead angle by comparing the instananeous phase current experimental results and computer simulation results.

• Journal of the Korean Applied Science and Technology
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• v.33 no.3
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• pp.568-574
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• 2016

In this study, the mixing method of positive paste and mixing temperature to improve the capacity of the lead-acid batteries has been investigated. The results show that the initial current capacity of lead acid battery depend on the mixing temperature and mixing method of positive paste. In the results of the capacity cycle repetition tests for estimating the life cycle, the 3BS showed the PCL. but the fine 4BS represented certain improved cycles compared to that of the coarse 4BS. It was considered that the fine 4BS showed higher bond strength between active materials than the coarse 4BS and represented large contact areas and that lead to prevent possible sulfation due to the suppression of insulating layers.

• Journal of the Korean Chemical Society
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• v.6 no.2
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• pp.108-112
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• 1962

Lead ion gives a well-defined wave with $E_{1/2}$=-0.57V(vs. S.C.E.) from a base electrolyte consisting of 0.1M TEA=0.5M$KNO_3$=0.0002% methl red. (pH 9.8).The reduction wave of lead is lead(II) to lead(0) and electrode reaction of this wave diffusion controlled.Its diffusion current constant is 2.45 and temperature coefficient of this wave is about 1.2%.Under above conditions, diffusion current is proportional to the concentration of lead in the range of $10^{-3}$ ~$10^{-4}$ M.

• Journal of the Korean institute of surface engineering
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• v.19 no.3
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• pp.92-108
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• 1986

An electroplating on the lead frame fabricated from domestic copper plate was studied experimentally. In this study, nickel was plated on the thin copper lead frame and silver layer was coated on the nickel film in the cyanide electrolyte. The effect of process variables such as current density, plating time, coating thickness and flow rate of electrolytic solution on the properties of coating was investigated. Some samples on each step were fabricated during electroplating. The results obtained from polarization measurement, observation of SEM photograph, adhesion test of coating and microhardness test are as follows. On silver plating, polarization resistance of potentiostatic cathodic polarization curve is reduced as the flow rate of Ag electrolytic solution increases. And above resistance is also reduced when the minor chemicals of sodium cyanide and sodium carbonate are added in potassium silver cyanide bath. The reduced polarization resistance makes silver deposition on the cathode easy. An increase in the current density and the coating thickness causes the particle size of deposit to coarsen, and consequently the Knoop microhardness of the coating decreases. On selective plating an increase in the flow rate of plating solution lead to do high speed plating with high current density. In this case, the surface morphology of deposit is of fine microstructure with high Knoop hardness. An increasing trend of the adhesion of coating was shown with increasing the current density and flow rate of electrolytic solution.

• Journal of the Korean Chemical Society
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• v.13 no.2
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• pp.165-169
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• 1969

On the electrolytic preparation of sodium chlorate, lead dioxide anode, instead of graphite was tested to find out the characteristics for current efficiency and life in various conditions. The results obtained are summerized as follows; 1. The current efficiency is slightly increased with the anode current density, until 25A/$dm^2$ 2. The higher the current concentrations. the lower current efficiencies are observed, particularly in case of both not-adding the potassium dichromate and large current concentration of more than 50A/l 3. The current efficiency may be improved linearly as the both temperature is raised.

• Applied Chemistry for Engineering
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• v.7 no.2
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• pp.280-288
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• 1996

In the ozone evolution using $PbO_2$, which was electrodeposited on Ti plate at various conditions in electrolyte, the effects of lead dioxide structure on the current efficiency and surface structure changes of lead dioxide were investigated. Also the effects of oxygen transfer reaction on the ozone evolution were investigated by means of a $PbO_2$ electrodeposited on the platinum rotating disk electrode. In order to develope an electrode for ozone evolution, durability of lead dioxide and optimum current density were investigated. At the electrodeposited lead dioxide with the larger grain size and higher crystallinity, the efficiency for ozone evolution was higher. Optimum current density to electrodeposite lead dioxide with large grain size and high crystalinity was $50mA/cm^2$. Lead dioxide deposited in the presence of glycerin showed the best advantage of ozone evolution. Also lead dioxide electrodeposited at less than $10mA/cm^2$ or at more than $100mA/cm^2$ has poor performance of ozone evolution and poor adhesive strength to substrate. In the beginning of ozone evolution, surface structure of lead dioxide was changed and this change resulted in good effects on ozone evolution. Lead dioxide doped with other elements was favorable not to ozone evolution but to oxygen evolution, so it is speculated that ozone evolution has not intermediate stage of oxygen evolution and occurs competitively with oxygen evolution. When ozone was evolved at $0.7{\sim}0.8A/cm^2$, the current efficiency was highest.