Synthesis of Cyclitol Derivatives (Ⅲ). Electrolytic Oxidation of myo-Inositol

Cyclitol 유도체 합성에 관한 연구 (제3보)-myo-Inositol의 전해 산화-

  • Joo Hwan Sohn (Department of Chemical Engineering, Inha Institute of Technology) ;
  • Chong Woo Nam (Department of Chemical Engineering, Inha Institute of Technology) ;
  • Yu Ok Kim (Department of Chemical Engineering, Inha Institute of Technology)
  • 손주환 (인하공과대학 화학공학과) ;
  • 남종우 (인하공과대학 화학공학과) ;
  • 김유옥 (인하공과대학 화학공학과)
  • Published : 1971.06.30

Abstract

To obtain the various kinds of inosose stereomers, the process of electrochemical oxidation is more effective than chemical oxidation of myo-inositol. So that myo-inositol aqueous solution was electrolyzed by platinum and lead peroxide anode to confirming the occurrence of electrochemical oxidation. The result is that myo-inosose-2 is producing with high yield comparatively by electrolytic oxidation of myo-inositol. Also we studied about the relation between the electrolytic current efficiency and electrolytic temperature and anodic current density. The current efficiency is rising with lowering of electrolytic temperature identically in both anode such as platinum and lead peroxide and also rising with increasing of anodic current density in platinum anode, but inversely in lead peroxide.

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