Journal of the Korean Chemical Society (대한화학회지)

Korean Chemical Society (대한화학회)
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The Statistical Thermodynamic Approach to the Liquid-Vapor Interface of Binary Solution

이성분 용액의 액체-증기 계면에 대한 통계 열역학적 연구

  • Hyungsuk Park (Department of Chemistry, College of General Studies, Seoul National University)
  • 박형석 (서울대학교 교양과정부 화학과)
  • Published : 1971.06.30
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Abstract

A method of theoretical calculation of the thermodynamic properties for liquid-vapor interface of binary solution is developed according to the transient state theory of significant liquid structure. The surface tensions, the adsorbed amounts at the liquid-vapor interface and the activity coefficients of the components for the solutions of $C_6H_{12}-C_6H_6$ $CCI_4-C_6H_6$, $CHCl_3-C_6H_6$, $CHCl_3-CCl_4$, $CCl_4-CS_2$ are calculated through the full ranges of the compositions.

액체구조의 천이상태이론을 이성분용액의 액체-증기 계면에 적용하여, $C_6H_{12}-C_6H_6$ $CCI_4-C_6H_6$, $CHCl_3-C_6H_6$, $CHCl_3-CCl_4$, $CCl_4-CS_2$계의 표면장력, 표면흡착량, 표면에서의 활동도 계수들을 계산하였다.

Keywords

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