• 제목/요약/키워드: curing agent

검색결과 429건 처리시간 0.028초

국내 시판 방동제의 품질 특성에 관한 조사 (Study on the Quality Properties of Anti Freeze Agent manufactured in Korea)

  • 이건철;노상균;조병영;김영근
    • 한국콘크리트학회:학술대회논문집
    • /
    • 한국콘크리트학회 2010년도 춘계 학술대회 제22권1호
    • /
    • pp.333-334
    • /
    • 2010
  • 본 연구에서는 국내 생산 판매되는 각종 방동제를 수집하여 품질특성에 대하여 검토하였으며, 구체적으로 방동제 사용에 따른 저온양생 모르타르의 강도 회복 특성에 대하여 검토하였다. 종류별 약간의 차이는 있지만 대부분의 방동제가 저온양생기간의 배합수의 동결온도 저하를 방지하는 것으로 나타났다.

  • PDF

DMDHEU/PEG와 분산염료를 이용한 면/폴리에스테르 혼방직물의 염색 (Dyeing of Cotton/Polyester Blends with Disperse Dyes in the Presence of DMDHEU/PEG)

  • 김은아;유효선
    • 한국의류학회지
    • /
    • 제24권7호
    • /
    • pp.1025-1034
    • /
    • 2000
  • Cotton differs from polyester in physical and chemical properties. When cotton/polyester blends are dyed, water-soluble dyes are generally used for cotton and disperse dye for polyester. Thus, two bath or one bath-two step dyeing process are usually accepted. These processes consume more energy and cost compared to a single step process. To save energy and cost, a single step dyeing and finishing is carried out with disperse dyes in the presence of a crossslinking agent. K/S values of the dyed fabrics were determined to examine the dyeing property of cotton, cotton/polyester, polyester fabrics dyed with disperse dyes in the presence of DMDHEU/PEG. The concentration of DMDHEU, molecular weight and concentration of PEG, curing time and curing temperature were varied.

  • PDF

에폭시 수지의 경화에 따른 온도 특성 (The Temperature Characteristics of Epoxy Resin by Curing Time)

  • 이진;이은학;임영철;이계호;박종건;김태성
    • 대한전기학회:학술대회논문집
    • /
    • 대한전기학회 1988년도 전기.전자공학 학술대회 논문집
    • /
    • pp.771-773
    • /
    • 1988
  • The Mechanical strength and the electrical insulation properties of the Epoxy Resin vary with the formation of chemical reactions between Epoxy and curing agent. Therefore, to study their reactions is important for understanding the properties of the cured Epoxy. In this paper, to get the cured Epoxy having good electrical insulation property, it is studied the effects of the surrounding temperature during the cure process on the property of the cured Epoxy. In the experiment, Epoxy is cured with the surrounding temperature varied between -5[$^{\circ}C$] to 50[$^{\circ}C$]. As the results, it follows that the higher the temperature is, the faster the cross-link process is.

  • PDF

m-Tluate를 분해하는 Peudomonas의 분리 및 Dgradative Pasmid와의 연관성에 관하여 (Studies on the m-Toluate Degradating Plasmid in Pseudomonas)

  • 박순희;하영칠;홍순우
    • 미생물학회지
    • /
    • 제17권1호
    • /
    • pp.25-41
    • /
    • 1979
  • A strain able to grow up m-toluate minimal medium has been isolated after selective enrichment and given the name T81X, which was later identified as pseudomonase putida according to its morphological and biochemical characteristics. After treatment with plasmied specific curing agent, mitomycin C, followed by replica plating on m-toluate and xylene minimal agar plate, T81Xstrain has been shown to harbour a curable plasmid relating to the m-toluate and xylene metabolism. Spontaneous curing frquency of this plasmid was also greatly enhanced by growing on benzoate minimal medium. After then, it was also xylene metabogrowing on benzoate minimal medium. After then, it was found to be conjugally nontransmissible. From the comparative investigation of catechol 1,2-oxygenase and catechol 2,3-oxygenase activities in wild type and cured strain on various growth substrate, it appeared that T81X strain has both of these two enzymes while cured strain has catechol 1,2-oxygenase only. Growing on m-toluate minimal medium T81X strain should carry the genetic information necessary for coding the catechol 1,2-oxygense induced by m-toluate or benzoate, on that curable plasmid.

  • PDF

Analysis of Peroxide Curing Agents in EVA Compounds and Vulcanizates

  • Chae, Eunji;Choi, Sung-Seen
    • Elastomers and Composites
    • /
    • 제55권1호
    • /
    • pp.6-12
    • /
    • 2020
  • Poly(ethylene-co-vinyl acetate) compounds and vulcanizates containing dicumyl peroxide (DCP) (HD) were prepared, and the curing agent and reaction products were analyzed using gas chromatography/mass spectrometry (GC/MS). Samples containing trially cyanurate (TAC) and DCP (HDT) were also prepared and analyzed. Some raw DCP were decomposed in the injector region of GC to produce acetophenone. DCP was detected in the HD compound but was not observed in the HD vulcanizate, and instead acetophenone and 2-phenyl-2-propanol were detected. Both DCP and TAC were observed in the HDT compound but not in the HDT vulcanizate, where acetophenone and 2-phenyl-2-propanol were detected. Thus, some of the DCP decomposed during the compounding process. The formation mechanism for acetophenone and 2-phenyl-2-propanol during the crosslinking reaction was identified, and differences in the crosslinking reactions of HD and HDT compounds were discussed.

액상봉지재용 Diglycidyl Ether of Bisphenol F/Nadic Methyl Anhydride 수치 시스템의 경화 및 유변학적 거동 (The Cure and Rheological Behavior of Diglycidyl Ether of Bisphenol F /Nadic Methyl Anhydride Resin System for Liquid Encapsulant)

  • 김윤진;김창제;윤호규
    • 한국마이크로전자및패키징학회:학술대회논문집
    • /
    • 한국마이크로전자및패키징학회 2002년도 춘계 기술심포지움 논문집
    • /
    • pp.152-157
    • /
    • 2002
  • The cure and rheological behavior of Diglycidyl ether of bisphenol F, catalyzed by four kinds of imidazoles and a Nadic methyl anhydride curing agent were studied using a differential scanning calorimeter (DSC) and rheometer. The isothermal traces were employed to analyze cure reaction. The DGEBF/anhydride conversion profiles showed autocatalyzed reaction characterized by maximum conversion rate at 20~40 % of the reaction. The rate constants obtained from isothermal test showed temperature dependance, but reaction order did not. The order of reaction (m+n) was calculated to be close to 3. The measurements of viscosity and relation time in the presence of inorganic fillers were carried out at different isothermal curing temperatures. The viscosity and gelation time increased with filler content at the same isothermal temperature.

  • PDF

임프린트 공법적용을 위한 절연재료의 열적, 기계적 성질 (Thermal stabilities and dynamic mechanical properties of dielectric materials for thermal imprint lithography)

  • 조재춘;나승현
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 2007년도 하계학술대회 논문집 Vol.8
    • /
    • pp.220-221
    • /
    • 2007
  • Recently, imprint lithography have received significant attention due to an alternative technology for photolithography on high performance microelectronic devices. In this work, we investigated thermal stabilities and dynamic mechanical properties of dielectric materials for thermal imprint lithography. Curing behaviours, thermal stabilities, and dynamic mechanical properties of the dielectric materials cured with various curing agent and spherical filler were studied using dynamic differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), rheometer and universal test machine(UTM).

  • PDF

3급아민기 함유 아크릴수지 합성과 에폭시실란 경화형 도료의 도막 물성 (Preparation and Physical Properties of Acrylic Resin Coatings Containing Tertiary Amine and Epoxysilane Curing Agent)

  • 김성길;박형진
    • 한국건축시공학회:학술대회논문집
    • /
    • 한국건축시공학회 2021년도 가을 학술논문 발표대회
    • /
    • pp.164-165
    • /
    • 2021
  • To prepare the good-adherent and weather-resistant acrylic resin coatings, acrylic resin was prepared by a radical polymerization. Glass transition temperature(Tg) of the acrylic copolymer was fixed at 30℃ and the contents of tertiary amine monomer(DMAEMA) was varied to be 5, 10, 15, 20 wt% respectively. γ-Glycidoxypropyltrimethoxysilane(GPTMS) containing epoxy group was used for curing agents and di-n-butyltindilaurate(DBTDL) was used for drying accelerator. The equivalent ratio of amine to epoxy was 1:1. The prepared coatings exhibited excellent adhesion to various substrates, and various physical properties of the coatings were satisfactory. The gloss retention and color difference were improved at low tertiary amine concentration. The coatings containing 10wt% tertiary amine concentration have especially good weather resistant properties.

  • PDF

느슨한 모래지반 개량을 위한 간편고화재의 최적 배합비 및 혼합률 (Optimum Conditions of Simple Solidifying Agent for the Improvement of Loose Sand Ground)

  • 권호진;정기룡
    • 한국지반환경공학회 논문집
    • /
    • 제5권2호
    • /
    • pp.15-21
    • /
    • 2004
  • 본 연구는 느슨한 모래지반에 간편하게 혼합 또는 주입하여 단시간에 고결되는 지반고화재를 개발하는 데 있으며, 지반고화재의 주성분으로 사용한 마이크로시멘트의 공학적 특성을 검토하고, 지반고화재가 최적의 강도와 유동성을 발휘할 수 있는 마이크로시멘트, 벤토나이트, 화학혼화제 등에 대한 최적의 배합비 및 혼합률을 실험을 통하여 구하였다. 시험결과로부터 느슨한 사질토지반의 개량을 위하여 본 연구에서 사용한 간편고화재는 마이크로시멘트 : 벤토나이트의 배합비가 70% : 20%, 고화재 혼합률은 8%, 양생기간 5일 정도일 때 효과적인 유동성과 강도를 발휘하는 것으로 판단되었다.

  • PDF

Novel thermoplastic toughening agents in epoxy matrix for vacuum infusion process manufactured composites

  • Bae, Jin-Seok;Bae, Jihye;Woo, Heeju;Lee, Bumjae;Jeong, Euigyung
    • Carbon letters
    • /
    • 제25권
    • /
    • pp.43-49
    • /
    • 2018
  • This study suggests the novel thermoplastic toughening agent, which can be applied in the monomer forms without increasing the viscosity of the epoxy resin and polymerized during the resin curing. The diazide (p-BAB) and dialkyne (SPB) compounds are synthesized and mixed with the epoxy resin and the carbon fiber reinforced epoxy composites are prepared using vacuum infusion process (VIP). Then, flexural and drop weight tests are performed to evaluate the improvement in the toughness of the prepared composites to investigate the potential of the novel toughening agent. When 10 phr of p-BAB and SPB is added, the flexural properties are improved, maintaining the modulus as well as the toughness is improved. Even with a small amount of polytriazolesulfone polymerized, due to the filtering effect of the solid SPB by the layered carbon fabrics during the VIP, the toughening and strengthening effect were observed from the novel toughening agent, which could be added in monomer forms, p-BAB and SPB. This suggests that the novel toughening agent has a potential to be used for the composites prepared from viscosity sensitive process, such as resin transfer molding and VIP.