• 제목/요약/키워드: cure conditions

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The Effect of ATH and Sb$_2$O$_3$on the Flammability and Mechanical Properties of Fiber Reinforced Plastics (ATH, Sb$_2$O$_3$조성에 따른 복합재료의 난연특성)

  • 강길호;최원종;김진곤;권경옥;박상윤;사공성호;김해형
    • Fire Science and Engineering
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    • v.16 no.4
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    • pp.65-71
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    • 2002
  • In this paper, the thermal and flame properties of GFRP with various flame retardant(aluminum trihydrate, antimony trioxide) compositions have been investigated by thermal analysis and flammability tests(LOI test, flammability 45 degree test). The flame and mechanical properties(hardness, tensile strength, modulus) of general purpose grade glass fiber/unsaturated polyester composite with flame retardant composition have been also evaluated. The effect of cure pressure on the flame properties of aerospace grade glass fiber/epoxy composite was investigated. Considering the flame and mechanical property of composite, we could determine the optimum flame retardant composition(ATH 10∼20 phr). Test results show that the flame property of glass fiber/epoxy composite is considerably affected by cure pressure conditions.

Characterization of Dicyclopentadiene and 5-Ethylidene-2-norbornene as Self-healing Agents for Polymer Composite and Its Microcapsules

  • Lee, Jong-Keun;Hong, Sun-Ji;Xing Liu;Yoon, Sung-Ho
    • Macromolecular Research
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    • v.12 no.5
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    • pp.478-483
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    • 2004
  • Two different diene monomers [dicyclopentadiene (DCPD) and 5-ethylidene-2-norbornene (ENB)] as self-healing agents for polymeric composites were microencapsuled by in situ polymerization of urea and formaldehyde. We obtained plots of the storage modulus (G') and tan $\delta$ as a function of cure time by using dynamic mechanical analysis to investigate the cure behavior of the unreacted self-healing agent mixture in the presence of a catalyst. Glass transition temperatures (T$\_$g/) and exothermic reactions of samples cured for 5 and 120 min in the presence of different amounts of the catalyst were analyzed by differential scanning calorimetry. Of the two dienes, ENB may have advantages as a self-healing agent because, when cured under same conditions as DCPD, it reacts much faster in the presence of a much lower amount of catalyst, has no melting point, and produces a resin that has a higher value of T$\_$g/. Microcapsules containing the healing agent were successfully formed from both of the diene monomers and were characterized by thermogravimetric analysis. Optical microscopy and a particle size analyzer were employed to observe the morphology and size distribution, respectively, of the microcapsules. The microcapsules exhibited similar thermal properties as well as particle shapes and sizes.

A COMPARATIVE STUDY ON THE ANTICARIOGENICITY OF ENAMEL SURFACE ADJACENT TO RESIN RESTORATION POLYMERIZED BY VISIBLE LIGHT OR ARGON LASER. (가시광선과 아르곤 레이저에 의해 중합된 레진 수복물 주변 법랑질의 항우식효과에 관한 비교연구)

  • Park, Young-Soo;Kim, Jong-Soo;Kim, Yong-Kee
    • Journal of the korean academy of Pediatric Dentistry
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    • v.23 no.4
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    • pp.840-858
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    • 1996
  • The main purpose of this study was to evaluate the anticariogenic effect of argon laser. Histological observations on lesion initiation and progression were performed under the polarized microscope. The results from the present study can be summarized as follows; 1. The specimens of laser cured group were shown to have more irregular and discontinuous lesion body in general than visible light cured group with rather continuous positive birefringence. 2. With lesion initiation and progression, almost all the specimens showed deeper body of lesion with shallower intact surface zone in the visible light cured group than the laser cured group(p<0.05). When the comparision was made between the two argon laser cured groups, the single-cure group showed deeper lesion body and the shallower surface layer than double-cure group. 3. Based upon the above mentioned results of this study, it can be assumed that the use of argon laser in the procedure of resin polymerization may provide the child and adolescent patient population with anticariogenic effect as well as efficient polymerization. Further studies using various materials and experimental conditions are being encouraged.

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Effect of Cross-Linking Characteristic on the Physical Properties and Storage Stability of Acrylic Rubber

  • Seong-Guk Bae;Min-Jun Gim;Woong Kim;Min-Keun Oh;Ju-Ho Yun;Jung-Soo Kim
    • Elastomers and Composites
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    • v.58 no.3
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    • pp.136-141
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    • 2023
  • Polyacrylic rubber (ACM) is well known for its excellent heat resistance and chemical stability. Additionally, its performance can be readily manipulated by modifying its functional groups, rendering it highly attractive to various industries. However, extreme climate changes have necessitated an expansion of the operating temperature range and lifespan of ACM products. This requires the optimization of both the compounding process and functional-group design. Hence, we investigated the relationship between the cross-linking system and mechanical properties of an ACM with a carboxylic cure site. The crosslink density is determined by chemical kinetics according to the structure of additives, such as diamine crosslinkers and guanidine accelerators. This interaction enables the manipulation of the scotch time and mechanical properties of the compound. This fundamental study on the correlation analysis between cross-linking systems, physical properties, and storage stability can provide a foundation for material research aimed at satisfying the increasingly demanding service conditions of rubber products.

Experience of Discharge from Rehabilitation Facility (경수완전손상환자의 재활병동생활 경험 - 퇴원을 중심으로 -)

  • Yee, Oon-Hee
    • The Korean Journal of Rehabilitation Nursing
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    • v.14 no.1
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    • pp.13-23
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    • 2011
  • Purpose: The purpose of this study was to explore and describe the essence of hospital life concerning discharge from rehabilitation facility as defined by clients with complete quadriplegia. Method: This was a qualitative research using Giorgi's descriptive phenomenology. Four participants with complete quadriplegia were participated. Results: The lived experience of discharge from rehabilitation facility among clients with complete quadriplegia was structured by 10 components and was defined as a life event which those patients felt fears and worries to leave the therapeutic environment and to return to their community with various changes due to their disability. During their hospital stay, the patients with quadriplegia were concerning to prepare proper living conditions and their health conditions so that they could keep their life independent and worthy. They also cherished a hope for cure for their cervical injury even at the moment of discharge. Conclusion: This study suggests developing a discharge program which relieves the clients' emotional burden for discharge from inpatient rehabilitation facility and helps them to take an active role in preparing for returning to their daily life.

Effect of DP Finishing Conditions on the Mechanical Properties and Hand of Cotton Fabrics (DP 가공조건이 면직물의 역학적 성질과 태에 미치는 영향)

  • 신윤숙
    • Journal of the Korean Society of Clothing and Textiles
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    • v.24 no.3
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    • pp.440-447
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    • 2000
  • The effects of DP finishing conditions including process technique and finishing agent on the mechanical properties and hand of cotton fabrics were investigated. 100% cotton fabrics were treated with NMA/DMDHEU and NMA/YF using wet-fixation and steam-fixation process. For comparison, conventional pad-dry-cure process was used with DMDHEU. After DP finishing, tensile and compressional resilience increased and bending hysteresis decreased, resulting in the improvement of dimensional stability of cotton fabric. WF and SF process rendered fabrics better shear properties, tensile energy, and compressional linearity and energy than PDC process. However, SF process produced fabrics with higher geometrical roughness than WF process. After DP finishing, primary hand values except Koshi increased, resulting in the increase of total hand value of cotton fabric.

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A Study on Laser Micro-Patterning using UV Curable Polymer (광경화성 폴리머를 이용한 레이저 미세패터닝의 기초연구)

  • 김정민;신보성;김재구;장원석;양성빈
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2003.06a
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    • pp.612-615
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    • 2003
  • Maskless laser patterning process is developed using 3rd harmonic Diode Pumped Solid State Laser with near visible wavelength of 355 nm. Photo-sensitive curable polymer is irradiated by UV laser and developed using polymer solvent to obtain quasi-3D patterns. We performed basic experiments for the various process conditions such as laser power, writing speed, laser focus, and polymer optical property to gain the optimal conditions. Experimentally, the patterns of trapezoidal shape were manufactured into dimension of 8${\mu}{\textrm}{m}$ width and 5.4${\mu}{\textrm}{m}$ height. This process could be applied to fabricate a single mode waveguide without expensive mask projection method.

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A Study on the Grinding Characteristics of the Carbon Fiber Epoxy Composite Materials with the Vitrified Bonded Wheel (탄소섬유 에폭시 복합재료 연삭숫돌 선정에 관한 연구)

  • 한흥삼
    • Composites Research
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    • v.13 no.5
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    • pp.44-49
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    • 2000
  • Although the net-shape molding of composites is generally recommended, molded composites frequently requires cutting or grinding due to the dimensional inaccuracy for precision machine elements. The surface roughness and cutting force were also measured to investigate the surface grinding characteristics of the composites using the vitrified bonded wheel (WA, GC). The experiments were performed dry grinding conditions with respect to cutting speed, feed speed, depth of cut of the stacking sequence $[O]_{nT.}$ From the experimental investigation, the optimal conditions both the vitrified bonded wheel WA and GC for the surface grinding are suggested.

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A Study on the Surface Grinding Temperature Characteristics of the Carbon Fiber Epoxy Composite Materials (탄소섬유 에폭시 복합재료의 평면 연삭온도 특성에 관한 연구)

  • 한흥삼
    • Proceedings of the Korean Society of Machine Tool Engineers Conference
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    • 2000.04a
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    • pp.441-446
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    • 2000
  • Although the net-shape molding of composites is generally recommended, molded composites frequently required cutting or grinding due to the dimensional inaccuracy for precision machine elements. During the composite machining operations such as cutting and grinding, the temperature at the grinding area may increase beyond the allowed limit due to the low thermal conductivity of composites, which might degrade the matrix of composite. Therefore, in this work, the temperature at the grinding point during surface grinding of carbon fiber epoxy composite was measured. The grinding temperature and surface roughness were also measured to investigate the surface grinding characteristics of the composited. The experiments were performed both under dry and wet grinding conditions with respect to cutting speed, feed speed, depth of cut and stacking angle. From the experimental investigation, the optimal conditions for the composite plain grinding were suggested.

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A Study on the Grinding Characteristics of the Carbon Fiber Epoxy Composite Material Grinding Temperature (탄소섬유 에폭시 복합재료 연삭온도에 의한 연삭특성)

  • 한흥삼;이동주
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.9 no.6
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    • pp.65-70
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    • 2000
  • Although the net-shape molding of composites is generally recommended, molded composites frequently requires cutting or grinding due to the dimensional inaccuracy for precision machine elements. During the composite machining operations such as cutting and grinding, the temperature at the grinding area may increase beyond the allowed limit due to the low thermal conductivity of composites, which might degrade the matrix of composite. Therefore, in this work, the temperature at the grinding point during surface grinding of carbon fiber epoxy composite was measured. The grinding temperature and surface roughness were also measured to investigate the surface grinding characteristics of the composites. The experiments were performed both under dry and wet grinding conditions with respect to cutting speed, feed speed, depth of cut and stacking angle. From the experimental investigation, the optimal conditions for the composite surface grinding were suggested.

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