• 제목/요약/키워드: cubic property

검색결과 84건 처리시간 0.027초

바이컨티니어스 큐빅상 액정의 생성과 자기조직화 (Self Assembly and Formation of Bi-continuous Cubic Liquid Crystalline Phase)

  • 김인영;최화숙;이소라;최성호
    • 한국응용과학기술학회지
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    • 제31권3호
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    • pp.478-485
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    • 2014
  • 이 연구는 경표피흡수를 위하여 큐빅액정의 자기조직체의 형성에 관한 것이다. 복수 수산기(-OH)를 가지는 친수부에 4개의 메칠 그룹을 가지는 양친매성지질인 diglyceryl phytylacetate (DGPA)를 합성하여 다양한 성능평가를 수행하였다. DGPA의 유화력은 1%의 적은 농도에서도 고 내상의 물을 함유하는 안정한 W/O water-in-oil)에멀젼이 유지되었다. DGPA, dimethicone (2CS), water의 3성분계의 특정영역에서, 안정한 큐빅상의 액정이 형성되었다. 3상 구조도 작성을 통하여 큐빅 액정영역, 헥사고날 영역, 물과 헥사고날이 혼제된 영역, 역미셀 영역을 확인하였고, SAXS (small angled x-ray scattering)분석을 통하여 그 구조를 증명하였다. 화장품의 응용으로, 큐보좀 (cubosome)에 10%의 마그네슘아스코르빌포스페이트, 5%의 피리독신트리헥사데카노에이트를 봉입하여 캡슐화하였다. 큐보좀의 occlusive 효과는 역미셀(reverse micelle)보다 1.7배 우수한 효과를 가졌다. 큐보좀을 분산제인 poloxamer를 사용하여 W/O 에멀젼을 만든 것으로부터 큐빅구조의 액정상으로 회복되는 것을 새롭게 발견하였다. 따라서, DGPA의 양친매성지질의 특성을 이용하여, 큐빅상의 액정을 형성하는 기재로써 화장품 산업과 의약품분야에서 경표피흡수제로써 응용이 가능할 것으로 기대된다.

3차원 기로틴 3단계 자재절단 방법에 관한 연구 (A study on the 3-stage 3-dimensional guillotine cutting-stock problem)

  • 김상열;박순달
    • 한국경영과학회:학술대회논문집
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    • 대한산업공학회/한국경영과학회 1996년도 춘계공동학술대회논문집; 공군사관학교, 청주; 26-27 Apr. 1996
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    • pp.276-279
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    • 1996
  • This paper deals with the method providing an exact solution to the 3-dimensional guillotine cutting stock problem. We suggest a 3-stage sutting method using the property that cubic material has to be cut into 2-dimensional planes firstly. This method requires more stocks that the general guillotine cutting methods but can save work force. By using the 1-dimensional dynamic programming, we reduce the computational time and the memory requirement in the 3-stage guillotine cutting method.

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Magnetic Property of Oxide with the Perovskite Structure, $A_2Fe(III)BO_6$ (A = Ca, Sr, Ba and B = Sb, Bi)

  • 이성옥;조태연;변송호
    • Bulletin of the Korean Chemical Society
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    • 제18권1호
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    • pp.91-97
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    • 1997
  • In the course of magnetic study on several perovskite-type oxides, A2Fe(Ⅲ)BO6 (A = Ca, Sr, Ba and B = Sb, Bi), we have observed a strong irreversibility in their dc-magnetizations. When the structural data and the Mossbauer spectra are considered, such an irreversibility is to be associated with some competitions between the nearest-neighbors (nn) and the next-nearest-neighbors (nnn) in their magnetic sublattices. Particularly, the Mossbauer spectra indicate that Sr2FeBiO6 of cubic perovskite-structure is apparently well ordered crystalline compound. Nontheless this antiferromagnet shows a magnetic property which resembles that of a spin-glass. The strong history dependence is observed below 91 K and the irreversible magnetic behavior is also observed from the measurement of hysteresis loops at 10 K after zero-field-cooled (zfc) and field-cooled (fc) processes. Considering the nn and the nnn superexchanges of almost same order in ordered perovskite, it is proposed that there exists a competition and cancellation of antiferromagnetic and ferromagnetic superexchange between the nearest-neighbors and the next-nearest-neighbors, thus introducing a certain degree of frustration.

3-Dimensional Thermoforming Computer Simulation Considering Orthotropic Property of Film

  • Son, Hyun-Myung;Yoon, Seok-Ho;Lee, Ki-Ho;Lyu, Min-Young
    • Elastomers and Composites
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    • 제57권3호
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    • pp.114-120
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    • 2022
  • The tensile properties of the extruded PC film were measured in the extrusion direction and perpendicular to the extrusion direction. The measured properties were the elastic modulus and Poisson's ratio at the glass transition temperature of PC. The measured orthotropic properties of the film were used for the computer simulation of vacuum forming. In this simulation, three mold shapes were tested: dome, trapezoid, and cubic, and the vacuum was applied between the mold surface and the heated film. The stress, strain, thickness, and stretch ratio distributions of the film in different mold shapes were observed and compared. The thermoforming simulation method used in this study and the obtained results, considering the determined orthotropic properties, can be applied to the thermoforming of various three-dimensional shapes.

시판치과주조용 고금합금의 물리적 성질 및 상변태 (Physical Property and Phase Transformation in a Commercial Dental Casting High Gold Alloy)

  • 이희경;박명호;이화식
    • 대한치과기공학회지
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    • 제28권1호
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    • pp.27-41
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    • 2006
  • The physical property and phase transformation in a commercial dental casting high gold alloy was investigated as a function of ageing temperature and time using microvickers hardness tester, X-ray diffraction, optical and electron microscopy and EPMA analyser. 1. With increasing ageing time, the hardness of solution-treated gold alloys increased slowly at the initial stage of ageing treatment at an ageing temperature of $300{\sim}400^{\circ}C$, and it reached a maximum value of hardness at the medium stage. Finally, it decreased gradually during further ageing. The maximum value of hardness at was similar with that of the conventional materials and suitable for using as the crown & bridge. 2. During isothermal ageing at a temperature range of $300{\sim}400^{\circ}C$, three phases consisting of the Au-rich ${\alpha}_1$phase with a face-centered cubic structure, the Pt3Zn ${\alpha}_2$phase with an ordered AuCu3(L12) type(f.c.c.) and the Pt-rich ${\alpha}_3$phase with face-centered cubic structure in solution-treated gold alloys were transformed into different three phases consisting of the ${\alpha}_1$phase, the ${\alpha}_3$phase and the PtZn $\beta$phase with an ordered AuCu I(L10) type. 3. The hardening of gold alloys was attributed to the lattice strains of the matrix resulting from the transformation of the ${\alpha}_2$phase to the $\beta$phase. 4. The softening of gold alloys during over-ageing was attributed to the coarsening of the nodules consisting of the $\beta$phase and ${\alpha}_1$matrix.

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GPS를 이용한 3차원의 지적의 도입방안과 문제점 (A study on the 3D- cadastre surveying by GPS)

  • 김선이
    • 항공우주정책ㆍ법학회지
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    • 제21권1호
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    • pp.7-27
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    • 2006
  • 우리니라의 지적제도가 도입된 초기에는 토지의 이용이 지표만을 이용하는 매우 단순한 형태였다. 그러나 토목건축기술의 발달과 인구의 급격한 증가 및 도시화의 급속한 확산 등으로 지표면의 지하공간 및 지상공간을 활용하는 토지의 입체적 이용이 극대화 하여 왔다. 이러한 토지에 대하여 우리민법 제212조에 "토지의 소유권은 정당한 이익이 있는 범위 내에서 토지의 상하에 미친다." 라고 규정하고 있어 일필지에 대한 권리는 지표는 물론이고 지상 및 지하에 걸쳐 소유권 영향이 미친다고 할 수 있다. 지적제도는 토지에 대한 유형적 측면의 관찰로서 토지 표지상의 사실관계를 지적공부라는 국가적 공부에 나타냄으로써 그 실체관계를 알 수 있게 한 제도이다. 그러나 현재 우리나라 지적제도는 지표면상의 사항만을 등록할 수 있는 2차원 지적의 상태로 되어 있고 지하건축물 및 지하시설물을 지적도에 등록관리하지 않기 때문에 지상 지하공간의 입체적 활용에 대해서는 효율적인 등록관리가 전혀 이루어지지 못하고 있는 실정이다. 본 논문에서는 이러한 필요성에 따라 3차원의 지적 공부를 만들기 위하여, 그 방법으로 필요한 항공측지측량인 GPS의 측량방법을 살펴보고 이렇게 작성된 지적공부를 기초로 한 사적 재산권의 보호 및 토지의 입체적인 이용에 대한 법제를 살펴보았다.

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$(Na_{0.5}Sr_{0.5})(Ti_{0.5}Nb_{0.5})O_{3}$의 온도변화에 따른 유전특성과 구조 상전이의 관계 (The relation of dielectric properties and structure change with temperature for $(Na_{0.5}Sr_{0.5})(Ti_{0.5}Nb_{0.5})O_{3}$)

  • 정훈택
    • 한국결정성장학회지
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    • 제5권4호
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    • pp.394-399
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    • 1995
  • 산소 팔면체의 tilting에 의한 초격자 구조를 하고 있는 $(Na_{0.5}Sr_{0.5})(Ti_{0.5}Nb_{0.5})O_{3}$의 온도 변화에 다른 유전 특성 및 X-선 회절에 의한 구조의 변화를 살펴보았다. 유전 손실 측정에서 관측되는 380 K 부근의 peak는 primitive cell이 정방정에서 입방정으로 변화함에 따라 생기는 peak임을 알 수 있었으며 이 때 유전율의 변화는 관측되지 않았다. 따라서 유전 손실이 재료 내의 구조적 변화를 인지하는데 유전율보다 민감하다는 것을 알 수 있었다. Primitive cell 이 입방정으로 변화한 후에도 산소 팔면체의 tilting에 의한 초격자 회절선은 여전히 관측되었으며 500 K 정도에서 완전히 사라짐을 알 수 있었다. 하지만 이때 유전 특성의 변화는 관측되지 않았다.

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Synthesis of Zirconium Oxide Nanoballs Using Colloid-Imprinted Carbon and Their Electrical Properties

  • Kim, Chy Hyung
    • Transactions on Electrical and Electronic Materials
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    • 제16권2호
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    • pp.86-89
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    • 2015
  • Uniform ZrO2 nanoballs were synthesized at 700℃ using the inverse replication method through a colloid-imprinted carbon (CIC) template. The structural, dielectric, and conducting properties of the ZrO2 nanoballs were investigated and compared with those of ZrO2 film prepared by sol-gel method and powdered ZrO2 chemical. Both the monoclinic and cubic phases were found in the ZrO2 balls and film but the ZrO2 chemical showed a monoclinic phase, where the cubic structure is known to be formed at above 2,300℃. ZrO2 nanoballs showed the lower dielectric property of k = 21.2 at 1 MHz because the 8-coordinated cubic phase in the ZrO2 nanoball produced lower polarization than the polarization of the 7-coordinated monoclinic ZrO2 chemical (k = 23.6). The dielectric stability was maintained in each ZrO2 ball, film, and chemical under the applied forward and reverse voltage range (−5 to +5 V) at 1 MHz. The ionic conductivities were 7.86 × 10−8/Ω·cm for ZrO2 nanoballs, 3.29 × 10−8/Ω·cm for ZrO2 chemical, and 6.70 × 10−5/Ω·cm for the thickness of 1,053 nm ZrO2 film at room temperature with the electronic contribution being less than 0.006%.

삼초(三焦)와 영위(營衛)의 상관성(相關性) (The Relation of Three Burning Space And Nutrient & Defensive Qi)

  • 문성식;강정수
    • 혜화의학회지
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    • 제9권1호
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    • pp.105-112
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    • 2000
  • Three burning space concentrating mainly on the text of ${\ll}NeiChing{\gg}$, we got this conclusion by looking at a longitudial perspective of three burning space function, nutrient & defensive qi creation, movement and numbers. 1. Longitudial movement is the law of the universe, by looking at oriental medicine by the thought of heaven and man unity we can tell that longitudial movement concept is used to analyze the physiology of our body. And we can look at our body in a cubic movement suck as top and bottom, left and right, outside and inside, internal and external, upward and downward movement. 2. In Nei Ching the concept of three burning space is seperated in to four different types of three burning space which are three burning space as a fu, three burning space as a water metabolism and excretion organ, and three burning space by its position. 3. nutrient & defensive qi's movement in the channel is the same as the twelve regular channels movement in our body, nutrient qi circulates the yang part twenty five during the day and circulates the ying part twenty five times during the night. Since channel functions corresponds with the sun, moon, and the stars the ups and downs of nutrient & defensive qi's property varies with the difference of the periods. 4. By comparing nutrient & defensive qi's production and property with three burning space's positional property, we can see that three burning space's positional property comes out from the longitudial movement of nutrient & defensive qi.

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α-In2S3:Co2+ 단결정의 광학적 특성에 관한 연구 (Optical Properties of α-In2S3:Co2+ Single Crystal)

  • 박광호;현승철;정진;오석균
    • 한국전기전자재료학회논문지
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    • 제21권12호
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    • pp.1057-1062
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    • 2008
  • The ${\alpha}-In_2S_3:Co^{2+}$ single crystal with a good quality and stabilized property were gained successfully by the CTR(Chemical Transport Reaction)method. XRD analysis showed that the grown single crystals were cubic structure. The optical absorption spectra of ${\alpha}-In_2S_3:Co^{2+}$ single crystal showed impurity absorption peaks due to cobalt impurity. These impurity absorption pesks were assigned to the ligand transition between the split energy levels of $Co^{2+}$ ions sited in $T_d$ symmetry of these semiconductor host lattice.