• 제목/요약/키워드: crystal analysis

검색결과 2,011건 처리시간 0.028초

Rietveld 법을 이용한 $(Na_{0.3}Sr_{0.7})(Ti_{0.7}M_{0.3})O_3 (M=Ta, Nb)$ 계에서의 결정구조 해석과 상전이 특성 (Phase Transition adn Crystal Structure Analysis Using Rietveld Method in the $(Na_{0.3}Sr_{0.7})(Ti_{0.7}M_{0.3})O_3 (M=Ta, Nb)$ System)

  • 정훈택;김호기
    • 한국세라믹학회지
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    • 제32권5호
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    • pp.582-586
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    • 1995
  • The crystal structures of (Na0.3Sr0.7)(Ti0.7M0.3)O3 (M=Ta, Nb) compounds were determined using the Rietveld method. Due to the tilting of a oxygen octahedron, (Na0.3Sr0.7)(Ti0.7Nb0.3)O3 had a superlattice of doubled a, b and c of simple perovskite. The crystal structure of (Na0.3Sr0.7)(Ti0.7M0.3)O3 was tetragonal with a space group 14/mmm. The crystal structure of (Na0.3Sr0.7)(Ti0.7M0.3)O3 was a cubic with space group Pm3m, in which no tilting of oxygen octahedron was observed. The difference in the oxygen tilting of these two materials was due to the larger covalency of Nb-O bond than that of Ta-O bond, which induced a strong $\pi$Nb0 bonding in (Na0.3Sr0.7)(Ti0.7M0.3)O3. Therefore, the higher transition temperature of (Na0.3Sr0.7)(Ti0.7M0.3)O3 could be related to the larger tilting of oxygen octahedron.

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수정진동자를 사용한 점탄성 유체의 점성계수와 전단 탄성계수 측정에 관한 이론해석 (Theoretical Analysis for the Measurement of Viscosity and Shear Modulus of Viscoelastic Fluids by Using a Quartz Crystal Oscillator)

  • 서용권;김영한
    • 대한기계학회논문집B
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    • 제32권7호
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    • pp.487-496
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    • 2008
  • Quartz crystal oscillator is frequently used in measuring a very small amount of mass attached to or adsorbed on the surface of an electrode on the quartz plate. The physical principle is that the resonance frequency of the shear vibration of the quartz caused by an applied electric field is a function of the mass. Recently, effort has been tried to measure physical properties of viscoelastic fluids, such as viscosity and shear modulus. This paper presents useful formula that can be used in estimating the properties of viscoelastic fluids. Important finding in this analysis is that the formula can produce multiple values for the physical properties of the viscoelastic materials.

Construction of Recombinant Xanthomonas campestris Strain Producing Insecticidal Protein of Bacillus thuringiensis

  • Shin, Byung-Sik;Koo, Bon-Tag;Choi, Soo-Keun;Park, Seung-Hwan
    • Journal of Microbiology and Biotechnology
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    • 제4권4호
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    • pp.285-289
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    • 1994
  • An insecticidal crystal protein gene, cryIA(c), from Bacillus thuringiensis HD-73 was integrated into the chromosome of a xanthan-producing bacterium, Xanthomonas campestris XP92. The cryIA(c) gene expression cassette was constructed that placed the gene between the trc promoter and rrnB transcriptional terminator. The $lacl^q$ gene was also included to prevent the expression of cryIA(c) gene in X campestris cells. Southem blot analysis confirmed the integration of the cryIA(c) gene expression cassette in chromosome of X campestris XP92 transconjugant. Expression of the insecticidal crystal protein was confirmed by Western blot analysis and bioassay against the larvae of Hyphantria cunea (Lepidoptera: Arctiidae) and Plutella xylostella (Lepidoptera:Plutellidae).

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Fabrication of Dual-mode Ultrasonic Transducer using PZT

  • Kim, Yeon-Bo;Park, Youn-Rae
    • 한국전기전자재료학회논문지
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    • 제15권10호
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    • pp.914-920
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    • 2002
  • This study investigates the mechanism of a dual mode probe that generates both of the longitudinal and shear waves simultaneously with a single FZT element. Most of conventional ultrasonic probes are constructed to generate either longitudinal or shear waves. After poling, PZT has the hexagonal 6mm crystal symmetry. All possible crystal cuts are checked to determine appropriate Euler transformation angles for efficient excitation of dual modes. For the selected cut, performance of the dual mode element is analyzed through numerical simulation and experiments. Results of the analysis determine the optimal crystal cut for simultaneous generation of P and S waves of equal strength.

Dynamic Pixel Models for a-Si TFT-LCD and Their Implementation in SPICE

  • Wang, In-Soo;Lee, Gi-Chang;Kim, Tae-Hyun;Lee, Won-Jun;Shin, Jang-Kyoo
    • ETRI Journal
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    • 제34권4호
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    • pp.633-636
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    • 2012
  • A dynamic analysis of an amorphous silicon (a-Si) thin film transistor liquid crystal display (TFT-LCD) pixel is presented using new a-Si TFT and liquid crystal (LC) capacitance models for a Simulation Program with Integrated Circuit Emphasis (SPICE) simulator. This dynamic analysis will be useful when predicting the performance of LCDs. The a-Si TFT model is developed to accurately estimate a-Si TFT characteristics of a bias-dependent gate to source and gate to drain capacitance. Moreover, the LC capacitance model is developed using a simplified diode circuit model. It is possible to accurately predict TFT-LCD characteristics such as flicker phenomena when implementing the proposed simulation model.

Crystal Forms of Ketorolac

  • Sohn, Young-Taek;Seo, Hyun-Ok
    • Archives of Pharmacal Research
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    • 제27권3호
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    • pp.357-360
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    • 2004
  • Four crystal forms of ketorolac have been obtained by recrystallization in organic solvents under variable conditions. Different ketorolac polymorphs and pseudo polymorph were characterized by X-ray powder diffraction crystallography (XRD), Differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA). In the dissolution studies in water at $37{\pm}0.5^{\circ}C$ four crystal forms showed different patterns. The solubility of Form I were the highest. The solubility decreased in rank order: Form I> Form II > Form III > Form IV. Form land Form III were shown to have a good physical stability at room temperature for 60 days. However, Form II is converted to Form III and Form IV is converted to Form I after 60 days storage. Therefore, these observations indicate that crystalline polymorphism for ketorolac is readily inter-convertible and the relationship may have to taken into consideration in the formulation of the drug.

반정육면체 알고리즘 및 단결성 성장로의 열해석에의 응용 (Hemi-cube algorithm and its application to thermal analysis of crystal growth furnace)

  • 이승복;정진수;고상근
    • 대한기계학회논문집B
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    • 제22권7호
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    • pp.905-914
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    • 1998
  • View factor determination is very important in thermal analysis problems with surface radiation but it is very difficult to determine view factors for complex geometries. Exact calculation of view factors for crystal growth furnace is essential due to not only its high surface temperature but the radiation shield, complicated heating system. In this study, view factor calculation algorithm is introduced and applied to cylindrical crystal growth furnace. This algorithm is based on the Hemi-Cube Algorithm and the results obtained with this algorithm show good agreements with those of analytical solution. As an application of this algorithm, temperature profiles and heating value distributions for various furnaces are calculated and the shape criteria for better furnace are suggested.

다결정재의 이방성 탄.점소성 유한요소해석 (Anisotropic Elasto-Viscoplastic Finite Element Analysis for Polycrystalline Materials)

  • 이용신;김응주
    • 한국CDE학회논문집
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    • 제2권2호
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    • pp.71-76
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    • 1997
  • The deformations of polycrystalline materials are modelled by linking a constitutive equation for the crystallographic slip of a single crystal to the macroscopic behavior of the aggregate. In this study, anisotropic elasticity (lattice stretching) of a cubic crystal is incoporated into the anisotropic plasticity from crystallographic slip. The constitutive description for the aggregate, derived from a crystal plasticity theory, is used to formulate a Consistent Penalty Finite Element Method for the anisotropic elasto-viscoplastic deformation of polycrystalline materials. As an application, a plane-strain forging process is simulated and the effects of the initial textures on the deformation behavior of the workpiece are examined.

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Synthesis and Crystal Structures of Mn(II)- and Ni(II)-Dicarboxylate Complexes with 1,10-Phenanthroline

  • Koo, Bon-Kweon
    • Bulletin of the Korean Chemical Society
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    • 제33권7호
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    • pp.2299-2304
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    • 2012
  • Two new metal(II) complexes, $[Mn(dpa)(phen)(H_2O)_2]_n$ (1) ($H_2dpa$ = dephenic acid, phen = 1,10-phenanthroline) and $[Ni_2(nda)(phen)_2(H_2O)_6](nda)(H_2O)$ (2) ($H_2nda$ = 2,6-naphthalenedicarboxylic acid) have been synthesized and characterized by elemental analysis, infrared spectroscopy, thermogravimetric analysis, and single crystal X-ray diffraction. In complex 1, Mn(II) ion is six-coordinated, and Mn(II) ions are bridged by dpa ligands into 1D chains. While, the complex 2 is dimer and two Ni(II) ions are bridged by one nda ligand cooperated with the terminal ligand phen. In each complex, the dicarboxylate ligand is coordinated to metal(II) ions as a bis-monodentate.

감성 소재 기반의 스포츠 휠체어 소재 적용에 관한 연구 (A study on the application of sports wheelchair materials based on emotional materials)

  • 송성일
    • 한국결정성장학회지
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    • 제31권1호
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    • pp.43-54
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    • 2021
  • 본 연구는 제품 개발의 소재 적용에 있어 트렌드 리서치를 기반으로 하는 감성 소재의 요소를 도출하는 프로세스를 제안하였다. 케이스 모델인 한국형 스포츠 휠체어 개발에 적용하고자 하였으며, CMF(Color, Material, Finish) 기반의 리서치 중 소재 부분에 초점을 맞추어 연구하였다. 메가트렌드, 경쟁사 제품 및 파트별 분석, 심리 색채 분석 등 리서치 방법론을 통해 소재 적용의 최적화 및 검증, DB화를 연구하였으며 FGI 검증을 통한 최종 적용안을 도출하였다.