• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2001년도 추계학술대회 논문집 Vol.14 No.1
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• pp.350-353
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• 2001

Aligning capabilities for nematic liquid crystal (NLC) using a in-situ photodimerization method on various photo-crosslinkable polyimide (PI) based polymer and blending photopolymer surfaces were stuided. High pretilt angle of the NLC can be measured by obliquely polarized UV exposure on a photo-crosslinkable polyirnide based polymer surface containing biphenyl (BP), decyl (de), and cholesteryl (chol) group, respectively, However, the low pretilt angle of the NLC was measured by obliquely polarized UV exposure on the blending photopolymer (PI and cinnamate materials) surfaces. Consequently, the pretilt angle of the NLC generated on the photo-crosslinkable polyimide based polymer surfaces using the in-situ photodimerization method was higher than that of the blending photopolymers.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2001년도 추계학술대회 논문집
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• pp.350-353
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• 2001

Aligning capabilities for nematic liquid crystal (NLC) using a in-situ photodimerization method on various Photo-crosslinkable polyimide (PI) based Polymer and blending photopolymer surfaces were studied. High pretilt angle of the NLC can be measured by obliquely polarized UV exposure on a photo-crosslinkable polyimide based polymer surface containing biphenyl (BP), decal (de), and cholesterol (chol) group, respectively. However, the low pretilt angle of the NLC was measured by obliquely polarized UV exposure on the blending photopolymer (PI and cinnamate materials) surfaces. Consequently, the pretilt angle of the NLC generated on the photo-crosslinkable polyimide based polymer surfaces using the in-situ photodimerization method was higher than that of the blending photopolymers.

• 한국전기전자재료학회논문지
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• 제14권11호
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• pp.917-921
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• 2001

Aligning capabilities for nematic liquid crystal (NLC) using a in-situ photodimerization method on various Photo-crosslinkable Polyimide (Pl) based polymer and blending photopolymer surfaces were investigated. High pretilt angle of the NLC can be measured by obliquely polarized UV exposure on a photo-crosslinkable polyimide based polymer surface containing biphenyl (BP), decyl (de), and cholesteryl (chol) group, respectively. However, the low pretilt angle of the NLC was measured by obliquely polarized UV exposure on the blending photopolymer (Pl and cinnamate materials) surfaces. Consequently, the pretilt angle of the NLC generated on the photo-crosslinkable polyimide based polymer surfaces using the in-situ photodimerization method was higher than that of the blending photopolymers.

• 한국정보디스플레이학회:학술대회논문집
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• 한국정보디스플레이학회 2009년도 9th International Meeting on Information Display
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• pp.810-813
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• 2009

Fluorene derivatives are well-known in the polymer OLEDs due to their good charge carrying property. In this work, we synthesized a series of conjugated copolymers based fluorene derivative and phenylamine units by using Buchwald-Hartwig reaction in order to investigate their photoreactivities and use as the HIL/HTL layers of OLEDs using solution processes.

• 한국전기전자재료학회논문지
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• 제14권5호
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• pp.430-434
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• 2001

We synthesized a new photo-crosslinkable polymer (polyimide (PI)-chalcone-biphenyl (BP)) and liquid crystal (LC) aligning capabilities for nematic (N) LC with obliquely polarized UV exposure on a photo-crosslinkable polymer were studied. The high pretilt angle in NLC was obtained by polarized UV exposure on a PI-Chal-BP surface for 3 min. The high pretilt angle generated in NLC is attributed to the biphenyl moieties and the photo-dimerized chalclone group of a photopolymer. Also, good thermal stability of a PI-Chal-BP were obtained by thermogravimetric analysis (TGA) measurement until 450$^{\circ}C$. Finally, good voltage-transmittance curves and response time were observed by UV exposure on a PI-Chal-BP surface for 3min.

• 한국전기전자재료학회논문지
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• 제14권7호
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• pp.595-599
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• 2001

The mechanisms of pretilt angle generation for a nematic liquid cystal (NLC) using a photodimerization method with obliquely polarized UV exposure on the various new photo-crosslinkable polymer were studied. A good thermal stability of all the photo-crosslinkable polymers was obtained by thermogravimetric analysis (TGA) measurement until 450$\^{C}$. High pretilt angle of the NLC was observed by polarized UV exposure on the three kinds of the photo-crosslinkable polymers containing biphenyl(BP), decyl(de), and cholesteryl(chol) group, respectively. However, the low pretilt angle of the NLC was measured by obliquely polarized UV exposure on the two kinds of the photo-crosslinkable polymers containing fluorine and chalcone group. Consequently, the high NLC angle generated is attributable to the biphenyl and alkyl moieties, and photo-dimerized chalcone group of the photopolymer.

• 한국전기전자재료학회논문지
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• 제14권4호
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• pp.341-344
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• 2001

We synthesized a photo-crosslinkable polymide (polymide (PI)-chalcone-biphenyl (BP)) based polymer and control of pretilt angle for a nematic liquid crystal (NLC) using two kinds of the photodimerization methods by polarized UV exposure the photopolymer surfaces was studied. Pretilt angle of the NLCs using a conventional photodimerization method could be varied between 0$^{\circ}$ and 3$^{\circ}$, by controlling the condition of UV exposure. Pretilt angle of the NLCs using the conventional photodimerization method was higher than a in-situ photodimerization method.

• 센서학회지
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• 제24권3호
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• pp.165-168
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• 2015

We demonstrated low-voltage organic thin-film transistors (OTFTs) with bilayer insulators, high-k polymer and low temperature crosslinkable polymer, on a flexible plastic substrate. Poly (vinylidene fluoridetrifluoroethylene) (P(VDF-TrFE)) and poly (2-vinylnaphthalene) are used for high-k polymer gate insulator and low temperature crosslinkable polymer insulators, respectively. The mobility of flexible OTFTs is $0.17cm^2/Vs$ at gate voltages -5 V after bending operation.

• 폴리머
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• 제34권3호
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• pp.202-209
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• 2010

열적 안정성과 기계적 강도에서 우수한 장점을 지니고 있는 메타계 aramid segment와 제막 특성이 우수하고 내가수분해성이 우수한 sulfone segment로 이루어진 공중합체를 이용하여 연료 전지용 막으로서의 응용가능성을 연구하였다. 아라미드 고분자의 solubility와 processability를 향상시키기 위해 아민기를 갖는 sulfonated ether sulfone단량체와 m-phenylene diamine 그리고 isophthaloyl chloride를 반응시켜 아민으로 말단화된 랜덤공중합체를 합성하고 이것을 acryloyl chloride와 반응시켜 양 말단에 2중 결합이 도입된 고분자전구체를 합성하였다. 얻어진 고분자전구체는 열 가교를 통해 고분자 전해질 막으로 제조되었으며, 전구체의 합성을 비롯한 각 단계의 반응은 $^1H$ NMR, FTIR, 및 적정에 의하여 확인되었다. 얻어진 전해질막은 이온교환용량과 함수율, 수소이온전도도, 열적 특성 등이 측정되었으며, sulfonated ether sulfone 단량체의 함유량이 증가할수록 이온교환용량, 함수율, 수소이온전도도가 증가하는 것이 관찰되었다. Sulfonic acid sulfone segment를 30 몰%로 갖는 고분자 전해질 막의 경우 이온교환용량이 1.57 meq/g, 함수율은 44 wt% 이하의 수치를 보였으며, 가장 높은 수소이온전도도의 값은 상대습도 100%, $25^{\circ}C$에서 $3.93{\times}10^{-2}S/cm$이었다.

• KIEE International Transactions on Electrophysics and Applications
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• 제11C권4호
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• pp.133-137
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• 2001

In this research, we synthesized various photo-crosslinkable polyimide based polymers. The control of pretilt angles for a nematic liquid crystal (NLC) using the photodimerization method on the photopolymers was studied. A good thermal stability of the photopolymers was measured by thermogravimetric analysis (TGA) measurement until 450C. High pretilt angles of the NLC were otained by polarized UV exposure on the photopolymers containing biphenyl (BP), decyl (de), and cholesteryl (chal) groups, respectively. However, low pretilt angles of the NLC were measured by polarized UV exposure on the photopolymers containing fluorine and chalcone groups. The high NLC pretilt angles generated are attributable to the biphenyl and alkyl moieties, and the photodimerized chalocone group of the photopolymers. Additionally, good voltage-transmittance and response time characteristics were observed by UV exposure on the photopolymers.