• Bulletin of the Korean Chemical Society
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• 제27권9호
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• pp.1473-1476
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• 2006

• Elastomers and Composites
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• 제57권4호
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• pp.222-230
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• 2022

In this study, a low-heat additive with a crosslink structure was dispersed in asphalt to simultaneously lower the production temperature of, and to modify the asphalt binder. This low-heat additive was prepared by different feeding ratios of styrene-butadiene-styrene (SBS) and polyvinylchloride (PVC) as polymer modifiers, and ZnO as a crosslinking agent. In order to confirm the crosslinking density and compatibility of the crosslink structured low-heat additive with asphalt, surface free energy, swelling ratio, differential scanning calorimetry (DSC), and scanning electron microscope (SEM) parameters were carefully investigated to examine this relationship, and the role of the crosslink structured low-heat additive. In addition, by measuring the penetration and softening point of the asphalt binder, it was confirmed that it corresponds to PG 64-22. With increasing ZnO in the crosslink structured low-heat additive, the swelling ratio decreased, leading to an increase in crosslinking density. The crosslink structured low-heat additive and the asphalt binder were found to be compatible with each other by DSC and SEM analysis.

• 접착 및 계면
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• 제3권2호
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• pp.30-39
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• 2002

실리카로 보강된 천연고무 가황물에서 가황촉진제의 양이 열노화에 의한 가교밀도의 변화에 미치는 영향에 대해 연구하였다. 또한 실란커플링제의 영향도 조사하였다. 가황촉진제로는 N-tert-butyl-2-benzothiazole sulfenamide(TBBS)를 실란 커플링제로는 bis-(3-(triethoxysilyl)-propyl)-tetrasulfide(TESPT)를 사용하였다. 가황물을 열노화 시키면 가교밀도는 증가하였고 노화 온도가 높을수록 그 변화 정도는 컸다. 실란 커플링제가 포함되지 않은 가황물의 가교밀도 변화가 실란 커플링제를 포함한 것에 비해 더 크게 나타났다. 실란 커플링제가 포함되지 않은 가황물의 경우에는 가교밀도의 변화에 대한 활성화 에너지가 가황촉진제의 함량이 증가할수록 순차적으로 낮아지는 경향을 보였다.

• Elastomers and Composites
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• 제46권3호
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• pp.237-244
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• 2011

비보강, 카본블랙, 카본블랙과 실란커플링제, 실리카, 실리카와 실란커플링제 등 5가지의 다른 충전 시스템을 갖는 NR 복합체를 열노화시켰으며, 가속 열노화에 의한 가교밀도 변화를 연구하였다. 가교밀도는 충전 시스템과 관계없이 노화 시간이 경과함에 따라 증가하였다. 노화 온도가 높아질수록 가교밀도는 눈에 띄게 변하였다. 카본블랙으 로 보강된 NR 복합체의 경우, 실란커플링제는 가교밀도를 증가시켰다. 하지만 실리카로 보강된 NR 복합체의 경우에는 $60^{\circ}C$와 $70^{\circ}C$ 노화에서는 가교밀도 증가분이 감소하였으며, $80^{\circ}C$와 $90^{\circ}C$에서는 거의 영향을 주지 않았다. 카본블랙으로 보강된 NR 복합체의 가교밀도 변화에 대한 활성화 에너지는 로그 함수 형태로 지속적으로 증가한 반면, 실리카로 보강된 NR 복합체의 경우에는 노화 시간 30-150일 구간에서는 거의 변화가 없었다. 비보강 시험편의 활성화 에너지 는 노화 시간에 따라 지수 함수 형태로 증가하였다. 실험 결과는 실란커플링제로부터의 황 제공, 실란커플링제에 의한 충전제의 표면 개질, 실리카 표면에서의 가교제 잔류물의 흡착, 그리고 흡착된 가교제 잔류물의 방출 등으로 설명하였다.

• 환경위생공학
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• 제23권1호
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• pp.57-65
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• 2008

Resins were synthesized with 1-aza-15-crown-5 macrocyclic ligand attached to styrene(dangerous matter) divinylbenzene(DVB) copolymer with crosslink of 1, 2, 6 and 15% by substitution reaction. The synthesis of these resins was confirmed by content of chlorine, element analysis, and IR-spectrum. The effects of pH, time and crosslink on adsorption of metal ion　from water fire extinguishing agent by the synthetic resin adsorbent were investigated. The metal ion was showed fast adsorption on the resins above pH 3. The optimum equilibrium time for adsorption of metallic ions was about two hours. The adsorption selectivity determined in water was in increasing order of $Mg^{2+}>Al^{3+}>Pb^{2+}$. The adsorption was in the order of 1, 2, 6, and 15% crosslink resin.

• 한국응용과학기술학회지
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• 제29권2호
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• pp.317-322
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• 2012

미세 조직은 SEM, FT-IR 스펙트라, 인장특성, 그리고 [NCO]/[OH]의 mole %, 입도분석에 의해 측정하였다. 친환경적인 NATM에 관한 관심이 고조됨에 따라 스테인레스같은 금속코팅에 더욱더 중요한 열경화 무용제 수지를 합성 하였다. 이 수지는 일반적 도료와 비교하여 매우 강도가 강하고 내구성이 매우 좋다. 폴리우레탄 수지는 폴리올, IPDI, 실리콘 계면활성제, 촉매, 충전제로 구성된다. 폴리우레탄 화합물은 가교제가 첨가된 수지가 가교제가 첨가되지 않은 수지보다 물성이 우수함을 나타냈다. 견고한 폴리우레탄 도료의 기계적 특성은 [NCO]/[OH]와 가교제가 증가함에 따라 강도가 증가하였다. 합성한 도료의 물성 향상은 스테인레스 산업뿐만 아니라 다양한 산업에서 폴리우레탄 고분자 수지가 강구조물의 보수보강에 많은 응용이 기대된다.

• 한국전기전자재료학회논문지
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• 제25권10호
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• pp.779-785
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• 2012

The epoxy/micro-and nano-mixed silica composites(EMNC) systems were prepared and the AC insulation breakdown strength was evaluated. Glass transition temperature (Tg) and crosslink density were also measured by dynamic mechanical analyzer(DMA) in order to correlate them with the electrical and mechanical properties, and the effect of silane coupling agent on the electrical properties was also studied. Electrical properties and crosslink density of epoxy/micro-silica composite were noticeably improved by addition of nano-silica and silane coupling agent, and the highest breakdown strength was obtained by addition of 0.5~5 phr of nano-silica and 2.5 phr of silane coupling agent, and the highest tensile and flexural strength were obtained by addition of 2.5 phr of nano-silica.

• Corrosion Science and Technology
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• 제15권6호
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• pp.297-302
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• 2016

Water-based systems are dominating the coating market because of worldwide VOCs regulations. Research is focusing especially on waterborne polyurethane (WPU) because of its unique mechanical and chemical properties. However, commercial WPU consists of linear thermoplastic polymers with polar groups on the main chain, which do not perform as well as solvent-borne PU in a two-pack system. In this study, APTES were used as a chain crosslink agent to overcome commercial WPU's limited performance. WPUs synthesized by using a sol-gel process were evaluated with FT-IR, particle analysis, TGA, tensile tests, pull-off tests, SEM, and EIS. The results showed that WPUs with added APTES had better thermal stability, mechanical properties, and water resistance than did WPUs without added APTES. Consequently, the sol-gel process increased the crosslink density of WPUs and modified the WPU's own properties.

• 대한의용생체공학회:의공학회지
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• 제35권6호
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• pp.192-196
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• 2014

Collagen scaffolds were synthesized by cross linking into a solution mixture of 1-ethyl-3-[3-dimethylaminopropyl] carbodiimide hydrochlorid(EDC) in ethanol, followed by pressing, cleaning and lyophilization process after the type I atelo-collagen solutions in D.I water(pH3). The experimental conditions are collagen concentration of 1.0 wt%, 3.0 wt%, 5.0 wt% and differential concentration of cross-linker. Then, parametric studies were performed by varying the parameters to investigate the morphology, the porosity, the swelling ratio and the thickness and genotoxicity of the scaffolds. The scaffolds thickness pattern was regular to concentration of the degree of cross-linker and collagen. It was observed that the swelling ratio, the degree of crosslink, and the pore size(thickness of scaffold) can be controlled by adjusting the collagen, crosslinker. Among the parameters investigated, the smallest thickness can be achieved by collagen, crosslinker concentrate condition. The collagen scaffold is induced no genotoxicity. The lowest swelling ratio, as an indication of the highest degree of crosslink, can be obtained by adding crosslink agent.

• Membrane and Water Treatment
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• 제13권3호
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• pp.111-119
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• 2022

In this research, bentonite was intercalated with CMC and then two different percentages of glutaraldehyde (5 & 10%) were added as a crosslink agent to achieve non water-soluble composites. Then the composites were coated on clay-based microfiltration membranes which were synthesized in the previous work of the authors. The XRD technique was used to track the intercalation mechanism and FTIR was used to study the crosslink procedure. SEM was used to study the microstructure and morphology of the coated samples and then the ability of non-coated and coated samples for removal of Cr³⁺ ions was studied and compared. It was seen that the samples coated with the synthesized composite including 10% of glutaraldehyde showed the best results and removed 99.7% of Cr³⁺ ions from water polluted with 5 ppm of Cr³⁺ ions.