• Elastomers and Composites
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• v.58 no.4
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• pp.201-207
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• 2023

Owing to their unique properties originating from slidable cross-links, polyrotaxane derivatives have potential applications as polymer electrolytes for lithium-ion batteries, lightweight polymer alloys for vehicular bodies and their glazing, elastic rubbers for tires, hydrogels for drug delivery. This article reviews the structures of polyrotaxanes comprising cyclic molecules threaded by a linear axle polymer. Next, the versatile characteristics of polyrotaxane gels, elastomers, and polymer alloys such as toughness, elasticity, and softness are discussed in relation to their supramolecular architectures. Finally, the mechanical behavior of solid ring cross-links are compared with that of conventional fixed cross-links for better understanding.

• Proceedings of the Korean Society For Composite Materials Conference
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• 2003.04a
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• pp.103-107
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• 2003

The objective of this thesis is to develop the optimal design of composite links containing complicated cross-section. To accomplish this objective, a composite links structural analysis program was developed. The method of calculating effective modulus of composite beam containing complicated cross-section is proposed. Genetic algorithm was implemented for the optimization method to manipulate the discrete ply angles as the design variables and to utilize its high reliability to find the global optimum. The design variables were the number of plies, the fiber orientations and the stacking sequence. The optimal design of composite links was performed by genetic algorithm to minimize the weight of the structure and to constrain ply failure

• Bulletin of the Korean Chemical Society
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• v.35 no.12
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• pp.3627-3631
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• 2014

In this study we examined two ester-containing cross-links, hex-2-enyl acetate and hex-2-enyl propionate, as new cross-linking systems for helix stabilization of short peptides. We demonstrated that these hexenyl ester cross-links can be readily installed via a ruthenium-mediated ring-closing metathesis reaction of L-aspartic acid 4-allyl ester or L-glutamic acid 5-allyl ester at position i and (S)-2-(4'-pentenyl)alanine at position i+4 using second generation Hoveyda-Grubbs catalyst at $60^{\circ}C$. Between these two cross-links, we found that the hex-2-enyl propionate significantly stabilizes the ${\alpha}$-helical conformations of short model peptides. The helix-stabilizing effects of the hex-2-enyl propionate tether appear to be as powerful as Verdine's i,i+4 all-hydrocarbon stapling system, which is one of the most widely used and the most potent helix-stabilizing cross-linking systems. Furthermore, the hex-2-enyl propionate bridge is reasonably robust against non-enzymatic hydrolytic cleavage at a physiological pH. While extended studies for probing its chemical scopes and biological applications are needed, we believe that this new helix-stabilizing system could serve as a useful chemical tool for understanding protein folding and designing conformationally-constrained peptide drugs.

• Journal of Korea Multimedia Society
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• v.19 no.8
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• pp.1404-1414
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• 2016

Cross-layer design is a concept, which captures the dependencies and interactions and enables information sharing among layers in order to improve the network performance and security. There are two key challenges in wireless networks, lossy features of links and power assumption of network nodes. Cross-layer design of congestion control and power allocation in wireless lossy networks has been studied in the existing literature; however, there has been no contribution proposed in the literature that exploits the path diversity. In this paper, we are motivated to develop a cross-layer design of congestion control and power allocation, which takes into account lossy features of wireless links and transmission powers of network nodes and can be implemented in a distributed manner. Numerical simulation is conducted to illustrate the performance of our proposed algorithm and the comparison with current alternative approaches.

• Journal of the Korean Applied Science and Technology
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• v.38 no.1
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• pp.300-308
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• 2021

In this study, 3D networked poly(sodium acrylate) gel was polymerized and controlled with the crosslinking environment to evaluate the mechanical properties and swelling behavior. In general, as the degree of crosslinking in a pre-gelled solution increases, the swelling ratio of the 3D networked gel decrease while the mechanical strength of the gel increases. Interestingly, this study demonstrates that the polymerization and crosslinking efficiency in gelling process could be depended on the crosslinking environment by evaluating the number of elastically cross-links in 3D networked gel. As a result, the number of elastically corss-links would be changed with 3.6 times as varying of the crosslinking environment while keeping the degree of crosslinking. It is expected that the 3D networked gel would be optimized as an effective absorbing agent for VOCs by using the gel evaluation method based on the number of elastically cross-links.

• ETRI Journal
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• v.34 no.6
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• pp.858-868
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• 2012

In this paper, stochastic models for the cross-correlation of multiple channels are established based on measurement data collected using a wideband multiple-input multiple-output relay Band Exploration and Channel Sounder system at 3.7 GHz. We propose models for the cross-correlation characteristics of large-scale parameters (LSPs) between two links, that is, the base station and mobile station (MS) link and the relay station and MS link. The LSPs include shadow fading, Rician K-factor, delay spread, angle spread of arrival, and angle spread of departure. Furthermore, models are established for the cross-correlation of the small-scale fading in the impulse responses of two links. The statistics of these model parameters are investigated as functions of geometrical features of the multilink. They are extracted from a large amount of cross-correlation observations, which are obtained in three measurement sites along more than one hundred measurement routes. These models can be used together with the standard single-link channel models for the generation of correlated components, for example, path clusters, in two separate channels.

• Journal of the Korean Society for Precision Engineering
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• v.13 no.12
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• pp.22-29
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• 1996

In this paper the nodes of the multilayer hidden layers have been modified for modeling the nonlinear systems. The structure of nodes in the hidden layers is built with the feedforward, the cross talk and the recurrent connections. The feedforward links are mapping the nonlinear function and the cross talks and the recurent links memorize the dynamics of the system. The cross talks are connected between the modes in the same hidden layers and the recurrent connection has self feedback, and these two connections receive one time delayed input signals. The simplified steam boiler and the analytic multi input multi output nonlinear system which contains process noise have been modeled using this neural networks.

• Korean Journal of Cognitive Science
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• v.10 no.1
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• pp.25-43
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• 1999

The focus of this study is on the elements of structure design that facilitate u user interaction with applications within cyberspace Structure design entails decisions regarding the optimal classification and hierarchical organization of information into s successively higher units. i.e .. the grouping of highly related information in the form of nodes of a site and the subsequent connection of nodes that are inter-related. The decisions are based on the designer's subjective classification framework. which is not always compatible with that of the user. We propose that the ensuing cognitive dissonance can be reduced via the employment of multiple hierarchies and cross-referencing links. Multiple hierarchies represent a single information space in terms of a number of single hierarchies. each of which represent a different perspective Cross-referencing refers to the inter-connection between the constituent hierarchies by providing a link to the alternate hierarchy for information that is most likely to be categorized in diverse manners by users with differing perspectives. In this study we conducted two empirical studies to gauge the effectiveness of multiple hierarchies and Cross-referencing links in the domain of cyber shopping malls. In the first phase. an experiment was conducted to determine how subjects classified given products with respect to two different perspectives for categorization. Experimental cyber malls were developed based on the results from the first phase to test the effectiveness of multiple hierarchies and cross-referencing links. Results show that the ease of navigation was higher for cyber malls that had implemented cross-referencing links are of greater value when used in conjunction with single hierarchical designs rather than multiple hierarchies. Users satisfaction with and ease of navigation was higher for cyber malls that had not implemented multiple hierarchies. This paper concludes with discussion of these results and their implications for designers of cyber malls.

• Archives of Pharmacal Research
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• v.19 no.3
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• pp.191-196
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• 1996

Bizelesin is a promising novel anticancer agent which is known to alkylate N3 of adenine to induce DNA interstrand cross-links (ISC) with in $5^I-TAATTA\; and\; 5^I-TAAAAAA$. We have investigated the base specificity for DNA ISC induced by bizelesin using oligomers containing the cross-linkable sequence $5^I-TAATTA\; and\; 5^I-TAAAAAA$. in which "N" was either A, C, G, or T. An analysis of denaturing polyacrylamide gel showed that bizelesin is able to induce DNA ISC in the duplex oligomer containing sequences $5^I-TAATTA\; and\; 5^I-TAAAAAA$. The formation of interstrand crosslinking did not occur in the sequences $5^I-TAATTA\; and\; 5^I-TAAAAAA$. DNA strand cleavage assay to determine the cross-linking site within $5^I-TAATTA$sequence showed that bizelesin alkylates guanine. These results demonstrate that bizelesin is able to induce DNA ISC at guanine but not at cytosine or thymine. In addition, guanine adducts have been found to be susceptible to DNA strand cleavage by exposure to hot piperidine. The extent of DNA strand cleavage, however, was not 100% efficient in either neutral pH buffer or hot piperidine.

• Smart Structures and Systems
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• v.23 no.6
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• pp.653-667
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• 2019

Using cross-ties to connect cables together when forming a cable network is regarded as an efficient method of mitigating cable vibrations. Cross-ties have been extended and fixed on bridge decks or towers in some engineering applications. However, the dynamics of this kind of system need to be further studied, and the effects of extending cross-links to bridge decks/towers on the modal response of the system should be assessed in detail. In this paper, a system of two cables connected by an inter-supported cross-link with another lower cross-link extended to the ground is proposed and analyzed. The characteristic equation of the system is derived, and some limiting solutions in closed form of the system are derived. Roots of cable system with special configurations are also discussed, attention being given to the case when the two cables are identical. A predictable mode behavior was found when the stiffness of inter-connection cross-link and the cross-link extended to the ground were the same. The vector of mode energy distribution and the degree of mode localization index are proposed so as to distinguish global and local modes. The change of mode behaviors is further discussed in the case when the two cables are not identical. Effects of cross-link stiffness, cross-link location, mass-tension ratio, cable length ratio and frequency ratio on $1^{st}$ mode frequency and mode shape are addressed.