• Title/Summary/Keyword: critical degree of corrosion

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The Effect of Burn-out Temperature and Cooling Rate on the Microstructure and Corrosion Behavior of Dental Casting Gold Alloy (치과용 합금 주조 시의 소환온도와 주조 후 냉각방법이 미세조직과 부식거동에 미치는 영향)

  • Lee, Sang-Hyeok;Ham, Duck-Sun;Kim, Hak-Kwan;Jang, Ju-Woong;Kim, Myung-Ho
    • Journal of Technologic Dentistry
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    • v.22 no.1
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    • pp.69-78
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    • 2000
  • The microstructure and corrosion behavior of commercially dental casting gold alloys were investigated to clarify the effect of burn-out temperature and cooling rate. In the case of water quenching after casting, only the αphase, which is typical dendritic microstructure of golda alloy, was detected. However, the precipitates along the grain boundary were detected only at the slow cooling rate and they increased inversely proportional to the burn-out temperature. This might be due to the time difference which solute atom could diffuse. EPMA and SEM results also demonstrated that the precipitate should be lamellar structure consisted of Ag rich phase(${\alpha}_1$) and Cu rich phase (${\alpha}_2$). In terms of corrosion, the galvanic coupling was formed due to the difference of composition between precipitates and matrix at the slow cooling rate. In the case of water quenching, the critical current density($i_p$) which indicate the degree of corrosion was lowest at $650^{\circ}C$ and below the burnout temperature, $i_p$ increased with it because of the effect of grain boundary segregation. But above the temperature, $i_p$ increased with it. This may be due to the strain field effect by residual thermal stress.

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Bond Strength and Development Length Model for Corroded Reinforcing Bars (부식된 철근의 부착강도 및 정착길이 산정모델)

  • Han, Sun-Jin;Lee, Deuckhang
    • Journal of the Earthquake Engineering Society of Korea
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    • v.28 no.5
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    • pp.267-274
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    • 2024
  • This study aims to propose a simplified equation for estimating the bond strength of corroded reinforcing bars. To this end, extensive parametric analyses were performed using the detailed analysis method presented in the authors' previous study, where a wide range of critical variables were considered, such as compressive strength of concrete, net cover thickness, and reinforcing bar diameter. The sensitivity in bond strength of the corroded reinforcing bar according to each variable was evaluated. On this basis, a simplified formula for the bond strength of the corroded reinforcing bar was derived through regression analysis. The proposed equation was rigorously tested and verified using the bond test results of corroded reinforcing bars collected from the literature. The results confirmed that the proposed equation could estimate the bond strengths of specimens with better accuracy than the existing models, providing a reliable tool for engineers and researchers. In addition, the proposed equation was used to analyze the development length required for corroded tensile reinforcement to exert its yield strength, and it showed that the cover thickness of concrete must be at least four times the diameter of the reinforcing bar to achieve the yielding strength of reinforcing bar even at a corrosion degree of more than 5.0%.

Investigation and Evaluation on Performance of Durability for Freeway Concrete Viaducts in Seoul Metropolitan Area (서울시내 위치한 콘크리트 고가차도의 내구성능 조사 및 평가)

  • Lee, Chang-Soo;Yoon, In-Seok
    • Journal of the Korean Society of Hazard Mitigation
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    • v.2 no.1 s.4
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    • pp.143-152
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    • 2002
  • The objectives of this paper were to obtain the fundamental data to analyze the causes of deterioration of 39 freeway concrete viaducts in Seoul metropolitan area. To investigate the degree of concrete deterioration, carbonation depth, soluble chloride concentration in hardened concrete and half-cell potentials of reinforcement were measured. The number of structures which carbonation depth penetrates to reinforcement was 25% of total. The model of carbonation .ate was induced to 3.92 $\sqrt{t}$, which was 5% faster than 3.727 $\sqrt{t}$ assumed 60% water-cement ratio, R=1 in that of kishitani. After measuring chloride concentration in concrete, it was concluded that about 24% of all readings on samples from concrete exceed the critical content to minimize the risk of chloride-induced corrosion. About 31% of the freeway viaducts structures had a value lower than -350mV(vs. CSE), so it could conclude that the excessive chloride concentration was the major cause of reinforcement corrosion. Among the structures which measured half-cell potentials less than -350mV, about 50% exceeds the maximum acceptable limit of chloride concentration.

Evaluation of Shrinkage Cracking Characteristics and Degree of Restraint for Ultra-High-Strength Concrete (초고강도 콘크리트의 수축 균열 특성 및 구속도 평가)

  • Yoo, Doo-Yeol;Min, Kyung-Hwan;Yang, Jun-Mo;Yoon, Young-Soo
    • Journal of the Korea Concrete Institute
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    • v.22 no.5
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    • pp.641-650
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    • 2010
  • The concrete cracking from the restrained stress caused by the shrinkage may play significant cause of deterioration of concrete structures by allowing the permeation of sulphate and chloride ions which in turn triggers corrosion of steel reinforcement. In particular, the cracking becomes more critical as water binder ratio (W/B) is reduced and concrete strength increases. Therefore, it needs to evaluate correctly the comprehensive shrinkage behavior of concrete with high strength: high-strength concrete (HSC), ultra-highstrength concrete (UHSC). The unrestrained shrinkage tests, however, cannot estimate the net shrinkage effectively which affects cracking after full development of strength and stiffness because it does not consider the degree of restraint, strength development, stress relaxation, and so on. Therefore, in this study, both free and restrained shrinkage tests with variables of W/B (W/B of 30, 25 and 16%) and admixtures (fly ash (FA) and granulated blast-furnace slag (BFS)) for HSC, very-high-strength concrete (VHSC) and UHSC were performed. The test results indicated that the autogenous shrinkage and total shrinkage at drying condition were reduced as W/B increased and FA, BFS were added, and the cracking behavior was suppressed as W/B increased and FA was added.

A Study on Resistance of Chloride Ion Penetration in Ground Granulated Blast-Furnace Slag Concrete (고로슬래그 미분말 콘크리트의 염화물 침투 저항성에 관한 연구)

  • Song, Ha-Won;Kwon, Seung-Jun;Lee, Suk-Won;Byun, Keun-Joo
    • Journal of the Korea Concrete Institute
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    • v.15 no.3
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    • pp.400-408
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    • 2003
  • Chloride ion inside concrete destroys the so-called passive film surrounding reinforcing bars inside concrete so that the so-called salt attack accelerates corrosion which is the most critical factor for durability as well as structural safety of reinforced concrete structures. Recently, as a solution of the salt attack, the ground granulated blast-furnace slag(GGBFS) have been used as binder or blended cement more extensively. In this paper, characteristics of chloride ion diffusion for the GGBFS concrete, which is known to possess better resistance to damage due to the chloride ion penetration than ordinary portland cement(OPC) concrete possesses, are analyzed and a chloride ion diffusion model for the GGBFS concrete is proposed by modifying an existing diffusion model for the OPC concrete. The proposed model is verified by comparing diffusion analysis results using the model accelerated chloride penetration test results for concrete specimens as well as field test results for an RC bridge pier. Then, an optimal resistance condition to chloride penetration for the GGBFS concrete is obtained according to degrees of fineness and replacement ratios of the GGBFS concrete. The result shows that the GGBFS concrete has better resistance to chloride ion penetration than OPC concrete has and the resistance is more affected by the replacement ratio than the degree of fineness of the GGBFS.