• Title/Summary/Keyword: critical concentration

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A Study on the Autoignition of Granulated Activated Carbon with Change of Oxygen Concentration (산소농도 변화에 따른 입상활성탄의 자연발화에 관한 연구)

  • 목연수;최재욱;류동현;최일곤;김상렬
    • Journal of the Korean Society of Safety
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    • v.10 no.2
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    • pp.84-91
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    • 1995
  • The characteristics of critical spontaneous ignition of granulated activated carbon were investigated In atmospheres of differing oxygen concentration. At the same concentration the larger vessels yielded the lower critical spontaneous ignition temperature. At the same vessel, as the concentration of oxygen was reduced, Ignition occurred later and at higher ambient temperature, and critical spontaneous ignition temperature increased. The apparent activation energy calculated from the Frank-Kamenetskii's ignition theory appeared to be the slight different value respectively and the mean apparent activation energy was 19850㎈/㏖.

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The Study for Surface Activity of Alkylquinolinium Halide Ⅰ. The Critical Micelle Concentration of Solution of Dodecylquinolinium Bromide (Alkylquinolinium Halide의 계면활성에 관한 연구 Ⅰ. Dodecylquinolinium Bromide 수용액의 Critical Micelle Concentration)

  • Lee Chong-Man
    • Journal of the Korean Chemical Society
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    • v.16 no.4
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    • pp.205-207
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    • 1972
  • Dodecylquinolinium bromide has been synthesized and the critical micelle concentrations of it in the aqueous solution have been determined by the measurement of the surface tension and the electrical conductance. The values are $3.34 {\times} 10^{-3}mole/l$ and 3.41 {\times} $10^{-3}$mole/l, respectively. Since dodecylquinolinium bromide has the larger hydrophobic group than dodecylpyridinium bromide, it is considered that the former has the smaller critical micelle concentration than the latter.

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A Study on the Antimicrobial Effect of Garlic Extract using Super-Critical Carbon Dioxide (초임계 이산화탄소를 이용한 마늘 추출물의 항균효과에 관한 연구)

  • Sung, Ki-Chun
    • Journal of the Korean Applied Science and Technology
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    • v.20 no.1
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    • pp.51-56
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    • 2003
  • Garlic extract using super-critical carbon dioxide is influenced by temperature and pressure, and the optimum condition can make under super-critical state. We can know the defects in process of super-critical extration, It can indicate the drop of product rate, energy loss and equipment expense etcs. The minimum inhibition concentration of microbe which garlic extract contains has apperared the concentration more than 800ppm in this experiment. According to the result of this experiment, we can know that the antibiosis effect in the microbe of staphylococcus and fungus has disappeared in the incubation time more than 12 hours.

Analyses on the recriticality and sub-critical boron concentrations during late phase of a severe accident of pressurized water reactors

  • Yoonhee Lee;Yong Jin Cho;Kukhee Lim
    • Nuclear Engineering and Technology
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    • v.55 no.9
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    • pp.3241-3251
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    • 2023
  • The potential for recriticality and sub-critical boron concentrations is analyzed during the relocation of the fuel rods in the assembly, which we call late phase of a severe accident, via coupling between MELCOR and whole-core Monte Carlo analyses by Serpent 2. The recriticality, initiated during the early phase, is found to maintain when the fuel assemblies containing intact fuel rods are submerged by the cooling water. It is also found that the effect of the negative reactivity insertion via remaining fission products in the fuel debris increases as the burnup increases. The sub-critical boron concentrations during the late phase are found to be 76~544 ppm lower than those during the early phase. Therefore, it can be concluded that the boron concentration that prevents recriticality not only during the early phase but also during the late phase is the sub-critical boron concentration during the early phase.

ON A CLASS OF NONCOOPERATIVE FOURTH-ORDER ELLIPTIC SYSTEMS WITH NONLOCAL TERMS AND CRITICAL GROWTH

  • Chung, Nguyen Thanh
    • Journal of the Korean Mathematical Society
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    • v.56 no.5
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    • pp.1419-1439
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    • 2019
  • In this paper, we consider a class of noncooperative fourth-order elliptic systems involving nonlocal terms and critical growth in a bounded domain. With the help of Limit Index Theory due to Li [32] combined with the concentration compactness principle, we establish the existence of infinitely many solutions for the problem under the suitable conditions on the nonlinearity. Our results significantly complement and improve some recent results on the existence of solutions for fourth-order elliptic equations and Kirchhoff type problems with critical growth.

Determination of Frequency Independent Critical Concentration of Xathan and Carob Mixed Gels

  • Yoon, Won-Byong;Gunasekaran, Sundaram
    • Food Science and Biotechnology
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    • v.16 no.6
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    • pp.1069-1071
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    • 2007
  • The frequency independent critical concentration (Cc) of xanthan and carob (X/C) mixed gel was determined based on the Winter-Chambon's theory. X/C mixed (X/C=1:1 ratio) gels were prepared from 0.1 to 1% of concentration. The linear viscoelastic properties, i.e., storage and loss modulus, of X/C mixed gel at $20^{\circ}C$ were measured by frequency sweep tests. The frequency independence of tangent function of phase angle (tan ${\delta}$) of X/C mixed gels was graphically determined from the intersection of the plot of phase angle against concentration at varied frequencies. The intersection (C=0.43%) was considered to be Cc of X/C mixed gel.

Molecular dynamics study of Al solute-dislocation interactions in Mg alloys

  • Shen, Luming
    • Interaction and multiscale mechanics
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    • v.6 no.2
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    • pp.127-136
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    • 2013
  • In this study, atomistic simulations are performed to study the effect of Al solute on the behaviour of edge dislocation in Mg alloys. After the dissociation of an Mg basal edge dislocation into two Shockley partials using molecular mechanics, the interaction between the dislocation and Al solute at different temperatures is studied using molecular dynamics. It appears from the simulations that the critical shear stress increases with the Al solute concentration. Comparing with the solute effect at T = 0 K, however, the critical shear stress at a finite temperature is lower since the kinetic energy of the atoms can help the dislocation conquer the energy barriers created by the Al atoms. The velocity of the edge dislocation decreases as the Al concentration increases when the external shear stress is relatively small regardless of temperature. The Al concentration effect on the dislocation velocity is not significant at very high shear stress level when the solute concentration is below 4.0 at%. Drag coefficient B increases with the Al concentration when the stress to temperature ratio is below 0.3 MPa/K, although the effect is more significant at low temperatures.

Critical Micelle Concentration of Sucrose Monostearate (모노스테아르산설탕의 Critical Micelle Concentration)

  • Noh Jang Sook;Lee Kwang Soon;Chang Sae Hee;Ahn Woon-Sun
    • Journal of the Korean Chemical Society
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    • v.18 no.5
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    • pp.354-357
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    • 1974
  • The critical micelle concentration(CMC) of sucrose monostearate is determined between 20 and $40^{\circ}C$, and the effect caused by the addition of sucrose distearate on the CMC is also studied. It is found that, when both of monoester and diester are dissolved, the curve of surface tension of the solution versus the concentration shows a discontinuity at about 40 dyne $cm^{-1}$ of the surface tension. The discontinuity is interpreted as the associate formed between monoester and diester changes its surface orientation at this region.

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Physical Characteristics of Hydrophobic Poly(sodium acrylate)s (소수성 성질을 갖는 Poly(sodium acrylate)s의 물리적 특성)

  • Ahn, Beom-Shu
    • Journal of the Korean Applied Science and Technology
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    • v.27 no.4
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    • pp.545-551
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    • 2010
  • Hydrophobically monoendcapped poly(sodium acrylate)s formed hydrophobic microdomains in water. This was concluded on poly(sodium acrylate)s with a linear $C_{12}$-alkyl chain attached specifically at the end of the polymer. There was no well defined CMC (critical micelle concentration), but rather a gradual transition from a micelle free solution to a micelle solution. Steady state fluorescence spectroscopy indicates that the micro domains are rather hydrophobic. At pH 5 in the abscence of salt and at pH 9 in the prescence of 1 M sodium citrate the CAC (critical aggregation concentration) was in the range of 0.1 to 2.4 mM. However at pH 5 there was a linear increase in the transition concentration with a head-group size due to an increase in steric and electrostatic repulsions between polymer main chains. At pH 9 in the abscence of salt the transition concentration was in the range of 1 to 80 mM. For the larger polymers there was a effect which consisted of a concentration gradient of sodium counterion toward the hydrophobic domain. The effect was larger for the larger polymers because of the higher total sodium concentration and the less steep counterion concentration gradient.