• 콘크리트학회논문집
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• 제25권1호
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• pp.99-106
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• 2013

고속 비상체에 의한 충격을 받는 콘크리트는 그 충격력에 의해 관통, 표면관입 및 배면박리뿐만 아니라 균열의 확산에 의해 나타나는 국부적인 파괴 등 정하중을 받을 때와 다른 파괴거동을 보인다. 이러한 콘크리트의 파괴거동은 비상체의 재료적 특성, 충돌속도, 질량 및 기하학적 구조뿐만 아니라 콘크리트의 재료적 특성, 시험체의 크기 및 두께, 보강재료 및 방법 등 다양한 요인에 의해 영향을 받는다. 이 연구에서는 콘크리트 재료의 압축강도에 따른 표면관입깊이 및 배면박리성상에 대하여 평가하고, 섬유보강에 의한 배면박리억제효과에 대하여 검토하고자 하였다. 그 결과 압축강도의 증가로 인하여 표면관입깊이는 감소하였으며, 이 연구 범위의 결과는 수정 NDRC식 및 US ACE식과 유사한 경향을 나타냈다. 반면, 배면박리억제에 있어 압축강도 증가에 의한 영향은 확인할 수 없었으며, 섬유보강에 의한 인성의 향상을 통하여 배면박리를 억제할 수 있었다.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2021년도 가을 학술논문 발표대회
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• pp.125-126
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• 2021

In order to improve the housing culture, construction changes for the utilization of diverse and multifunctional spaces are appearing in response to the increasing diverse needs of consumers. Cellular Light-weight Concrete (CLC) is being developed for use in fire-resistant heat-insulating walls and non-bearing walls. However, manufacturing non-uniformity has become a problem as a drawback due to the use of foamed bubbles and normal temperature curing, and additional research is required. Therefore, in order to suppress cracks due to drying shrinkage, silica sand is mixed with CLC to try to understand its characteristics. In the experiment, the compressive strength from 7 to 28 days of age was measured via a constant temperature and humidity chamber, and the drying shrinkage was analyzed according to each condition using a strain gauge. The compressive strength of matrix tends to decrease as the substitution rate of silica sand increases. This is judged by the result derived from the fact that the specific surface area of silica sand is smaller than that of slag. Based on KS F 2701 (ALC block), the compressive strength of 0.6 products is 4.9 MPa or more as a guide, so the maximum replacement rate of silica sand that satisfies this can be seen at 60%. Looking at the change in drying shrinkage for just 7 days, the shrinkage due to temperature change and drying is 0.7 mm, and the possibility of cracking due to shrinkage can be seen, and it seems that continuous improvement and supplementation are needed in the future.

• Journal of Electrochemical Science and Technology
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• 제13권2호
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• pp.269-278
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• 2022

Utilization of high-voltage electrolyte additive(s) at a small fraction is a cost-effective strategy for a good solid electrolyte interphase (SEI) formation and performance improvement of a lithium-rich layered oxide-based high-energy lithium-ion cell by avoiding the occurrence of metal-dissolution that is one of the failure modes. To mitigate metal-dissolution, we explored fluorinated dual-additives of fluoroethylene carbonate (FEC) and di(2,2,2-trifluoroethyl)carbonate (DFDEC) for building-up of a good SEI in a 4.7 V full-cell that consists of high-capacity silicon-graphite composite (15 wt% Si/C/CF/C-graphite) anode and Li_1.13Mn_0.463Ni_0.203Co_0.203O₂ (LMNC) cathode. The full-cell including optimum fractions of dual-additives shows increased capacity to 228 mAhg^-1 at 0.2C and improved performance from the one in the base electrolyte. Surface analysis results find that the SEI stabilization of LMNC cathode induced by dual-additives leads to a suppression of soluble Mn²⁺-O formation at cathode surface, mitigating metal-dissolution event and crack formation as well as structural degradation. The SEI and structure of Si/C/CF/C-graphite anode is also stabilized by the effects of dual-additives, contributing to performance improvement. The data give insight into a basic understanding of cathode-electrolyte and anode-electrolyte interfacial processes and cathode-anode interaction that are critical factors affecting full-cell performance.