• Title/Summary/Keyword: couplings

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Four-Component Synthesis of 2-(N,N-Dialkylamino)-2,4,6-Cycloheptatrien-1-One Derivatives from Tropolone, an Isocyanide, a Primary Amine and an Aldehyde via Ugi-Smiles Coupling Reaction

  • Massoudi, Abdolhossain;Amini, Issa;Ramazani, Ali;Nasrabadi, Fatemeh Zeinali;Ahmadi, Yavar
    • Bulletin of the Korean Chemical Society
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    • v.33 no.1
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    • pp.39-42
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    • 2012
  • The use of Smiles rearrangement in Ugi-type couplings with tropolone allows very straightforward multicomponent formation of 2-(N,N-dialkylamino)-2,4,6-cycloheptatrien-1-one derivatives. The Ugi four-component reaction of isocyanides with tropolone (2-hydroxy-2,4,6-cycloheptatrien-1-one), primary amines and aldehydes proceeds smoothly and cleanly under mild conditions to afford 2-(N,N-dialkylamino)-2,4,6-cycloheptatrien-1-one derivatives in fairly good yields.

Determination of the Structure for Polysubstituted Flavonoid and 6-C-Glucosyl Flavonoids using $^{13}C-^{1}H$ Long Range Couplings

  • Lee, Min-Won
    • Archives of Pharmacal Research
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    • v.17 no.6
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    • pp.487-489
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    • 1994
  • A flavone glycoside was isolated from the leaves of Betula platyphylla var. latifolia and characterized as $4, 6-Dimethoxy-5-hydroxyflavone-7-O-{\beta}-D-glucoside(pectolinarigenin-7-O-{\beta}-D-glucopy-ranoside)$ by method of chemical and NMR spectral analysis. $^13C-^1H$ long range coupling was confirmative for determination of its substituted position. In connection with this study, 6-C-Glucosylnalingenin and 6-C-Glucosylaromadendrin were confirmed its structures using this technique.

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An Enhanced Skirt Characteristics Triple-Mode Filter

  • Lee, Ja-Hyeon;Nam, Hun;Lim, Yeong-Seog
    • Journal of electromagnetic engineering and science
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    • v.12 no.3
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    • pp.210-215
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    • 2012
  • This paper presents a compact microstrip triple-mode filter with enhanced skirt characteristics. The presented triple-mode filter configuration supports three transmission poles and three transmission zeros within the nearby passband. Two of transmission zeros are generated by a triple-mode resonator itself, and the third one is generated by small cross-couplings between the I/O ports. Each resonance condition and the transmission zero generation conditions are analyzed using an equivalent circuit. The bandpass filter is designed for a 2.4 GHz WLAN. The filter was fabricated with a relative dielectic constant of 3.5 and a thickness of 0.76 mm. The fabricated filter has a small size ($7.9mm{\times}7.2mm$, i.e., $0.107{\lambda}_g{\times}0.098{\lambda}_g$, where ${\lambda}_g$ is guided wavelength at a center frequency) and shows high performing skirt characteristics.

A Study of High Performance Composite Flexible Couplings (고성능 복합재료 가요성 커플링에 관한 연구)

  • Kim P. J.;Park I. K.;Kim K. T.;Woo K.
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2004.04a
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    • pp.79-82
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    • 2004
  • The rotor drive system in rotor-craft carries out power transmission from powerplant to rotors and the drive shafts are fallen into misaligned condition by the vibration of engine and shafts and the deformation of supporting structures. The high performance flexible coupling accommodates these misalignments of drive shafts. In this study, we compare the performance of the metalic flexible coupling with the composite flexible coupling through analytic method to develop the high performance flexible coupling used in the rotor drive system of UAV tilt-rotor.

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LED Light Coupler Design for a Ultra Thin Light Guide

  • Lee, J.H.;Chang, W.;Choi, D.
    • Journal of the Optical Society of Korea
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    • v.11 no.3
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    • pp.113-117
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    • 2007
  • A LED light coupler is proposed for coupling light from a mini side LED of 0.4 mm height to a very thin (${\sim}0.3 mm$) light guide. Due to the ultra thinness of the light guide, conventional light couplings between LEDs and light guides do not provide adequate coupling efficiency. The designed LED coupler is a compound lens of 3.5 mm length, 1.2 mm height, and 3.3 mm width. The courier first collimates the light from the LED and then concentrates the light in a manner similar to a compound parabolic concentrate, (CPC) into the light guide. The exit surface of the coupler is additionally textured to have micro patterns in order to control the radiance profile.

Glassy Dynamics in Giant Magnetoresistive Melt-spun Co-Cu

  • Idzikowski, B.;RoBler, U.K.;Handstein, A.;Eckert, D.;Wolf, M.;Nenkov, K.;Muller, K.H.
    • Journal of Magnetics
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    • v.4 no.3
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    • pp.76-79
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    • 1999
  • We report results on metastable CuCo ribbons at low Co contents (2 and 10 at %), which were prepared by conventional melt-spinning technique and subsequent annealing. The properties of these materials cannot consistently be described by those of an assembly of superparamagnetic single-domain particles. Magnetic measurements related to magnetic dynamics reveal spin-glass-like properties. Especially, we find very slow nonequilibrium relaxation processes in Co10Cu90, which depend on prehistory, when probing the relaxation of the resistivity. The results are clear evidence for frustrated interaction effects due to magnetic couplings between Co clusters or precipitates in these alloys.

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Decoupling of Background and Resonance Scatterings in Multichannel Quantum Defect Theory and Extraction of Dynamic Parameters from Lu-Fano Plot

  • Lee, Chun-Woo
    • Bulletin of the Korean Chemical Society
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    • v.30 no.4
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    • pp.891-896
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    • 2009
  • Giusti-Suzor and Fano introduced translations of the scales of Lu-Fano plots by phase renormalization in order to decouple the intra- and inter-channel couplings in multichannel quantum defect theory (MQDT). Their theory was further developed by others to deal with systems involving a larger number of channels. In different directions, MQDT was reformulated into forms with a one-to-one correspondence to those in Fano's configuration mixing theory of resonance for photofragmentation processes involving one closed and many open channels. In this study, the theory was further developed to fully reveal the coupling nature, decoupling of the background and resonance scattering in physical scattering matrices as well as to further extract the dynamic parameters undiscovered by Fano and his colleagues. This theory was applied to the photoabsorption spectrum of $H_2$ observed by Herzberg's group.

Functionalization of Organotrifluoroborates via Cu-Catalyzed C-N Coupling Reaction

  • Lee, Jung-Hyun;Kim, Heejin;Kim, Taejung;Song, Jung Ho;Kim, Won-Suk;Ham, Jungyeob
    • Bulletin of the Korean Chemical Society
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    • v.34 no.1
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    • pp.42-48
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    • 2013
  • Potassium N-heterobiaryltrifluoroborates were successfully prepared via a selective Cu-catalyzed C-N coupling reaction. The $BF_3K$ moiety was well tolerated under the reaction conditions involving CuI and dimethyl-ethylenediamine (DMEDA) in the presence of DMSO. The Pd-catalyzed Suzuki-Miyaura cross couplings of potassium N-heterobiaryltrifluoroborates with bromoarenes were studied to prepare the N-heterotriaryl compounds. Moreover, homocoupling, iodination, and hydroxylation of potassium N-heterobiaryltrifluoroborates provided the corresponding products in high yields.

A Trend of Direct Drive Traction Motor for Next Generation Railway Vehicles (차세대 철도차량용 직접구동방식 T/M개발관련 기술개발 동향)

  • 권중록;김남해;김근웅;이정일;이종인
    • Proceedings of the KSR Conference
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    • 2002.10a
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    • pp.434-439
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    • 2002
  • The researches on the direct drive system, which directly transfers axle load of the traction motor to wheels, have been developed as a next generation drive system in Japan and Europe. As a result of excluding couplings and gear units, the direct drive system has advantages on the bogie mount space to be smaller sized, lower noisy, more efficient and less weighted than the conventional drive system - indirect drive system. Since the simplification of the direct drive system design depends on the design of the traction motors, the researches on the direct drive system with focusing on the traction motors get started. The advantages/disadvantages of direct drive system, types, structures, cooling systems and interfaces of the traction motors are presented on this paper. Furthermore, the development of other countries on the electric equipments of the next generation railway vehicles are discussed and the necessity & requirement for developing new concepts of traction motors are assured.

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Simultaneous Switching Noise Reduction Technique in Multi-Layer Boards using Conductive Dielectric Substrate (전도성 유전기판을 이용한 다층기판에서의 Simultaneous Switching Noise 감소 기법)

  • 김성진;전철규;이해영
    • Journal of the Microelectronics and Packaging Society
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    • v.6 no.4
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    • pp.9-14
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    • 1999
  • In this paper, we proposed a simultaneous switching noise (SSN) reduction technique in multi-layer boards (MLB) for high-speed digital applications and analyzed it using the Finite Difference Time Domain (FDTD) method. The new structure using conductive dielectric substrates is effective for the reduction of SSN couplings and resonances. The uniform insertion of the conducive layer reduced the SSN coupling and resonance by 85% and the partial insertion only around the edges reduced by 55% respectively.

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