• Title/Summary/Keyword: coupling model

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Use of Plant Materials for Decontamination of Waste Water Polluted with 2,4-Dichlorophenol (2,4-Dichlorophenol로 오염된 폐수의 정화를 위한 식물체의 이용)

  • Lee, Jung-Eun;Park, Jong-Woo;Kim, Jang-Eok
    • Korean Journal of Environmental Agriculture
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    • v.18 no.3
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    • pp.292-297
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    • 1999
  • This study was performed to estimate the possibility of use of plant materials as catalytic agents fur the decontamination of waste waters contaminated with organic pollutants by using 2,4-dichlorophenol(2,4-DCP) as a model pollutant. Plant materials containing high peroxidase activity were selected as catalysts for the removal of 2,4-DCP. Peroxidase activity, which plant materials were containing, was measured, and the greatest peroxidase activity was observed in shepherd's purse, followed by turnip, sweet potato, Chinese cabbage and white radish. The peroxidase activity in shepherd's purse was four times higher than that of horseradish purchased in U.S.A. Using shepherd' s purse and turnip, it was investigated the effect of various factors on the decontamination of 2,4-DCP through oxidative coupling. The removal of 2,4-DCP was extremely fast, and a maximal removal could be achieved within 3 min for shepherd' s purse and 15min for turnip. The pH range was from 3.0 to 8.0 and the amount of $H_2O_2$ added was 9mM when maximal removal was achieved(over 90%). No increasing removal of 2,4-DCP was observed due to increasing the amount of $H_2O_2$ added (over 9mM). The initial concentration affected the transformation of 2,4-DCP incubated with plant materials. When turnip was used as catalytic agent, it was observed decreasing transformation of 2,4-DCP due to increasing initial concentration.

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Hair Strengthening Effect of Silane Coupling and Carbodiimide Chemistry (카르보디이미드 반응과 실란 커플링을 이용한 모발강화 효과)

  • Son, Seong Kil;Choi, Wonkyung;Lim, Byung Tack;Song, Sang-hun;Kang, Nae Kyu
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.44 no.2
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    • pp.133-139
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    • 2018
  • Chemically damaged hair is vulnerable to external stimuli in daily life due to the weakened physical properties of the hair strand itself. The purpose of this work was to determine whether chemical conjugation between hair keratin proteins restores tensile strength and thus results inpreventing further deterioration under repeated combing. A model damaged hair tress was produced by a typical perm-process. Then, it was internally crosslinked by the bifunctional crosslinker (3-aminopropyl)triethoxysilane (APTES), via both silane coupling and carbodiimide chemistry. Physical properties, including tensile strength, Young's modulus, and plateau stress, were measured to verify the effect of internal crosslinking, and the existence of crosslinking was verified by Fourier transform infrared (FT-IR) spectroscopy. The degrees of hair breakage and split ends were evaluated by repeated combing-drying tests. Physical properties of chemically damaged hair were restored by internal crosslinking. Successful crosslinking of APTES via both silane coupling and carbodiimide chemistry was verified by FT-IR spectra. Prevention of breakage and split ends after repeated combing with heat was observed. Human hair can be weakened by chemical damage including perm-processing, so restoring such properties is a major issue in the hair care industry. This work shows that internal crosslinking of damaged hair via chemical conjugation would be a potent method to restore the healthy hair.

Tunable Interlayer Exchange Coupling Energy (조절 가능한 층간교환상호작용에 관한 연구)

  • Ha, Seung-Seok;You, Chun-Yeol
    • Journal of the Korean Magnetics Society
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    • v.16 no.2
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    • pp.130-135
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    • 2006
  • We theoretically demonstrate that the interlayer exchange coupling (IEC) energy can be manipulated by means of an external bias voltage in a $F_1/NM/F_2/S$$(F_1:ferromagnetic,\;NM:nonmagnetic\;metallic,\;F_2:ferromagnetic,\;S:semiconductor\;layers)$ four-layer system. It is well known that the IEC energy between two ferromagnetic layers separated by nanometer thick nonmagnetic layer depends on the spin-dependence of reflectivity to the $F_1/NM/F_2/S$ four-layer system, where the reflectivities at the interface in $NM/F_2$ interface also depends on $F_2/S$ interface due to the multiple reflection of an electron-like optics. Finally, the IEC energy depends on the spin-dependent electron reflectivity not only at the interfaces of $F_1/NM/F_2$, but also at the interface of $F_2/S$. Naturally the Schottky barrier is formed at the interface between metallic ferromagnetic layer and semiconductor, the Schottky barrier height and thickness can be tailored by an external bias voltage, which causes the change of the spin-dependent reflectivity at $F_2/S$ interface. We show that the IEC energy between two ferromagnetic layers can be controlled by an external bias voltage due ti the electron-optics nature using a simple free-electron-like one-dimensional model.

Nature of the Interfacial Regions in the Antiferromagnetically-coupled Fe/Si Multilayered Films

  • Moon, J.C.;Y.V. Kudryavtsev;J.Y.Rhee;Kim, K.W.;Lee, Y.P.
    • Proceedings of the Korean Vacuum Society Conference
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    • 2000.02a
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    • pp.174-174
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    • 2000
  • A strong antiferromagnetic coupling in Fe/Si multilayered films (MLF) had been recently discovered and much consideration has been given to whether the coupling in the Fe/Si MLF system has the same origin as the metal/metal MLF. Nevertheless, the nature of the interfacial ron silicide is still controversial. On one hand, a metal/ semiconductor structure was suggested with a narrow band-gap semiconducting $\varepsilon$-FeSi spacer that mediates the coupling. However, some features show that the nature of coupling can be well understood in terms of the conventional metal/metal multilayered system. It is well known that both magneto-optical (MO) and optical properties of a metal depend strongly on their electronic structure that is also correlated with the atomic and chemical ordering. In this study, the nature of the interfacial regions is the Fe/Si multilayers has been investigated by the experimental and computer-simulated MO and optical spectroscopies. The Fe/Si MLF were prepared by rf-sputtering onto glass substrates at room temperature with the number of repetition N=50. The thickness of Fe sublayer was fixed at 3.0nm while the Si sublayer thickness was varied from 1.0 to 2.0 nm. The topmost layer of all the Fe/Si MLF is Fe. In order to carry out the computer simulations, the information on the MO and optical parameters of the materials that may constitute a real multilayered structure should be known in advance. For this purpose, we also prepared Fe, Si, FeSi2 and FeSi samples. The structural characterization of Fe/Si MLF was performed by low- and high -angle x-ray diffraction with a Cu-K$\alpha$ radiation and by transmission electron microscopy. A bulk $\varepsilon$-FeSi was also investigated. The MO and optical properties were measured at room temperature in the 1.0-4.7 eV energy range. The theoretical simulations of MO and optical properties for the Fe/Si MLF were performed by solving exactly a multireflection problem using the scattering matrix approach assuming various stoichiometries of a nonmagnetic spacer separating the antiferromagnetically coupled Fe layers. The simulated spectra of a model structure of FeSi2 or $\varepsilon$-FeSi as the spacer turned out to fail in explaining the experimental spectra of the Fe/Si MLF in both intensity and shape. Thus, the decisive disagreement between experimental and simulated MO and optical properties ruled out the hypothesis of FeSi2 and $\varepsilon$-FeSi as the nonmagnetic spacer. By supposing the spontaneous formation of a metallic ζ-FeSi, a reasonable agreement between experimental and simulated MO and optical spectra was obtained.

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Array Calibration for CDMA Smart Antenna Systems

  • Kyeong, Mun-Geon;Park, Hyung-Geun;Oh, Hyun-Seo;Jung, Jae-Ho
    • ETRI Journal
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    • v.26 no.6
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    • pp.605-614
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    • 2004
  • In this paper, we investigate array calibration algorithms to derive a further improved version for correcting antenna array errors and RF transceiver errors in CDMA smart antenna systems. The structure of a multi-channel RF transceiver with a digital calibration apparatus and its calibration techniques are presented, where we propose a new RF receiver calibration scheme to minimize interference of the calibration signal on the user signals. The calibration signal is injected into a multi-channel receiver through a calibration signal injector whose array response vector is controlled in order to have a low correlation with the antenna response vector of the receive signals. We suggest a model-based antenna array calibration to remove the antenna array errors including mutual coupling errors or to predict the element patterns from the array manifold measured at a small number of angles. Computer simulations and experiment results are shown to verify the calibration algorithms.

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A New Approach to Motion Modeling and Autopilot Design of Skid-To-Turn Missiles

  • Chanho Song;Kim, Yoon-Sik
    • Transactions on Control, Automation and Systems Engineering
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    • v.4 no.3
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    • pp.231-238
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    • 2002
  • In this paper, we present a new approach to autopilot design for skid-to-turn missiles which may have severe aerodynamic cross-couplings and nonlinearities with angle of attack. The model of missile motion is derived in the maneuver plane and, based on that model, pitch, yaw, and roll autopilot are designed. They are composed of a nonlinear term which compensates for the aerodynamic couplings and nonlinearities and a linear controller driven by the measured outputs of missile accelerations and angular rates. Besides the outputs, further information such as Mach number, dynamic pressure, total angle of attack, and bank angle is required. With the proposed autopilot and simple estimators of bank angle and total angle of attack, it is shown by computer simulations that the induced moments and some aerodynamic nonlinearities are properly compensated and that the performance is superior to that of the conventional ones.

Finite Element Method (FEM) Study on Space Charge Effects in Organic Light Emitting Diodes (OLED)

  • Kim, Kwang-Sik;Hwang, Young-Wook;Won, Tae-Young
    • JSTS:Journal of Semiconductor Technology and Science
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    • v.12 no.4
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    • pp.467-472
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    • 2012
  • In this paper, we present a finite element method (FEM) study on the space charge effects in organic light emitting diodes. The physical model covers all the key physical processes in OLEDs, namely charge injection, transport and recombination, exciton diffusion, transfer and decay as well as light coupling, and thin-film-optics. The exciton model includes generation, diffusion, and energy transfer as well as annihilation. We assumed that the light emission originates from oscillation which thus is embodied as exciton in a stack of multilayer. We discuss the accumulation of charges at internal interfaces and their signature in the transient response as well as the electric field distribution. We also report our investigation on the influence of the insertion of the emission layer (EML) in the bilayer structure.

A Study on the Reduction of Differential Vibration of FR Passenger Car (후륜구동 승용차의 디퍼렌셜 진동저감에 관한 연구)

  • 최은오
    • Proceedings of the Korean Society of Machine Tool Engineers Conference
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    • 1997.10a
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    • pp.316-321
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    • 1997
  • The purpose of this study is to reduce the vibration noise of differential gear by reducing torque fluctuation of drive pinion shaft which causes vibration noise of differential gear in rear wheel drive vehicles. For this we developed multi-degree of freedom analysis model in which mass moment of inertia and torsional spring combined, the validity of the simulation model was checked by the field test and we examined the influence of torsional vibration of driveline elements by performing forced vibration analysis of engine excitation torque. We studied the methods for reducing torsional vibration of driveline according to the design factor of propeller shaft and examined the effects reducing vibration differential gear by applying flexible coupling.

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Modal Sky-Hook Dampers for Active Suspension Control (능동형 현가시스템을 위한 모드 SKY-HOOK 감쇠 제어기)

  • 곽병학;박영진
    • Transactions of the Korean Society of Automotive Engineers
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    • v.3 no.4
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    • pp.1-11
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    • 1995
  • Active suspension control for vehicles is developed to improve both ride comfort and steering stability which are in trade off relation. In this study, the modal sky-hook controller for 7 D. O. F. model is proposed to resolve the problems such as computaional power restriction and uncertainties in modeling of systems and environments. Modal sky-hook controller reduces the coupling between the modes to be controlled. The simulation result for ride comfort shows that the perform ance of the proposed controller matches that of the optimal controller. Systematic method of determining its gain is proposed. The model sky-hook controller shows the robustness to road irregularity and modeling error.

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Application of Virtual SEA for the Prediction of Acoustic Performance of Cockpit (칵핏 흡차음 성능 예측을 위한 Virtual SEA 의 활용)

  • Jeong, Won-Tae;Ko, Chang-Sung;Park, Hyung-Hwan
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2007.11a
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    • pp.903-912
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    • 2007
  • One of the crucial factors which determine the quality and the accuracy of SEA model is how subsystems are defined. Experimental SEA technique had been a unique way to divide entire systems accurately for mid-frequency range, until FEA based virtual FRF response technique, virtual SEA method presented. Virtaul SEA has been developed for predictive SEA tool in early design process. In this study, Modal analysis results from modified crash FE model is used for Statistical transfer matrix. Observation nodes on the cockpit are grouped by attractive substructuring method based on point to point transfer and correlation matrix. Complex cockpit structure is divided into subsystems by automatic substructuring. Comparison with experimental SEA results validates the application of Virtual SEA to cockpit.

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