• Title/Summary/Keyword: coupling material

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Synthesis and Characterization of Graphene and Graphene Oxide Based Palladium Nanocomposites and Their Catalytic Applications in Carbon-Carbon Cross-Coupling Reactions

  • Lee, Minjae;Kim, Bo-Hyun;Lee, Yuna;Kim, Beom-Tae;Park, Joon B.
    • Bulletin of the Korean Chemical Society
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    • v.35 no.7
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    • pp.1979-1984
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    • 2014
  • We have developed an efficient method to generate highly active Pd and PdO nanoparticles (NPs) dispersed on graphene and graphene oxide (GO) by an impregnation method combined with thermal treatments in $H_2$ and $O_2$ gas flows, respectively. The Pd NPs supported on graphene (Pd/G) and the PdO NPs supported on GO (PdO/GO) demonstrated excellent carbon-carbon cross-coupling reactions under a solvent-free, environmentally-friendly condition. The morphological and chemical structures of PdO/GO and Pd/G were fully characterized using X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and transmission electron microscopy (TEM). We found that the remarkable reactivity of the Pd/G and PdO/GO catalysts toward the cross-coupling reaction is attributed to the high degree of dispersion of the Pd and PdO NPs while the oxidative states of Pd and the oxygen functionalities of graphene oxide are not critical for their catalytic performance.

Characteristics according to increase of the fault current level of Flux-Coupling Type Superconducting Fault Current Limiter(SFCL) (자속커플링 SFCL의 사고전류 변화에 따른 전류제한특성 분석)

  • Kim, Yong-Jin;Han, Byoung-Sung;Du, Ho-Ik;Park, Chung-Ryul;Du, Seung-Gyu;Kim, Min-Ju;Ha, Seung-Ryong
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.06a
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    • pp.288-288
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    • 2008
  • The flux-coupling type superconducting fault current limiter(SFCL) is composed of a series transformer and superconducting unit of the YBCO thin films. The primary and secondary coils in the transformer were wound in series each other through an iron core and the YBCO thin film was connected with secondary coil in parallel. In a normal condition, the flux generated from a primary coil is cancelled out by its structure and the zero resistance of the YBCO thin films. When a fault occurs, the resistance of the YBCO thin films was generated and the fault current was limited by the SFCL. In this paper, we investigated the fault current limiting characteristics according to fault current level in the flux-coupling type SFCL. The experiment results that the fault current limiting characteristics was improved according to increase of the fault current level.

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Analysis on Current Limiting and Voltage Sag Compensating Characteristics of a SFCL using Magnetic Coupling of Parallel Connected Two Coils (병렬연결된 두 코일의 자기결합을 이용한 초전도 전류제한기의 전류제한 및 전압강하 보상 특성 분석)

  • Lim, Sung-Hun
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.23 no.2
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    • pp.159-163
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    • 2010
  • The superconducting fault current limiter (SFCL) plays a role in compensating the voltage sag of the sound feeder adjacent to the fault feeder as well as the fault current limiting operation of the fault feeder. Especially, the SFCL using magnetic coupling of two coils with parallel connection has different voltage sag compensating and current limiting characteristics due to the winding direction and the inductance ratio of two coils. In this paper, the current limiting and the voltage sag compensating characteristics of a SFCL using magnetic coupling of parallel connected two coils were analyzed. Through the analysis on the experimental results considering the winding direction of two coils, the SFCL designed with the additive polarity winding was shown to have the higher limited fault current than the SFCL designed with the subtractive polarity winding. In addition, it could be confirmed that the higher fault current limitation of the SFCL could be contributed to the higher load voltage sag compensation.

Optimization of the Coupling and the Reflector Material in the DOI PET Detector Module using the WLS Fiber (파장변이섬유를 사용하는 반응 위치 측정 양전자방출 단층촬영기기 검출기 모듈의 연결물질과 반사체 물질의 최적화)

  • Lee, Seung-Jae
    • Journal of the Korean Society of Radiology
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    • v.13 no.1
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    • pp.15-20
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    • 2019
  • We developed a novel depth-of-interaction positron emission tomography (PET) detector using wavelength shifting (WLS) fibers and optimized it. The optimization module was designed by using two scintillators and three WLS fibers and attaching a sensor to the end of the WLS fiber. Optimum combinations were obtained through the light collection efficiency and the light collection ratio between sensors depending on coupling materials and reflectors of scintillators, WLS fibers and sensors. The highest light collection efficiency and the light collection ratio between sensors were obtained in the combination of the epoxy (coupling materials)-diffuse reflector (scintillators)-specular reflector (WLS fibers).

Fabrication of Circulation Structures of Microfluidic Devices for Observation and Analysis of Micrometer-Scale Chemical Reactions (마이크로미터 단위 화학 반응 관찰 및 분석을 위한 미세 유량 제어 장치의 순환구조 제작 연구)

  • Jang, Wonjun;Lee, Namjong;Jung, Dawoon;Kim, Hong-Seok;Jung, Seung Chan;Han, Jae-Hee
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.35 no.4
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    • pp.342-347
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    • 2022
  • In-situ analyzation and detection of real-time chemical reactions can be a significant part in interpreting the underlying mechanism in very reactive chemical reactions. To do this, first we have designed a microfluidic device (MFD) pattern for observation of synthesis of hierarchical nanostructures based on graphene oxide (GO), conjugating the well-known coupling reaction by which the solution of 1-ethyl-3-(3-dimethylaminopropyl) carbodiimide (EDC)-mediated coupling is enhanced in the presence of n-hydroxysuccinimide (NHS) to make amide bonding, hereafter called as the EDC coupling. Then, we have manufactured microfluidic devices with multiple tens of micrometer-sized channels that can circulate those nanomaterials to be chemically reacted in the channels. These microfluidic devices were made by negative photo lithography and soft lithography. We showed the possibility of using Raman spectroscopy to reveal the basic mechanism of the energy storage applications.

The medium coupling effect on propagation of guided waves in engineering structures and human bone phantoms

  • Chen, Jiangang;Su, Zhongqing;Cheng, Li
    • Coupled systems mechanics
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    • v.1 no.4
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    • pp.297-309
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    • 2012
  • As a result of the medium coupling, propagation characteristics of ultrasonic waves guided by a multi-phase medium can be different from those in a homogeneous system. This phenomenon becomes prominent for a medium consisting of phases with considerably distinct material and physical properties (e.g., submerged structures or human bones covered with soft tissues). In this study, the coupling effect arising from both fluid and soft tissues on wave propagation in engineering structures and human bone phantoms, respectively, was explored and calibrated quantitatively, with a purpose of enhancing the precision of ultrasonic-wave-based non-destructive evaluation (NDE) and clinical quantitative ultrasound (QUS). Calibration results were used to rectify conventional NDE during evaluation of corrosion in a submerged aluminium plate, and QUS during prediction of simulated healing status of a mimicked bone fracture. The results demonstrated that with the coupling effect being appropriately taken into account, the precision of NDE and QUS could be improved.

Surface Modification of Glass Fiber for Polymer Insulator by Plasma Surface Treatment (플라즈마 표면처리에 따른 고분자절연재료용 유리섬유의 표면개질)

  • 임경범;이덕출
    • The Transactions of the Korean Institute of Electrical Engineers D
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    • v.52 no.5
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    • pp.206-206
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    • 2003
  • It is hard to expect excellent electrical, mechanical and chemical properties from most of the composite materials presently used as insulators due to insufficient wettability property caused by the difference of interfacial properties between the matrix material and the reinforcer. Therefore, various interfacial coupling agents have been developed to improve the interfacial properties of composite materials. But if the wettable coupling agents are used outdoor for a long time, change in quality takes place in the coupling agents themselves, bringing about deterioration of the properties of the composite materials. In this study, glass surface was treated by plasma to examine the effect of dry interface treatment without coupling agent. It was identified that the optimum parameters for the best wettability of the samples at the time of generation of plasma were oxygen atmosphere, 0.1 torr of system pressure, 100 W of discharge power, and 3 minutes of discharge time. Also, the surface resistance rate and dielectric property were improved.

Surface Modification of Glass Fiber for Polymer Insulator by Plasma Surface Treatment (플라즈마 표면처리에 따른 고분자절연재료용 유리섬유의 표면개질)

  • 임경범;이덕출
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.52 no.5
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    • pp.206-212
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    • 2003
  • It is hard to expect excellent electrical, mechanical and chemical properties from most of the composite materials presently used as insulators due to insufficient wettability property caused by the difference of interfacial properties between the matrix material and the reinforcer. Therefore, various interfacial coupling agents have been developed to improve the interfacial properties of composite materials. But if the wettable coupling agents are used outdoor for a long time, change in quality takes place in the coupling agents themselves, bringing about deterioration of the properties of the composite materials. In this study, glass surface was treated by plasma to examine the effect of dry interface treatment without coupling agent. It was identified that the optimum parameters for the best wettability of the samples at the time of generation of plasma were oxygen atmosphere, 0.1 torr of system pressure, 100 W of discharge power, and 3 minutes of discharge time. Also, the surface resistance rate and dielectric property were improved.

Effect of Heat Treatment on the Adhesive Strength of Electoless Nickel Deposits (무전해법으로 Slide Glass 위에 도금된 Ni층의 접착력에 미치는 열처리의 영향)

  • Hyun, Yong-Min;Yu, Sung-Yeol;Yoon, Jung-Yun;Kim, Bo-Young;Kim, Sun-Ji;Tahk, Song-Hee;Kim, Hee-San
    • Journal of the Korean institute of surface engineering
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    • v.44 no.6
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    • pp.246-249
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    • 2011
  • Surface modification before coating nickel by coupling agents and/or etchant of glass did not provide enough adhesive strength of electroless nickel deposits on glass. Effect of heat treatments on hardness as well as adhesion of nickel deposits was studied by using tape test for adhesion, nanoindenter for hardness and glancing angle x-ray diffractometer (GAXRD) for phase characterization. Heat treatment improved hardness as well as adhesion. XRD results give that the improvements of adhesion and hardness are due to the formation of $NiSiO_4$ around the interface between the nickel deposits and the glass and the precipitation of $Ni_3P$ causing precipitation hardening, respectively. The details in effects of heat treatment on adhesion and hardness are described here.

Analysis of Coupling Loss with Size and Material in the KSTAR PF Superconducting Coils (KSTAR PF 초전도자석의 크기 및 재료에 따른 결합손실 특성 분석)

  • Lee, H.J.;Chu, Y.;Lee, S.;Park, Y.M.;Park, H.T.;Oh, Y.K.
    • Progress in Superconductivity and Cryogenics
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    • v.11 no.3
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    • pp.1-5
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    • 2009
  • It is important to predict AC loss in $Nb_3Sn$ and NbTi cable-in-conduit-conductor (CICC) reliably for the design and operation of large superconducting coils. The hysteresis loss in the superconducting filaments and coupling loss within strands and among strands in a cable or composite are dominant ac losses in superconducting magnets. The coupling loss in a superconductor can be characterized by identifying the coupling constant time $n{\tau}$. To reduce the coupling loss, all the strands (superconductor and Cu) in KSTAR (Korea Superconducting Tokamak Advance Research) are chromium plated with thickness of $l{\pm}0.5{\mu}m$. The ac losses of PF1, PF5 and PF6 coils has been measured by calorimetric method while applying trapezoidal current pulses with various ramp rate from 0.5 kA/s to 2 kA/s. The coupling time constants for $Nb_3Sn$ coils are $25{\sim}55$ ms and the values are not co-related with the coil size, the time constants for NbTi coil is 30 ms.