• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.19 no.6
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• pp.568-573
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• 2006

We have synthesized new blue light emitting random copolymers, poly(9,9'-n-dioctylfluorene-co-perfluorobenzene-1,4-diyl)s (PFFBs), via Ni(0)-mediated coupling reactions. The weight-average molecular weights ($M_w$) of the PFFB copolymers ranged from 9,000 to 15,000. The PFFB copolymers dissolved in common organic solvents such as THF and toluene. The PL emission peaks of the PFFB copolymers were at around 420, 440, and 470 nm. EL devices were fabricated in ITO/PEDOT/polymer/Ca/Al configurations using these polymers. These EL devices were found to exhibit pure blue emission with approximate CIE coordinates of (0.15, 0.11) at $100cd/m^2$. The blue emissions of these devices might be due to the restriction of the polymer chains to aggregation by introducing of the highly electronegative fluorine moieties. The maximum brightnesses of the PFFB copolymer devices ranged from 140 to $3600cd/m^2$ with maximum efficiencies from 0.2 to 0.6 cd/A. The enhanced efficiency of the PFFB (8/2) copolymer device results from the inhibition of excimer formation by the introduction of the electronegative fluorine moieties into the copolymers.

• Journal of Power Electronics
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• v.15 no.2
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• pp.366-377
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• 2015

In order to minimize switching losses for high power applications, a boost PFC rectifier with a novel passive lossless snubber circuit is proposed. The proposed lossless snubber is composed of coupled inductors merged into a boost inductor. This method compared with conventional methods does not need additional inductor cores and it reduces extra costs to implement a soft switching circuit. Especially, the proposed circuit can reduce the reverse recovery current of output diode rectifiers due to the coupling effect of the inductor. During turn-on and turn-off operating modes, the proposed PFC converter operates under soft switching conditions with high power conversion efficiency. In addition, the performance improvement and analysis of the operating effects of the coupled inductors were also presented and verified with a 3.3 kW prototype rectifier.

• Journal of Power Electronics
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• v.17 no.3
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• pp.777-787
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• 2017

A new single phase half-bridge cascaded multilevel inverter based series active power filter (SAPF) is proposed. The main parts of the inverter are presented in detail. With the proposed inverter topology, any compensation voltage reference can be easily obtained. Therefore, the inverter acts as a harmonic source when the reference is a non-sinusoidal signal. A 31-level inverter based SAPF with the proposed topology, is manufactured and the voltage harmonics of the load connected to the point of common coupling (PCC) are compensated. There is no need for a parallel passive filter (PPF) since the main purpose of the paper is to represent the compensation capability of the SAPF without a PPF. It is aimed to compensate the voltage harmonics of the load fed by a non-sinusoidal supply using the proposed inverter. The validity of the proposed inverter based SAPF is verified by simulation as well as experimental study. The system efficiency is also measured in this study. Both simulation and experimental results show that the proposed multilevel inverter is suitable for SAPF applications.

• The Transactions of the Korean Institute of Power Electronics
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• v.22 no.2
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• pp.150-158
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• 2017

This study proposes a new pulse-width modulation switching pattern for the low conduction loss of a three-level neutral point clamped (NPC)-based dual-active bridge (DAB) converter. The operational principle for a bidirectional power conversion is a phase-shift modulation. The conventional switching method of the three-level NPC-based DAB converter shows a symmetric switching pattern. This method has a disadvantage of high root-mean-square (RMS) value of the coupling inductor current, which leads to high conduction loss. The proposed switching method shows an asymmetrical pattern, which can reduce the RMS value of the inductor current with lower conduction loss than that of the conventional method. The performance of the proposed asymmetrical switching method is theoretically analyzed and practically verified using simulation and experiment.

• Journal of Power Electronics
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• v.18 no.1
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• pp.289-299
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• 2018

Electric-field coupled power transfer (ECPT) systems employ a high frequency electric field as an energy medium to transfer power wirelessly. Existing ECPT systems have made great progress in terms of increasing the transfer distance. However, the topologies of these systems are complex, and the transfer characteristics are very sensitive to variations in the circuit parameters. This paper proposes an ECPT system with a double-sided LC network, which employs a parallel LC network on the primary side and a series LC network on the secondary side. With the same transfer distance and output power, the proposed system is simpler and less sensitive than existing systems. The expression of the optimal driving voltage for the coupling structure and the characteristics of the LC networks are also analyzed, including the transfer efficiency, parameter sensitivity and total harmonic distortion. Then, a design method for the system parameters is provided according to these characteristics. Simulations and experiments have been carried out to verify the system properties and the design method.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2004.07a
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• pp.559-562
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• 2004

The $high-T_c$ Superconducting(HTS) antenna which consists of "H" type resonator has the benefits for the miniaturization of antenna in comparison with the microstrip antenna of the similar dimension. To fabricate the "H" type antenna HTS $YBa_2Cu_3O_{7-x}$(YBCO) thin films were deposited on MgO substrates using rf-magnetron sputtering. Standard etching processes were performed for the patterning of the "H" type antenna. For comparison between normal conducting antennas and superconducting antennas, the gold antennas with the same dimension were also fabricated. An aperture coupling was used for impedance matching between $50\Omega$ feed line and HTS radiating patch. The diverse experimental results were reported in terms of the resonant frequency, the return loss and the characteristics impedance. The "H" type superconducting antenna showed the performance of 1.36 in SWR, 24 % in efficiency, and 14.6 dB in the return loss superior to the normal conducting counterpart.

• Journal of Photoscience
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• v.2 no.1
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• pp.19-25
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• 1995

Picosecond time-resolved and static protein fluorescence spectra and absorption spectra of octopus rhodopsin, a photorecepting protein, are measured and compared with those of bacteriorhodopsin, a photon-induced proton pumping protein, to understand the protein conformations and functions of octopus rhodopsin and its deprotonated photocycle intermediate. The bluer and weaker absorption of retinal indicates that octopus rhodopsin is better in thermal noise suppression but less efficient in light harvesting than bacteriorhodopsin. The protein fluorescence of octopus rhodopsin shows the characteristic of Trp only and the uantum efficiency and lifetime variations may result primarily from variations in the coupling strength with the retinal. The stronger intensity by four times and larger red shift by 12 nm of fluorescence suggest that octopus rhodopsin has more open and looser structure compared with bacteriorhodopsin. Fluorescence decay profiles reveal two decay components of 300 ps (60%) and 2 ns (40%). The deprotonation of protonated Schiff's base increases the shorter decay time to 500 ps and enhances the fluorescence intensity by 20%. The fluorescence and its decay time from Trp residues near retinal are influenced more by the deprotonation. The increase of fluorescence intimates that protein structure becomes loosened and relaxed further by the deprotonation of protonated Schiff's base. The driving force of sequential changes initiated by absorption of a photon is too exhausted after the deprotonation to return the intermediate to the ground state of the begun rhodopsin form.

• Textile Coloration and Finishing
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• v.4 no.4
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• pp.81-89
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• 1992

Graft polymers of alginic acid-PMMA, different in composition and Mv of branched PMMA, were prepared by emulsion graft polymerization at various MMA concentrations. In aqueous dispersion solution, the adsorption of graft polymer on the montmorillonite was carried out to modify the surface property of powder, and the adsorption of PMMA in organic solvents (acetone, benzene) on the modified surface of powder were observed. The results obtained were as follows. 1. In emulsion graft polymerization of MMA on the sodium alginate in aqueous solution, SA conversion, MMA conversion and % grafting were increased with increasing MMA concentration where as graft efficiency was decreased. 2. The adsorption amount of graft polymer was increased with the elevation of temperature and the increased of dispersion concentration and with the increase of branched PMMA composition of graft polymer. 3. In organic solvent, the adsorption of PMMA on the surface modified particle was proceeded by the orientation along the stretched branched PMMA of adsorbed graft polymer which is in radial direction to the particle surface. 4. The adsorbed amount of PMMA was increased as the temperature and concentration of PMMA solution, the branching of adsorbed graft polymer and the solvency of solvent were increased.

• Bulletin of the Korean Chemical Society
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• v.21 no.4
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• pp.393-400
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• 2000

2,2￠-Dihydroxyazobenzene (DHAB) was attached to poly(ethylenimine) (PEI) to obtain DHAB-PEI. Spectral titration revealed that uranyl, Fe(III), Cu(II), and Zn(II) ion form 1 : 1-type complexes with DHAB attached to PEI. Formation constants for the metal complexes formed by the DHAB moieties of DHAB-PEI were mea-sured by using various competing ligands. The results indicated thatthe concentrations of uranyl, Fe(III), and Cu(II) ions can be reduced to 10 -16 -10 -23 M at p 8 with DHAB-PEI when the concentration of the DHAB moiety is 1 residue M. By using cyanuric chloride as the coupling reagent, DHAB-PEI was immobilized on Sephadex G-25 resin to obtain DHAB-PEI-Seph. Binding of uranyl,Fe(III), Cu(II), and Zn(II) ion by DHAB-PEI-Seph was characterized by using competing ligands. A new method has been developed for characteriza-tion of metal sequestering ability of a chelating resin. Formation constants and metal-binding capacity of two sets of binding sites on the resin were estimated for each metal ion. DHAB-PI-Seph was applied to recovery of metals such as uranium,Fe, Cu, Zn, Pb, V, Mn, and W from seawater. The uranium recovery from seawaterby DHAB-PEI-Seph does not meet the criterion for economical feasibility partlydue to interference by Fe and Zn ions. The seawater used in the experiment was contaminated by Fe and Zn and, therefore, the efficiency of uranium extractionfrom seawater with DHAB-PEI-Seph could be improved if the experiment is carried out in a cleaner sea.

• Proceedings of the Korea Water Resources Association Conference
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• 2019.05a
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• pp.158-158
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• 2019

Recent studies show the possibility of more frequent extreme events as a result of the changing climate. These weather extremes, such as excessive rainfall, result to debris flow, river overflow and urban flooding, which post a substantial threat to the community. Therefore, an effective flood model is a crucial tool in flood disaster mitigation. In recent years, a number of flood models has been established; however, the major challenge in developing effective and accurate inundation models is the inconvenience of running multiple models for separate conditions. Among the solutions in recent researches is the development of the combined 1D-2D flood modeling. The coupled 1D-2D river flood modeling allows channel flows to be represented in 1D and the overbank flow to be modeled over two-dimension. To test the efficiency of this approach, this research aims to assess the capability of HEC-RAS model's implementation of the combined 1D-2D hydraulic simulation of river overflow inundation, and compare with the results of GERIS and FLUMENS 2D flood model. Results show similar output to the flood models that had used different methods. This proves the applicability of the HEC-RAS 1D-2D coupling method as a powerful tool in simulating accurate inundation for flood events.