• 대한화학회지
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• 제37권1호
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• pp.43-48
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• 1993

핵자기공명분광법으로 일련의 n-알코올 용액에서 N-에틸아세트미드(NEAA) NH-기의 $^1H-NMR$ 스펙트럼을 310~350k 온도 영역에서 찍어내었다. $^{14}N$-핵에 짝짓기를 한 $^1H$-스펙트럼의 선모양을 분석하여 NEAA의 재배향 상관관계시간 ${\tau}_c$를 얻었다. 용질과 용매의 상호작용은 용매의 사슬 길이가 증가하면서 감소하는 것을 실험 데이타는 보여주고 있다. 그러나 알코올 용매에서 재배향 운동은 실험한 온도영역에서 용매의 η/T에 거의 선형적으로 비례하였다. 그 결과를 subslip 현상으로 고찰하였다.

• Journal of electromagnetic engineering and science
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• 제14권4호
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• pp.329-331
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• 2014

A simple realization of an alignment-free wireless power transmission (WPT) system is presented in this letter. The WPT system consists of a transmitter with three reconfigurable modes corresponding to various controllable magnetic field directions in the azimuthal plane and an algorithm for the optimum mode selection carried by sensing the reflected voltage of the system. Twelve light emitting diodes (LEDs) are used to confirm the on- and off-state of LEDs powered wirelessly by the transmitter at every $15^{\circ}$ of the azimuthal plane. A criterion voltage from the reflected power of the system is found by using the correlation between the reflected voltage and the on- and off-state of the LEDs. Simply by continuous; monitoring of the voltage from the system, the system maintains power to the LEDs. The system is realized by MATLAB/Simulink and a National Instrument data acquisition device (DAQ) board. Measurements using the system show on-state LEDs in the azimuthal plane except at the angles of $60^{\circ}$, $75^{\circ}$, $180^{\circ}$, and $300^{\circ}$.

• 대한기계학회논문집A
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• 제31권2호
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• pp.182-189
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• 2007

This paper is concerned with the empirical flow stress constitutive equation of steel sheets for an auto-body with the variation of temperature and strain rate. In order to represent the strain rate and temperature dependent behavior of the flow stress at the intermediate strain rates accurately, an empirical hardening equation is suggested by modifying the well-known Khan-Huang-Liang model. The temperature and strain rate dependent sensitivity of the flow stress at the intermediate strain rate is considered in the hardening equation by coupling the strain, the strain rate and the temperature. The hardening equation suggested gives good correlation with experimental results at various intermediate strain rates and temperatures. In order to verify the effectiveness and accuracy of the suggested model quantitatively, the standard deviation of the fitted result from the experimental one is compared with those of the other two well-known empirical constitutive models such as the Johnson-Cook and the Khan-Huang-Liang models. The comparison demonstrates that the suggested model gives relatively well description of experimental results at various strain rates and temperatures.

• Structural Engineering and Mechanics
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• 제39권1호
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• pp.47-75
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• 2011

An accurate substructural synthesis method including random responses synthesis, frequency-response functions synthesis and mid-order modes synthesis is developed based on rigorous substructure description, dynamic condensation and coupling. An entire structure can firstly be divided into several substructures according to different functions, geometric and dynamic characteristics. Substructural displacements are expressed exactly by retained mid-order fixed-interfacial normal modes and residual constraint modes. Substructural interfacial degree-of-freedoms are eliminated by interfacial displacements compatibility and forces equilibrium between adjacent substructures. Then substructural mode vibration equations are coupled to form an exact-condensed synthesized structure equation, from which structural mid-order modes are calculated accurately. Furthermore, substructural frequency-response function equations are coupled to yield an exact-condensed synthesized structure vibration equation in frequency domain, from which the generalized structural frequency-response functions are obtained. Substructural frequency-response functions are calculated separately by using the generalized frequency-response functions, which can be assembled into an entire-structural frequency-response function matrix. Substructural power spectral density functions are expressed by the exact-synthesized substructural frequency-response functions, and substructural random responses such as correlation functions and mean-square responses can be calculated separately. The accuracy and capacity of the proposed substructure synthesis method is verified by numerical examples.

• Bulletin of the Korean Chemical Society
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• 제14권5호
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• pp.546-548
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• 1993

The discrete structure of substituted 9-benzonorbornenyl cation 3a and 3c was studied using the empirical ${\Delta}$J equation which was developed by Kelly and coworker$^5$. The ${\Delta}$J values of substituted 9-benzonorbornenyl cations were obtained from p-methyl-6,7-dimethyl benzonorbornen-9-yl (3a) and 9-methyl-6,7-dimethyl benzonorbonen-9-yl (3c) cations under stable ion conditions, and were compared with those of the corresponding ketone analog; these cations were generated by dissolving the corresponding carbinols in superacid at -120$^{\circ}$C and the nmr spectra taken at -60$^{\circ}$C~-90$^{\circ}$C. The ${\Delta}$J values are 8.7 Hz for the bridgehead carbons in cation 3c and 3.1 Hz for cation 3b. The ${\Delta}$J values at C5,8 in fused benzene ring are 14.3 Hz for cation 3c and 8.7 Hz for cation 3a. The excellent correlation of the ${\Delta}$J values with 1$^9F$ chemical shifts of p-fluorophenyl-6,7-dimethylbenzonorbornenyl cation (3d) indicate that ${\Delta}$J value is a reliable probe to charge density at adjacent cationic carbon. These NMR parameters strongly support that the symmetrically ${\pi}$-bridged nonclassical structure (type 2) of substituted 9-benzonorbornenyl cations in stable ion conditions.

• 전력전자학회논문지
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• 제26권2호
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• pp.75-81
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• 2021

This study analyzes the resonance characteristics caused by the mutual interference between LCL filters and the grid impedance under the parallel operation of the grid-connected inverter using the LCL filter. These characteristics are verified through simulation and experiment. Two inverters are used to connect to the grid in parallel, and the system parameters, including the LCL filter, are set to the same conditions. In the case of inverters running in parallel at the point of common coupling, the presence of grid impedance causes mutual interference between the LCL filters of each inverter, and the deviation of the filter resonance frequency is analyzed to understand the parallel inverter. The correlation between the number of devices and the size of grid impedance is simulated by PSIM and verified by MATLAB. By connecting the real-time digital simulator Typhoon HILS to the DSP 28377 control board, the mutual interference characteristics are tested under the condition of two inverters running in parallel. The experimental and analysis results are the same, indicating the validity of the analysis.

• 한국지구과학회지
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• 제40권1호
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• pp.1-8
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• 2019

Although recent reports suggest that the negative correlation between the Arctic Oscillation (AO) and the East Asian winter monsoon (EAWM) has been strengthened, it is not clear whether this intermittent relationship is an intrinsic oscillation in the climate system. We investigate the oscillating behavior of the AO-EAWM relationship at decadal time scales using the long-term (500-yr) climate model simulation. The results show that ice cover over the East Siberian Seas is responsible for the change in the coupling strength between AO and EAWM. We found that increased ice cover over these seas strengthens the AO-EAWM linkage, subsequently enhancing cold advection over the East Asia due to anomalous northerly flow via a weakened jet stream. Thus, this strengthened relationship favors more frequent occurrences of cold surges in the EAWM region. Results also indicate that the oscillating relationship between AO and EAWM is a natural variability without anthropogenic drivers, which may help us understand the AO-EAWM linkage under climate change.

• Journal of Astronomy and Space Sciences
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• 제36권3호
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• pp.133-147
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• 2019

Challenging Minisatellite Payload (CHAMP) satellite magnetic data are used to investigate the latitudinal variation of the storm-time meso-scale field-aligned currents by defining a new metric called the FAC range. Three major geomagnetic storm events are considered. Alongside SymH, the possible contributions from solar wind dynamic pressure and interplanetary magnetic field (IMF) $B_Z$ are also investigated. The results show that the new metric predicts the latitudinal variation of FACs better than previous studies. As expected, the equatorward expansion and poleward retreat are observed during the storm main phase and recovery phase respectively. The equatorward shift is prominent on the northern duskside, at ${\sim}58^{\circ}$ coinciding with the minimum SymH and dayside at ${\sim}59^{\circ}$ compared to dawnside and nightside respectively. The latitudinal shift of FAC range is better correlated to IMF $B_Z$ in northern hemisphere dusk-dawn magnetic local time (MLT) sectors than in southern hemisphere. The FAC range latitudinal shifts responds better to dynamic pressure in the duskside northern hemisphere and dawnside southern hemisphere than in southern hemisphere dusk sector and northern hemisphere dawn sector respectively. FAC range exhibits a good correlation with dynamic pressure in the dayside (nightside) southern (northern) hemispheres depicting possible electrodynamic similarity at day-night MLT sectors in the opposite hemispheres.

• 한국수자원학회:학술대회논문집
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• 한국수자원학회 2022년도 학술발표회
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• pp.136-136
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• 2022

This study investigates the possibility of coupling empirical mode decomposition (EMD) for runoff prediction from machine learning (ML) models. Here, support vector regression (SVR) and convolutional neural network (CNN) were considered for ML algorithms. Precipitation (P), minimum temperature (Tmin), maximum temperature (Tmax) and their intrinsic mode functions (IMF) values were used for input variables at a monthly scale from Jan. 1973 to Dec. 2020 in the Grand river basin, Canada. The support vector machine-recursive feature elimination (SVM-RFE) technique was applied for finding the best combination of predictors among input variables. The results show that the proposed method outperformed the individual performance of SVR and CNN during the training and testing periods in the study area. According to the correlation coefficient (R), the EMD-SVR model outperformed the EMD-CNN model in both training and testing even though the CNN indicated a better performance than the SVR before using IMF values. The EMD-SVR model showed higher improvement in R value (38.7%) than that from the EMD-CNN model (7.1%). It should be noted that the coupled models of EMD-SVR and EMD-CNN represented much higher accuracy in runoff prediction with respect to the considered evaluation indicators, including root mean square error (RMSE) and R values.

• 한국자기학회지
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• 제26권2호
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• pp.39-44
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• 2016

대표적 열전물질인 비스무스 텔루라이드에 자성원자를 도핑한 합금에 대한 구조 및 전자적 그리고 자기적 성질에 관한 연구는 고효율 열전물질의 개발이라는 목적뿐만 아니라 특이한 자기적 상호작용 규명 및 위상절연체 분야에서도 큰 관심을 끌고 있다. 본 연구에서는 희토류 원자로서 매우 국소화된 f 전자를 갖는 Gd이 Bi을 치환하여 도핑된 비스무스 텔루라이드 합금의 자성 안정성을 밀도범함수(Density Functional Theory)에 입각하여 제일원리적으로 연구하기 위하여 모든 전자(all-electron) FLAPW(full-potential linearized augmented plane-wave) 방법을 이용하여 전자구조 계산을 수행하였다. 전자간 교환-상관 상호작용은 일반기울기 근사법(Generalized Gradient Approximation)을 도입하여 계산하였으며, 국소화된 f 전자를 기술하는 데 필요한 Hubbard+U 보정과 스핀-궤도 각운동량 상호작용은 제2 변분법적 방법을 이용하여 고려하였다. 계산 결과, 강자성 안정성을 보이는 Gd 덩치계와 다르게 이 합금은 강자성과 반강자성의 총에너지 차이가 ~1 meV/Gd 정도의 아주 작은 값으로 얻어져서, 그 자성 안정성은 결함이나 strain 등에 의한 구조변화에 민감하게 의존하여 변할 수 있음을 알 수 있었다. 특히 Gd 스핀자기모멘트는 덩치에서의 값에 비해 감소하였고, Gd에 가장 가까운 Te에 유도 자기모멘트가 형성되는 것으로 미루어 Te를 매개로 한 자성상호작용이 자성 안정성을 결정하는 데에 중요한 역할을 하는 것으로 예측할 수 있었다.