• Computers and Concrete
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• v.4 no.3
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• pp.221-241
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• 2007

Based on the experiment results, the damage and fracture behavior of concrete at the ages of 1d, 2d, 7d and 28d, in three-point bending and uniaxial tensile tests, were simulated with a finite element program, ABAQUS. The critical stress intensity factor $K_{IC}^s$ and the critical crack tip opening displacement ($CTOD_C$) of concrete were calculated with effective-elastic crack approach for the three-point bending test of grade C30 concrete. Based on the crack band model, a bilinear strain-softening curve was derived to simulate the LOAD-CMOD curves and LOAD-Displacement curves. In numerical analysis of the uniaxial tension test of concrete of grade C40, the damage and fracture mechanics were combined. The smeared cracking model coupling with damaged variable was adopted to evaluate the onset and development of microcracking of uniaxial tensile specimen. The uniaxial tension test was simulated by invoking the damage plastic model which took both damage and plasticity as inner variables with user subroutines. All the numerical simulated results show good agreement with the experimental results.

• Progress in Superconductivity
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• v.10 no.2
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• pp.74-78
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• 2009

Inter-grain nanobridges of the $MgB_2$ superconductor have been fabricated by focused-ion-beam(FIB) and their electrical transport properties were studied. The $MgB_2$ film was prepatterned into microbridges by a standard argon ion milling technique and then FIB-patterned into 100 nm$\times$100 nm bridges. Current-voltage characteristics showed a strong flux-flow type behavior at all temperatures with a trait of Josephson coupling near $T_c$. At low temperatures, the curves showed a two-step resistance-doubled transition with occasional hysteresis. The resistance-doubling transition is believed to be due to a two-channel flux-flow effect. The temperature-dependent critical current data showed $I_c(T){\propto}(1-T/T_c)^2$ near $T_c$, same as a normal barrier junction, and $I_c(T){\propto}(1-T/T_c)^{1.2}$ at low temperatures, similar to that of a film.

• Macromolecular Research
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• v.10 no.2
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• pp.85-90
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• 2002

Poly (ethylene oxide)/polylatide/poly(ethylene oxide) (PEO/PL/PEO) tri-block copolymers, which each block is connected by ester bond, were synthesized by coupling reaction of PL with PEO in the presence of pyridine. PL/PEO/PL tri-block copolymer was synthesized by ring opening polymerization of L-lactide initiated by PEO in the presence of stannous octoate. Degradation behavior of the copolymers was investigated in a pH 7.4 phosphate buffer saline (PBS) at 37$\pm$1 $^{\circ}C$. Gel permeation chromatography (GPC) and $^1$H-nuclear magnetic resonance (NMR) were used to monitor the change of mass loss, molecular weight and composition of copolymers. In hydrolytic degradation, the PEO/PL/PEO tri-block copolymer with high PEO contents affected the increase of its mass loss, and resulted in the decrease of its molecular weight as well as PEO composition. However, when PL/PEO/PL and PEO/PL/PEO tri-block copolymers had similar PEO contents, PEO/PL/PEO decreased faster in molecular weight and PEO composition than PL/PEO/PL.

• Macromolecular Research
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• v.15 no.4
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• pp.385-391
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• 2007

Block copolymer micelles are generally formed via the self-assembly of amphiphilic block copolymers in an aqueous medium. The hydrophilic and hydrophobic blocks form shell and core micelles, respectively. The block copolymers of methoxy poly(ethylene glycol) (MPEG)-b-poly(2-diisopropylamino)ethyl methacrylate (PDPA) were synthesized via atom transfer radical polymerization, with the macro initiator synthesized by the coupling of 2-bromoisobutyryl bromide with MPEG in the presence of a triethyl amine base catalyst. The atom transfer radical polymerization of 2-diisopropylamino)ethyl methacrylate was performed in conjunction with an N,N,N',N",N"-pentamethyl-diethylenetriamine/copper bromide catalyst system, in DMF, at $70^{\circ}C$. The pH induced micellization/demicellization was studied using fluorescence, with a pyrene probe. Furthermore, the pH dependent micellization was confirmed using the microviscosity method, with a dipyme fluorescence probe. The pH dependant micelle size distribution was studied using dynamic light scattering. The characterization of the synthesized polymers was established using gel permeation chromatography and from the $^1H-nuclear$ magnetic resonance spectroscopy.

• Bulletin of the Korean Chemical Society
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• v.28 no.7
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• pp.1175-1182
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• 2007

A series of new organic semiconductors hexyl end-capped thiophene-anthracene oligomers containing the anthracene moiety in the center of the oligomers are synthesized. The target oligomers have been obtained by Stille coupling reactions as key step reactions. The synthesized thiophene-anthracene oligomers were characterized by 1H-NMR, 13C-NMR and high-resolution mass spectroscopy, respectively. All of the oligomers are soluble in chlorinated solvents. Their optical, thermal and electrochemical properties were measured. The hexyl end-capped oligomers and their unsubstituted oligomers exhibit the same absorption behavior in dilute toluene solution. Hexyl end-capped bis-terthienylanthracene oligomer is observed to show liquid crystalline mesophase at 166 oC in heating process. The thermal analyses as well as the electrochemical measurement data indicate that the designed materials show better thermal and oxidation stability than the corresponding oligothiophenes without anthracene core. Fluorescence lifetimes and fluorescence quantum yields of the thiophene-anthracene oligomers are measured to be 10-14 ps and 3.4-9.9 × 10?3 which are much shorter and lower than those of oligothiophenes respectively.

• Wind and Structures
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• v.23 no.4
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• pp.301-311
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• 2016

The numerous benefits of Savonius turbine such as simple in structure, has appropriate self-start ability, relatively low operating velocity, water acceptance from any direction and low environmental impact have generated interests among researchers. However, it suffers from a lower efficiency compared to other types of water turbine. To improve its performance, parameters such flow pattern, pressure and velocity in different conditions must be analyzed. For this purpose, a detailed description on the flow field of various types of Savonius rotors is required. This article presents a numerical study on a nonlinear two-dimensional flow over a classic Savonius type rotor and a Benesh type rotor. In this experiment, sliding mesh was used for solving the motion of the bucket. The unsteady Reynolds averaged Navier-Stokes equations were solved for velocity and pressure coupling by using the SIMPLE (Semi-Implicit Method for Pressure linked Equations) algorithm. Other than that, the turbulence model using $k-{\varepsilon}$ standard obtained good results. This simulation demonstrated the method of the flow field characteristics, the behavior of velocity vectors and pressure distribution contours in and around the areas of the bucket.

• Proceedings of the Korean Geotechical Society Conference
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• 2008.03a
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• pp.676-679
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• 2008

Numerical simulations of fluid injection into particulate materials were conducted to observe cavity initiation and propagation using distinct element method. After generation of initial particles and wall elements, confining stress was applied by servo-control method. The fluid scheme solves the continuity and Navior-Stokes equations numerically, then derives pressure and velocity vectors for fixed grid by considering the existence of particles within the fluid cell. Fluid was injected as 7-step into the assembly in the x-direction from the inlet located at the center of the left boundary under confining stress condition, 0.1MPa and 0.5MPa, respectively. For each simulation, movement of particles, flow rate, fluid velocity, pressure history, wall stress including cavity initiation and propagation by interaction of flulid-paricles were analyzed.

• Journal of the Institute of Electronics Engineers of Korea TC
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• v.41 no.10
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• pp.103-108
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• 2004

In this paper, a compact patch antenna with four T-slits fed by crossed aperture coupling is proposed for miniaturized Portable GPS handsets. The mechanism for compact size antenna is investigated with the behavior of the currents on the radiating patch. The equivalent surface current path due to the slits is lengthened, reducing the resonant frequency at a fixed patch size. The results of embedded T-slits for compact antenna size show that the resonant frequency is significantly lowered from 2.545GHz to 1.575GHz, corresponding to a 44.65% antenna size reduction compared to reference design. Experimental results show that good CP radiation patterns are obtained and impedance bandwidth (VSWR $\leq$ 2), 3dB axial ratio are about 21MHz, 19MHz at the center resonant frequency, respectively.

• Proceedings of the Korean Geotechical Society Conference
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• 1987.06a
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• pp.51-80
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• 1987

In this studys a numerical analysis on the defomation of foundation layer was carried out by indroducing joint element. The method using the joust element between adj assent different materials has been originally developed for rock behavior(Goodman, et al. 1968) . The application of this method to the interface between the footing and soil layer proved satisfactory(Ghaboussi p et at. 1973). Authors tried to obtain the deformation of rrcompound foundation layerg", which vertically or horizontally or both consists of the natural(or intact) soft clay layer and the layer improved artificially in order to get high stiff-fness with replacement or chemical treatment to reduce the excessively detrimental settlemellt or lateral displacement in case of banking or building the civil structure on the soft layer. The joint conditions were classified into three categories : contacts sliding and separation. By coupling "JOINT" as a subroutine into multi-purpose code for the finite element method of the foundatlion daveloped by authors on the assumption that shearing and normal displacement can not be coupledl which terms pinon-dilatant" and by selecting modified Cam-clay modeIP the deformation analysis was performmed. The results using joint element were compared with those secured without introduction of joint element Nain results analized are as follows : 1. For the prediction of settlement and lateral desplacement, the result due to joint element was evaluated larger, which was regarded safe. 2. For the determination of ultimate bearing capacetyi the value using joint element appeared smaller by 20%, which was also safe.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2008.11a
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• pp.231-232
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• 2008

The coupling between electric, magnetic, and structural order parameters results in the so-called multiferroics, which possess ferroelectricity, ferromagnetism, and/or ferroelasticity. The simultaneous ferroelectricity and ferromagnetism (magnetoelectricity) allow potential applications in information storage, spintronics, and in magnetic or electric field sensors. Perovskite compound $BiFeO_3$ (BFO) is antiferromagnetic below Neel temperature of 647K and ferroelectric with a high Curie temperature of 1043K. It exhibits weak magnetism at room temperature(RT) due to the residual moment from a canted spin structure. It is likely that non-stoichiometry and second-phase formation are the factors which cause leakage in BFO. It has been suggested that oxygen non-stoichiometry leads to valence fluctuations of Fe ions in BFO, resulting in high conductivity. To reduce the large leakage current of BFO, one attempt is fabricating donor doped BFO compounds and thin films. We report here the successful fabrication of the Nd, Ti co-doped $BiFeO_3$ ceramics and thin films by pulsed laser deposition technique.