• Title/Summary/Keyword: coupled properties

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Synthesis of Silver Nanoparticles from the Decomposition of Silver(I) [bis(alkylthio)methylene]malonate Complexes

  • Lee, Euy-Jin;Piao, Longhai;Kim, Jin-Kwon
    • Bulletin of the Korean Chemical Society
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    • v.33 no.1
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    • pp.60-64
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    • 2012
  • Silver(I) [bis(alkylthio)methylene]malonates were synthesized from the reaction of silver nitrate and potassium [bis(alkylthio)methylene]malonates. The structures of the Ag complexes were characterized with nuclear magnetic resonance (NMR), inductively coupled plasma atomic emission spectrometry (ICP-AES) and elemental analysis. Ag nanoparticles (NPs) were obtained from the decomposition of the Ag complexes in 1,2-dichlorobenzene at $110^{\circ}C$ without an additional surfactant. The average sizes of the Ag NPs are in the range of 5.1-6.3 nm and could be controlled by varying the length of the alkyl chain. The optical properties, crystalline structure and surface composition of Ag NPs were characterized with ultraviolet-visible (UV-visible) spectroscopy, transmission electron microscopy (TEM), X-ray diffraction (XRD), gas chromatography-mass spectrometry (GC-MS), X-ray Photoelectron Spectroscopy (XPS) and thermal gravimetric analysis (TGA).

Finite Element Analysis of the Behavior of Early-age Concrete (유한요소법에 의한 초기재령 콘크리트의 거동해석)

  • 송하원;조호진;박상순;변근주
    • Proceedings of the Computational Structural Engineering Institute Conference
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    • 2001.04a
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    • pp.10-17
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    • 2001
  • With the introduction of durability examination into design code of concrete structure, a prediction of early-age behavior of concrete and its cracking resistance becomes very important. But, the early-age behaviors such as hydration, micro-structure development, moisture transport and mechanical properties development is quite complicated and coupled each other, and thus those can not be solved independently. One way to analyze those is to model their behaviors analytically and solve those computationally within a unified framework. In this paper, we propose a finite element technique to predict the early-age behaviors of concrete within the unified framework. The technique is applied to evaluatio of cracking in a massive concrete structure and then the analysis results are discussed.

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Free Vibration of Primary-Secondary Structures with Multiple Connections (다중 지지된 주-부 구조물의 자유 진동)

  • 민경원
    • Computational Structural Engineering
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    • v.4 no.4
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    • pp.97-106
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    • 1991
  • The frequency window method has been extended to include strong coupling and multiple connections between the primary structure and the secondary structures. The rational polynomial expansion of the eigenvalue problem and the analytical methods for its solution are novel and distinguish this work from other eigenvalue analysis methods. The key results are the identification of parameters which quantify the resonance and coupling characteristics; the derivation of analytical closed-form expressions describing the fundamental modal properties in the frequency windows; and the development of an iterative procedure which yields accurate convergent results for strongly-coupled primary-secondary structures.

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The Applicability of Numerical Analysis Technique to The Soft Clayey Foundation Improved by Sand Drain (Sand Drain 지반에 대한 변형해석법의 적용성)

  • Lee, Jean-Soo;Lee, Moon-Soo;Jang, Chul
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.40 no.1
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    • pp.96-105
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    • 1998
  • Soil properties, drain conditions and numerical analysis technique have great influence upon consolidation behavior. In relevant to the above described fact, this paper aims to examining the applicability of prediction model of consolidation as well as deformation characteristics for soft clayey foundation improved by sand drain. A case study for actual foundation of Kwangyang steel works was performed. Single drain consolidation model proposed by Hansbo and Biot's consolidation theory coupled with modified Cam-clay model developed during the research were employed for the FEM numerical analysis of the foundation. Both smear effect and drain capacity were taken into account for the analysis. Finally the applicability of the newly developed technique to the behavior of foundation composed of soft clay proved satisfactory.

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Synthesis and Characterization of Al2O3/ZrO2, Al2O3/TiO2 and Al2O3/ZrO2/TiO2 Ceramic Composite Particles Prepared by Ultrasonic Spray Pyrolysis

  • Shim, In-Soo;Lee, Chang-Seop
    • Bulletin of the Korean Chemical Society
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    • v.23 no.8
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    • pp.1127-1134
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    • 2002
  • Fine ceramic particles of zirconia toughened alumina (ZTA), titania toughened alumina (TTA), and zirconia-titania toughened alumina (ZTTA) have been synthesized by ultrasonic spray pyrolysis (USP) at various temperatures from starting salt solutio ns of various compositions aiming for the development of catalytic material. These particles were characterized for properties such as shape, size and size distribution, diffraction pattern, and chemical and phase composition of elements by scanning electron microscopy (SEM), particle size analyzer (PSA), x-ray diffraction (XRD), and inductively coupled plasma-atomic emission spectroscopy (ICP-AES). Chemical compositions and sizes of ceramic composites have been controled by the stoichiometry of salt solutions and the flow rate of spraying solutions. The optimum experimental conditions for the various composite particle syntheses have been proposed.

Temperature Characteristic Analysis according to Variation of Properties of Transformer Insulating Oil (변압기 절연유의 물성치 변화에 따른 온도특성해석)

  • Kim, Ji-Ho;Rhee, Wook
    • The Transactions of the Korean Institute of Electrical Engineers P
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    • v.63 no.4
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    • pp.327-332
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    • 2014
  • In this paper, the temperature distribution according to the property change of the insulating oil of the power transformer and max temperature were predicted through the ductility interpretation which heat-flow is coupled. By using CFD (Computation Fluid Dynamics) for the interpretation, the temperature distribution of 154kV the class single phase power transformer was predicted. The power loss causing the temperature rise of the transformer was changed to the heat source and we used as the input value for the heat-flow analysis. The temperature distribution was predicted according to the change of the density, specific heat, thermal conductivity and viscosity, that is the ingredient having an effect on the temperature rise of the transformer oil. The mineral oil of 4 kinds used in domestic and international based on the interpreted result was selected and the temperature distribution according to each load and Hot Spot temperature was predicted.

Characteristics of Line-type Internal Inductively Coupled Plasma Source for Flexible Display Processing

  • Lim, Jong-Hyeuk;Kim, Kyong-Nam;Gweon, Gwang-Ho;Hong, Seung-Pyo;Yeom, Geun-Young
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.1490-1493
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    • 2009
  • In this work we present a new type of line plasma source using an internal-type ICP operated at 2MHz with a ferrite module, describe the effect of ferrite module on the enhancement of the plasma properties and the uniformity, and compare to those obtained with 13.56MHz discharge. Also the electrical characteristics of the antenna line and the characteristics of the plasma uniformity were studied.

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Nonlinear analysis of reinforced concrete frame under lateral load

  • Salihovic, Amir;Ademovic, Naida
    • Coupled systems mechanics
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    • v.6 no.4
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    • pp.523-537
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    • 2017
  • This study aims to investigate the capacity of different models to reproduce the nonlinear behavior of reinforced concrete framed structures. To accomplish this goal, a combined experimental and analytical research program was carried out on a large scaled reinforced concrete frame. Analyses were performed by SAP2000 and compared to experimental and VecTor2 results. Models made in SAP2000 differ in the simulation of the plasticity and the type of the frame elements used to discretize the frame structure. The results obtained allow a better understanding of the characteristics of all numerical models, helping the users to choose the best approach to perform nonlinear analysis.

Mathematical modeling of smart nanoparticles-reinforced concrete foundations: Vibration analysis

  • Kargar, Masood;Bidgoli, Mahmood Rabani
    • Steel and Composite Structures
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    • v.27 no.4
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    • pp.465-477
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    • 2018
  • In this research, vibration and smart control analysis of a concrete foundation reinforced by $SiO_2$ nanoparticles and covered by piezoelectric layer on soil medium is investigated. The soil medium is simulated with spring constants and the Mori-Tanaka low is used for obtaining the material properties of nano-composite structure and considering agglomeration effects. With considering first order shear deformation theory, the total potential energy of system is calculated and by means of Hamilton's principle in three displacement directions and electric potential, the six coupled equilibrium equations are obtained. Also, based an analytical method, the frequency of system is calculated. The effects of applied voltage, volume percent and agglomeration of $SiO_2$ nanoparticles, soil medium and geometrical parameters of structure are shown on the frequency of system. Results show that with applying negative voltage, the frequency of structure is increased.

Vibration analysis of FGM beam: Effect of the micromechanical models

  • Hadji, Lazreg
    • Coupled systems mechanics
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    • v.9 no.3
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    • pp.265-280
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    • 2020
  • In this paper, a new refined hyperbolic shear deformation beam theory for the free vibration analysis of functionally graded beam is presented. The theory accounts for hyperbolic distribution of the transverse shear strains and satisfies the zero traction boundary conditions on the surfaces of the functionally graded beam without using shear correction factors. In addition, the effect of different micromechanical models on the free vibration response of these beams is studied. Various micromechanical models are used to evaluate the mechanical characteristics of the FG beams whose properties vary continuously across the thickness according to a simple power law. Based on the present theory, the equations of motion are derived from the Hamilton's principle. Navier type solution method was used to obtain frequencies, and the numerical results are compared with those available in the literature. A detailed parametric study is presented to show the effect of different micromechanical models on the free vibration response of a simply supported FG beams.