• Title/Summary/Keyword: corrosion-resistance

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Change of Compressive Deformation Behaviors of Ti-5Mo-xFe Metastable Beta Alloy According to Fe Contents (Fe 함량에 따른 Ti-5Mo-xFe 준안정 베타 합금의 압축 변형거동 변화)

  • Yong-Jae Lee;Jae Gwan Lee;Dong-Geun Lee
    • Journal of the Korean Society for Heat Treatment
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    • v.36 no.5
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    • pp.303-310
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    • 2023
  • β titanium alloys are widely used in aerospace industry due to their excellent specific strength and corrosion resistance. In particular, mechanical properties of metastable β titanium can efficiently be controlled by various deformation mechanisms such as slip, twinning, and SIM (Stress-Induced Martensite Transformation), making it an ideal material for many industrial applications. In this study, Ti-5Mo-xFe (x=1, 2, 4 wt%) alloy was designed by adding a relatively inexpensive β element to ensure price competitiveness. Additionally, microstructural analysis was conducted using OM, SEM, and XRD, while mechanical properties were evaluated through hardness and compression tests to consider the deformation mechanisms based on the Fe content. SIMT occurred in all three alloys and was influenced by the presence of βm (metastable beta) and beta stability. As the Fe content decreased, the α'' phase increased due to SIMT occurring within the βm phase, resulting in softening. Conversely, as the Fe content increased, the strength of the alloy increased due to a reduction in α'' formation and the contributions of solid solution strengthening and grain strengthening. Moreover, unlike the other alloys, shear bands were observed only in the fracture of the Ti-5Mo-4Fe alloy, which was attributed to differences in texture and microstructure.

THE MAGNETIC PROPERTIES OF Co-Ni-Fe-N SOFT MAGNETIC THIN FILMS

  • Kim, Y. M.;Park, D.;Kim, K. H.;Kim, J.;S. H. Han;Kim, H. J.
    • Proceedings of the Korean Magnestics Society Conference
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    • 2000.09a
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    • pp.492-499
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    • 2000
  • Co-Ni-Fe-N thin films were fabricated by a N$\sub$2/ reactive rf magnetron sputtering method. The nitrogen partial pressure (P$\sub$N2/) was varied in the range of 0∼10%. As P$\sub$N2/ increases in this range, the saturation magnetization (B$\sub$s/) linearly decreases from 19.8 kG to 14 kG and the electrical resistivity ($\rho$) increased from 27 to 155 ${\mu}$$\Omega$cm. The coercivity (H$\sub$c/) exhibits the minimum value at 4% of P$\sub$N2/. The magnetic anisotropy (H$\sub$k/) are in the range of 20∼50 Oe. High frequency characteristics of (Co$\sub$22.2/Ni$\sub$27.6/Fe$\sub$50.2/)$\sub$100-x/N$\sub$x/ films are excellent in the range of 3∼5% of P$\sub$N2/. Especially the effective permeability of the film fabricated at 4% of P$\sub$N2/ is 800, which is maintained up to 600 MHz. This film also shows Bs of 17.5 kG, H$\sub$c/ of 1.4 Oe, resistivity of 98 $\Omega$cm and H$\sub$k/ of about 25 Oe. Also, the corrosion resistance of (Co$\sub$22.2/Ni$\sub$27.6/Fe$\sub$50.2/)$\sub$100-x/N$\sub$x/ were improved with the increase in N concentration.

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An Experimental Study on the Mechanical Properties of High Modulus Carbon-Epoxy Composite in Salt Water Environment (염수 환경에 노출된 고강성 탄소/에폭시 복합재의 물성치 변화 연구)

  • Moon, Chul-Jin;Lee, Cheong-Lak;Kweon, Jin-Hwe;Choi, Jin-Ho;Jo, Maeng-Hyo;Kim, Tae-Gyeong
    • Composites Research
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    • v.21 no.6
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    • pp.1-7
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    • 2008
  • The main objective of this study is to investigate the effect of salt water on the mechanical properties of a high modulus carbon-epoxy composite. Specimens were made of a carbon-epoxy composite UPN139B of SK Chemical and tested under inplane tension and shear after 0, 1, 3, 6, 9, and 12 months immersion in 3.5% salt water. Acceleration technique such as temperature elevation was not used. The tensile strengths and modulli in fiber and matrix direction did not show any remarkable degradation until 12 months immersion. In contrast to the tensile properties, shear strength and modulus started to gradually decrease up to about 10% of values of dry specimens after 12 months immersion. It was confirmed through the test that the material UPN139B can be an effective material for the shell structures in salt water to resist against the external pressure buckling because of the high fiber directional modulus and corrosion resistance.

Characteristics of Structural Behavior and Safety Estimation of Water Supply GFRP Pipe (상수도용 유리섬유복합관의 구조적 거동특성 및 안전성 평가)

  • Lee, Bo-Be;Lee, Seung-Sik;Joo, Hyung-Jong;Yoon, Soon-Jng
    • Composites Research
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    • v.22 no.3
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    • pp.1-8
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    • 2009
  • In this paper, we present the results of experimental and analytical investigations on the structural behavior of GFRP pipes used in the water supply pipeline system. Cross-section of the pipe is consisted with two GFRP tubes and polymer mortar between the tubes. Due to the advantages such as light-weight, corrosion resistance, smooth surface, flexibility, etc., use of GFRP pipe in the water supply pipeline system is ever increasing trend. Therefore, more optimized structural design methodology should be developed. In the investigation, we conducted theoretical and analytical studies on the load versus radial deformation characteristics of GFRP pipes. In addition, ring stiffness test is also performed. Test results are compared with theoretical and analytical results and it was found that the results are agreed well within 5% of radial deformation. Finally, it was also found that the GFRP pipes used in the water supply pipeline system are strong enough to satisfy the industrial requirements.

Compressive behavior of concrete-filled square stainless steel tube stub columns

  • Dai, Peng;Yang, Lu;Wang, Jie;Ning, Keyang;Gang, Yi
    • Steel and Composite Structures
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    • v.42 no.1
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    • pp.91-106
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    • 2022
  • Concrete-filled square stainless steel tubes (CFSSST), which possess relatively large flexural stiffness, high corrosion resistance and require simple joint configurations and low maintenance cost, have a great potential in constructional applications. Despite that the use of stainless steel may result in high initial cost compared to their conventional carbon steel counterparts, the whole-life cost of CFSSST is however considered to be lower, which offers a competitive choice in engineering practice. In this paper, a comprehensive experimental and numerical program on 24 CFSSST stub column specimens, including 3 austenitic and 3 duplex stainless steel square hollow section (SHS) stub columns and 9 austenitic and 9 duplex CFSSST stub columns, has been carried out. Finite element (FE) models were developed to be used in parametric analysis to investigate the influence of the tube thickness and concrete strength on the ultimate capacities more accurately. Comparisons of the experimental and numerical results with the predictions made by design guides ACI 318, ANSI/AISC 360, Eurocode 4 and GB 50936 have been performed. It was found that these design methods generally give conservative predictions to the ultimate capacities of CFSSST stub columns. Improved calculation methods, developed based on the Continuous Strength Method, have been proposed to provide more accurate estimations of the ultimate resistances of CFSSST stub columns. The suitability of these proposals has been validated by comparison with the test results, where a good agreement between the predictions and the test results have been achieved.

Mechanical Properties of 3D Printed Composite Material on Various Thermal Environment (다양한 온도 환경에 따른 3D 프린트 복합재료의 기계적 물성 평가)

  • Sang-Hun Kang;Do-Hyeon Kim;Hyoung-Seock Seo
    • Composites Research
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    • v.36 no.3
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    • pp.193-198
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    • 2023
  • Currently, there are many discussions about composite materials and 3D printed composite material to weight reduction of ships. A test was conducted to confirm the applicability of the 3D printed composite material to ships and offshore structures by linking the 3D printing technology with excellent productivity and the composite material with corrosion resistance and lightweight characteristics in salt water environments. In order to apply the 3D printed composite material used in this paper to ships and offshore structures, the temperature environmental effects that can be exposed in the marine environment should be considered. Therefore, the tensile test was conducted with specimen of Carbon + Onyx, Carbon + Nylon, HSHT glass + Onyx, HSHT glass + Nylon material in low temperature (-50℃), room temperature (20℃), and high temperature (50℃) environments that can be exposed to the marine environment. As a result of the tensile test, the carbon + onyx specimen showed the highest tensile strength and the HSHT glass + onyx specimen showed the highest tensile strain. In addition, by analyzing the tested specimens, the failure mode of the 3D printed composite material specimens exposed to various temperature environments was analyzed.

Development of Estimated Model for Axial Displacement of Hybrid FRP Rod using Strain (Hybrid FRP Rod의 변형률을 이용한 축방향 변위추정 모형 개발)

  • Kwak, Kae-Hwan;Sung, Bai-Kyung;Jang, Hwa-Sup
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.26 no.4A
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    • pp.639-645
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    • 2006
  • FRP (Fiber Reinforced Polymer) is an excellent new constructional material in resistibility to corrosion, high intensity, resistibility to fatigue, and plasticity. FBG (Fiber Bragg Grating) sensor is widely used at present as a smart sensor due to lots of advantages such as electric resistance, small-sized material, and high durability. However, with insufficiency of measuring displacement, FBG sensor is used only as a sensor measuring physical properties like strain or temperature. In this study, FRP and FBG sensors are to be hybridized, which could lead to the development of a smart FRP rod. Moreover, developing the estimated model for deflection with neural network method, with the data measured through FBG sensor, could make conquest of a disadvantage of FBG sensor - uniquely used for sensing strain. Artificial neural network is MLP (Multi-layer perceptron), trained within error rate of 0.001. Nonlinear object function and back-propagation algorithm is applied to training and this model is verified with the measured axial displacement through UTM and the estimated numerical values.

Analysis of Activation Energy of Thermal Aging Embrittlement in Cast Austenite Stainless Steels (주조 오스테나이트 스테인리스강의 열취화 활성화에너지 분석)

  • Gyeong-Geun Lee;Suk-Min Hong;Ji-Su Kim;Dong-Hyun Ahn;Jong-Min Kim
    • Transactions of the Korean Society of Pressure Vessels and Piping
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    • v.20 no.1
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    • pp.56-65
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    • 2024
  • Cast austenitic stainless steels (CASS) and austenitic stainless steel weldments with a ferrite-austenite duplex structure are widely used in nuclear power plants, incorporating ferrite phase to enhance strength, stress relief, and corrosion resistance. Thermal aging at 290-325℃ can induce embrittlement, primarily due to spinodal decomposition and G-phase precipitation in the ferrite phase. This study evaluates the effects of thermal aging by collecting and analyzing various mechanical properties, such as Charpy impact energy, ferrite microhardness, and tensile strength, from various literature sources. Different model expressions, including hyperbolic tangent and phase transformation equations, are applied to calculate activation energy (Q) of room-temperature impact energies, and the results are compared. Additionally, predictive models for Q based on material composition are evaluated, and the potential of machine learning techniques for improving prediction accuracy is explored. The study also examines the use of ferrite microhardness and tensile strength in calculating Q and assessing thermal embrittlement. The findings provide insights for developing advanced prediction models for the thermal embrittlement behavior of CASS and the weldments of austenitic steels, contributing to the safety and reliability of nuclear power plant components.

Evaluation of Basic Beneficiation Characteristics for Optimizing Molybdenum Ore Flotation Process (몰리브덴광 부유선별 공정 최적화를 위한 기초 선광 특성 평가)

  • Seongsoo Han;Joobeom Seo
    • Resources Recycling
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    • v.33 no.2
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    • pp.37-45
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    • 2024
  • Molybdenum is used in various industries because of its high heat and corrosion resistance. It was selected as a critical mineral in Korea. However, there have been recent challenges in production because of the increased depth and decreased grade of molybdenum veins. Consequently, it is necessary to enhance the effectiveness of the molybdenum beneficiation process. In this study, a basic evaluation of beneficiation characteristics was conducted to enhance the effectiveness of the domestic molybdenum ore beneficiation process. The properties of the beneficiation process were assessed using mineralogical analysis, work index, and flotation kinetics. The results revealed that the allowable particle size of the molybdenum ore for liberation was ~100 ㎛. In addition, the work index was calculated to be 14.57 kWh/t. The operating conditions in the flotation units were achieved by determining the optimal flotation time for each process based on flotation kinetics. Finally, the characteristics of molybdenum ore beneficiation provided in this study can be utilized to diagnose the grinding and flotation processes of large-scale molybdenum beneficiation plants.

Impact Tensile Properties and Intergranular Fracture Behavior with Strain Rate Variations of Al-M g-X (X = Cr,Si) Alloy

  • Chang-Suk Han;Min-Gyu Chun;Sung-Soon Park;Seung-In Lim
    • Korean Journal of Materials Research
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    • v.34 no.7
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    • pp.330-340
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    • 2024
  • Al-Mg-Si alloys are light weight and have excellent corrosion resistance, and are attracting attention as a liner material for high-pressure hydrogen containers in hydrogen fuel cell vehicles. Because it has excellent plastic hardening properties, it is also applied to car body panel materials, but it is moderate in strength, so research to improve the strength by adding Si-rich or Cu is in progress. So far, the authors have conducted research on the intergranular fracture of alloys with excessive Si addition from the macroscopic mechanical point of view, such as specimen shape. To evaluate their impact tensile properties, the split-Hopkinson bar impact test was performed using thin plate specimens of coarse and fine grain alloys of Al-Mg-X (X = Cr,Si) alloy. The effect of the shape of the specimen on the characteristics was studied through finite element method (FEM) analysis. As a result, it was found that the intergranular fracture of the alloy with excessive Si depended on the specimen width (W)/grain size (d), which can be expressed by the specimen size and grain size. As W/d decreases, the intergranular fracture transforms into a transgranular fracture. As the strain rate increases, the fracture elongation decreases, and the fracture surface of the intergranular fracture becomes more brittle. It was confirmed that intergranular fracture occurred in the high strain rate region even in materials with small grain sizes.