• Title/Summary/Keyword: corrosion-grade

Search Result 89, Processing Time 0.024 seconds

Properties of Castable REfractories Containing Metallic Al Powder (금속 Al분말 첨가 Castable 내화물의 특성)

  • 김효준;김인술;이상완
    • Journal of the Korean Ceramic Society
    • /
    • v.27 no.7
    • /
    • pp.877-882
    • /
    • 1990
  • Effects of metallic Al powder addition on basic and thermal properties of castable refractories were investigated. Generally, low grade prooperties were obtained by metallic Al powder addition with the increase of temperature, comparing with those of non-addition of Al powder. Especially, Al addtion showed severe shrinkage, corrosiion and low strength above 1000$^{\circ}C$. As a result of Al addition, lower strength of and higher corrosion resistance were shown for 2% addition, but it was reversed for above 4% addition. It was found that Al addition was excellent in the explosive spalling test regardless of Al quantity.

  • PDF

Determination of electrical and geometric properties of brown eggs

  • Sung Yong Joe;Jun Hwi So;Seon Ho Hwang;Soon Jung Hong;Seung Hyun Lee
    • Korean Journal of Agricultural Science
    • /
    • v.49 no.4
    • /
    • pp.909-921
    • /
    • 2022
  • Eggs are considered an excellent complete food because they contain many major energy sources, including protein. Eggs are one of the most widely consumed foods worldwide, and egg consumption is steadily increasing. Eggs are generally classified according to their quality and weight. Various characteristics of eggs must be considered for the design and effective utilization of equipment used for the transport, processing, packaging, and storage of eggs. In this study, egg surface area, volume, density, etc. were measured according to the grade of the egg. The values of several geometrical properties that were measured tended to increase with increasing egg grade. The smallest grade eggs had the lowest shell thickness and density. The electrical conductivity of the eggshell and its contents was measured with a self-made electrode and equipment. The egg shell showed properties similar to insulators, and as the thickness increased, the electrical conductivity tended to increase. The electrical conductivity of the egg yolk showed almost constant values under all conditions. The electrical conductivity of the egg white and mixture was particularly low at 0.1 kHz. Fouling and electrode corrosion occurred in a low frequency region due to the egg white. In this study, various geometric and electrical characteristics of eggs were measured, and based on this, factors that could serve as new indicators for egg processed production were analyzed and investigated.

A Study of Acid Leaching for Metallurgical Grade Silicon Manufacturing Improved Purity (순도가 향상된 금속급 실리콘 제조를 위한 산침출 연구)

  • Um, Myeong-Heon;Ha, Beom-Yong
    • Journal of the Korea Academia-Industrial cooperation Society
    • /
    • v.18 no.11
    • /
    • pp.118-123
    • /
    • 2017
  • To manufacture MG-Si (Metallurgical grade silicon) for use in various industries, Acid leaching experiments were performed to remove aluminum (Al) and iron (Fe), which are the most common impurities found in the silicon raw material. The silicon raw material was reacted with five types of acids (HCl, HF, H2SO4, HNO3, H3PO4) at 1, 2, 4, and 6M; 1M HF showed the highest Al and Fe removal rates, 97.9% and 95.2%, respectively. HF, however, resulted in an 18% reduced yield due to the silicon corrosion properties. To minimize the yield reduction, 2M HCl, which has a second removal ratio result, was mixed with 1M HF and applied to the silicon raw material. The experiment was conducted to select the optimal conditions for the mixed solution, which were $80^{\circ}C$ and 2hr. Under the optimal conditions, the residual Al and Fe concentrations were 141 ppmw and 93 ppmw, respectively, and it very easy to produce MG-Si with 3N grade purity.

Fuzzy Inference Based Design for Durability of Reinforced Concrete Structure in Chloride-Induced Corrosion Environment

  • Do Jeong-Yun;Song Hun;Soh Yang-Seob
    • Journal of the Korea Concrete Institute
    • /
    • v.17 no.1 s.85
    • /
    • pp.157-166
    • /
    • 2005
  • This article involves architecting prototype-fuzzy expert system for designing the nominal cover thickness by means of fuzzy inference for quantitatively representing the environment affecting factor to reinforced concrete in chloride-induced corrosion environment. In this work, nominal cover thickness to reinforcement in concrete was determined by the sum of minimum cover thickness and tolerance to that defined from skill level, constructability and the significance of member. Several variables defining the quality of concrete and environment affecting factor (EAF) including relative humidity, temperature, cyclic wet and dry, and the distance from coast were treated as fuzzy variables. To qualify EAF the environment conditions of cycle degree of wet-dry, relative humidity, distance from coast and temperature were used as input variables. To determine the nominal cover thickness a qualified EAF, concrete grade, and water-cement ratio were used. The membership functions of each fuzzy variable were generated from the engineering knowledge and intuition based on some references as well as some international codes of practice.

Characteristics in Paintability of Advanced High Strength Steels

  • Park, Ha Sun
    • Corrosion Science and Technology
    • /
    • v.6 no.3
    • /
    • pp.83-89
    • /
    • 2007
  • It is expected that advanced high strength steels (AHSS) would be widely used for vehicles with better performance in automotive industries. One of distinctive features of AHSS is the high value of carbon equivalent (Ceq), which results in the different properties in formability, weldability and paintability from those of common grade of steel sheets. There is an exponential relation between Ceq and electric resistance, which seems also to have correlation with the thickness of electric deposition (ED) coat. Higher value of Ceq of AHSS lower the thickness of ED coat of AHSS. Some elements of AHSS such as silicon, if it is concentrated on the surface, affect negatively the formation of phosphates. In this case, silicon itself doesn't affect the phosphate, but its oxide does. This phenomenon is shown dramatically in the welding area. Arc welding or laser welding melts the base material. In the process of cooling of AHSS melt, the oxides of Si and Mn are easily concentrated on the surface of boundary between welded and non‐welded area because Si and Mn could be oxidized easier than Fe. More oxide on surface results in poor phosphating and ED coating. This is more distinctive in AHSS than in mild steel. General results on paintability of AHSS would be reported, being compared to those of mild steel.

Numerical study of ITZ contribution on diffusion of chloride and induced rebar corrosion: A discussion of three-dimensional multiscale approach

  • Tu, Xi;Pang, Cunjun;Zhou, Xuhong;Chen, Airong
    • Computers and Concrete
    • /
    • v.23 no.1
    • /
    • pp.69-80
    • /
    • 2019
  • Modeling approach for mesoscopic model of concrete depicting mass transportation and physicochemical reaction is important since there is growing demand for accuracy and computational efficiency of numerical simulation. Mesoscopic numerical simulation considering binder, aggregate and Interfacial Transition Zone (ITZ) generally produces huge number of DOFs, which is inapplicable for full structure. In this paper, a three-dimensional multiscale approach describing three-phase structure of concrete was discussed numerically. An effective approach generating random aggregate in polygon based on checking centroid distance was introduced. Moreover, ITZ elements were built by parallel expanding the surface of aggregates on inner side. By combining mesoscopic model including full-graded aggregate and macroscopic model, cases related to diffusivity and thickness of ITZ, volume fraction and grade of aggregate were studied regarding the consideration of multiscale compensation. Results clearly showed that larger analysis model in multiscale model expanded the diffusion space of chloride ion and decreased chloride content in front of rebar. Finally, this paper addressed some worth-noting conclusions about the chloride distribution and rebar corrosion regarding the configuration of, rebar diameter, concrete cover and exposure period.

How Through-Process Optimization (TPO) Assists to Meet Product Quality

  • Klaus Jax;Yuyou Zhai;Wolfgang Oberaigner
    • Corrosion Science and Technology
    • /
    • v.23 no.2
    • /
    • pp.131-138
    • /
    • 2024
  • This paper introduces Primetals Technologies' Through-Process Optimization (TPO) Services and Through-Process Quality Control (TPQC) System, which integrate domain knowledge, software, and automation expertise to assist steel producers in achieving operational excellence. TPQC collects high-resolution process and product data from the entire production route, providing visualizations and facilitating quality assurance. It also enables the application of artificial intelligence techniques to optimize processes, accelerate steel grade development, and enhance product quality. The main objective of TPO is to grow and digitize operational know-how, increase profitability, and better meet customer needs. The paper describes the contribution of these systems to achieving operational excellence, with a focus on quality assurance. Transparent and traceable production data is used for manual and automatic quality evaluation, resulting in product quality status and guiding the product disposition process. Deviation management is supported by rule-based and AI-based assistants, along with monitoring, alarming, and reporting functions ensuring early recognition of deviations. Embedded root cause proposals and their corrective and compensatory actions facilitate decision support to maintain product quality. Quality indicators and predictive quality models further enhance the efficiency of the quality assurance process. Utilizing the quality assurance software package, TPQC acts as a "one-truth" platform for product quality key players.

Surface Characteristics and Biocompatibility of Titanium Coated with Dentin-derived Hydroxyapatite

  • Kim, Hae-Jin;Son, Mee-Kyung;Lee, Kyung-Ku;Lee, Bo-Ah;Kim, Young-Joon
    • International Journal of Oral Biology
    • /
    • v.37 no.1
    • /
    • pp.9-16
    • /
    • 2012
  • The aim of this study was to evaluate surface characteristics and biological properties of the dentin -derived hydroxyapatite (HA) coating on titanium substrate. Dentinderived HA was obtained from extracted human teeth using a calcination method at $850^{\circ}C$. The commercially pure titanium (cp-Ti, ASTM Grade II) was used as a metallic substrate and a radio frequency magnetron sputtering method was employed as a coating method. Scanning electron microscopy (SEM) and energy dispersive X-ray analysis (EDX) were utilized to investigate the coating aspects and composition. Atomic forced microscopy (AFM) and a surface profiler were used to assess the surface morphology and roughness. Corrosion tests were performed in phosphate-buffered saline at a $36.5{\pm}1^{\circ}C$ in order to determine the corrosion behavior of the uncoated and coated specimens. The biocompatibility of dentin-derived HA coated specimens with fetal rat calvarial cells and human gingival fibroblasts was assessed by SEM and cell proliferation analysis. The results showed that the dentin-derived HA coatings appeared to cover thinly and homogeneously the surfaces without changing of the titanium substrate. The EDX analysis of this the coating surface indicated the presence of Ca and P elements. The mean surface roughness of cp-Ti and dentin-derived coating specimens was $0.27{\mu}m$ and, $1.7{\mu}m$, respectively. Corrosion tests indicated a stable passive film of the dentin-derived HA coating specimens. SEM observations of fetal rat calvarial cells and human fibroblast cells on coated surfaces showed that the cells proliferated and developed a network of dense interconnections. The cells on all specimens proliferated actively within the culture period, showing good cell viability. At day 1 and 3, dentin-derived coating specimens showed 89% and 93% cell viability, respectively, when normalized to cp-Ti specimens. These results suggest that dentin-derived HA coating using the RF magnetron sputtering method has good surface characteristics and biocompatibility.

Surface roughness changes caused by the galvanic corrosion between a titanium abutment and base metal alloy (티타늄 지대주와 비귀금속 합금사이의 갈바닉 부식에 의한 표면 거칠기 변화 평가)

  • Lee, Jung-Jin;Song, Kwang-Yeob;Ahn, Seung-Keun;Park, Ju-Mi
    • The Journal of Korean Academy of Prosthodontics
    • /
    • v.49 no.1
    • /
    • pp.65-72
    • /
    • 2011
  • Purpose: The purpose of this study was to evaluate the level of electro-chemical corrosion and surface roughness change for the cases of Ti abutment connected to restoration made of base metal alloys. Materials and methods: It was hypothesized that Ni-Cr alloys in different compositions possess different corrosion resistances, and thus the specimens ($13{\times}13{\times}1.5\;mm$) in this study were fabricated with 3 different types of metal alloys, commonly used for metal ceramic restorations. The electrochemical characteristics were evaluated with potentiostat (Parstat 2273A) and the level of surface roughness change was observed with surface roughness tester. Paired t-test was used to compare mean average surface roughness (Ra) changes of each specimen group. Results: All specimens made of nickel-chromium based alloys, average surface roughness was increased significantly (P < .05). Among them, the Ni-Cr-Be alloy ($0.016{\pm}.007\;{\mu}m$) had the largest change of roughness followed by Ni-Cr ($0.012{\pm}.003\;{\mu}m$) and Ni-Cr-Ti ($0.012{\pm}.002\;{\mu}m$) alloy. There was no significant changes in surface roughness between each metal alloys after corrosion. Conclusion: In the case of galvanic couples of Ti in contact with all specimens made of nickel-chromium based alloys, average surface roughness was increased.

Applications of Micro-Droplet Cell to Study of Localized Corrosion Resistance of Stainless Steels (스테인리스강의 국부부식 저항성 연구에 미세방울셀의 응용)

  • Kim Sung-Yu;Kim Hee-San
    • Journal of the Korean Electrochemical Society
    • /
    • v.9 no.2
    • /
    • pp.70-76
    • /
    • 2006
  • Micro-droplet cell with free droplet as a micro-electrochemical technique has been limited to apply to electrochemical systems with high wetting properties such as an acidic solution and low grade stainless steels(Type 316L). By loading negative pressure to a droplet, control of droplet size, and use of hydrophobic gasket, the cell is modified to be allowed to use for electrochemical systems with high wetting properties. For giving the reliability of new cell, studies on local corrosion were conducted for three different systems-an acidic chloride solution and high chromium ferritic stainless steel, the other acidic chloride solution and type 316, and a neutral chloride solution and type 316. stainless steel. Firstly, the modified micro-droplet cell allows the anodic polarization curves in an acidic chloride solution to show the fact that the local corrosion of high chromium stainless steel near the $\alpha/\sigma$ interface is due to the Cr depleted zone. Secondly, the local anodic polarization test of type 316 L in the other acidic chloride solution can be successfully conducted in the cell. Furthermore, the local polarization curves help elucidating the corrosion of type 316 with $\delta-ferrite$ phase. Finally, the polarization curves of type 316 L in a neutral chloride solution indicates that the factor affecting the pitting corrosion resistance was inclusions rather than $\delta-ferrite$.