• Title/Summary/Keyword: corrosion test

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Aggregate Utilization Estimation of River Sand according to Typical Location of Main Stream of Nakdong-River (낙동강 본류의 대표위치별 하천모래의 골재 활용성 평가)

  • Park, Jae-Im;Bae, Su-Ho;Kwon, Soon-Oh;Kim, Chang-Duk;Lee, Seung-Han
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.13 no.8
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    • pp.3719-3725
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    • 2012
  • Due to the recent shortage of well-graded river sand resulting from a rapid growth of concrete construction, sea sand, crushed sand, and etc. are increasingly used instead. It is, however, well noted that non-washed sea sand leads to corrosion of the reinforcing steel in concrete, and thus eventually results in damage to concrete. Also, the crushed sand is not being widely used, since it is difficult to maintain the allowable amount of passing 0.08mm sieve and to adjust grading. On the other hand, because the fine sand of Nakdong-River has a poor grading but good quality as a fine aggregate for concrete, it is strongly needed to investigate the fine sand as an alternative fine aggregate. Thus, the purpose of this research is to evaluate the physical properties of the fine sand of Nakdong-River to utilize it actively as a fine aggregate. For this purpose, after the sand samples were collected according to typical location of main stream of Nakdong-River, the physical properties such as density in oven-dry condition, grading, unit volume mass, and etc. of them were estimated. It was observed from the test results that physical properties of the fine sand of Nakdong-River except grading were found to be excellent.

A Development of Representative Condition Evaluation Standard for LNG Storage Tank Structures (LNG 저장탱크 구조물의 종합적 상태평가기준 개발)

  • Kim, Jung-Hoon;Jo, Young-Do
    • Journal of the Korean Institute of Gas
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    • v.22 no.6
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    • pp.44-51
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    • 2018
  • As the LNG storage tank is aged, if there is a crack in the outer wall concrete or corrosion of the reinforcing steel, there is a risk of a major accident such as collapse of the structure depending on the type and degree of damage. Since 2014, LNG storage tanks have undergone precise safety diagnosis and safety inspection has been carried out. The condition evaluation criteria for each component have been revised and applied in January 2016. The condition evaluation standard is to evaluate the status of storage tanks based on the appearance survey and material test results of LNG storage tanks and it is important for maintenance. In addition, the representative condition evaluation standard that shows the comprehensive state of each LNG storage tank is important in maintenance, but the related standard for LNG storage tank outer concrete is not available in Korea and abroad, and development of the condition evaluation standard is necessary. In this paper, we examined the structural characteristics of LNG storage tanks, analyzed the status of the condition evaluation criteria for each member, and developed a comprehensive status rating system by weighting the members. We used the AHP(Analytic Hierarchy Process) technique and developed a representative conditon evaluation criteria through surveys of professional organizations.

Evaluation of Chloride Diffusion Characteristics in Concrete with Fly Ash Cured for 2 Years (2년 양생된 Fly Ash 콘크리트의 염화물 확산 특성 평가)

  • Yoon, Yong-Sik;Hwang, Sang-Hyeon;Kwon, Seung-Jun
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.7 no.1
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    • pp.8-15
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    • 2019
  • When RC(Reinforced Concrete) structures are exposed to harsh environment, deterioration phenomenon occurs, and the corrosion in rebar due to chloride intrusion is known as representative deterioration, so called chloride attack. In this paper, chloride resistance performance of 2 years aged concrete is evaluated considering 3 levels of water to binder ratio(0.37, 0.42, and 0.47) and 2 levels of substitution ratio of fly ash(0% and 30%). Accelerated chloride diffusion coefficient tests referred to Tang's method, total passed charge tests referred to ASTM C 1202, and compressive strength tests referred to KS F 2405 are performed. With adaptation of the previous test results and the results from this study, time-dependent chloride diffusion characteristics are analyzed for each concrete. The FA(Fly Ash) concrete has higher chloride resistance performance than OPC(Ordinary Portland Cement) concrete. According to the evaluation standard of ASTM C 1202, the FA concrete has "Moderate" grade after 49 days while OPC concrete does "Moderate" grade after 365 days. As the results of time-parameter for chloride diffusion, OPC concrete and FA concrete show the decreasing behavior of time-parameters with increasing water to binder ratio. Also, FA concrete has 1.57~2.74 times of time-parameter than OPC concrete. That's cause is thought that the time-parameter indicates the gradient of decreasing of diffusion coefficient. FA concrete has higher time-parameters than OPC concrete by pozzolanic reaction of FA.

The effect of plasma treatment to improve adhesion strength of parylene-C coated medical grade SUS304 (Parylene-C 코팅된 의료용 SUS304 소재의 결합력 향상을 위한 플라즈마 처리 효과)

  • Kim, Dong-Guk;Song, Tae-Ha;Jeong, Yong-Hoon;Kang, Kwan-Su;Yoon, Deok-kyu;Kim, Min-Uk;Woo, Young-Jae;Seo, Yo-Han;Kim, Kyung-Ah;Roh, Ji-hyoung
    • Journal of the Korean institute of surface engineering
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    • v.55 no.6
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    • pp.390-397
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    • 2022
  • Parylene-C which was mainly used for industries such as electronics, machinery and semiconductors has recently been in the spotlight in the medical field due to its properties such as corrosion resistance and biocompatibility. In this study we intend to derive a plan to improve the bonding strength of Parylene-C coating with the SUS304 base material for medical use which can be applied to various medical fields such as needles, micro needles and in vitro diagnostic device sensors. Through plasma pretreatment the bonding strength between Parylene-C and metal materials was improved. It was confirmed that the coated surface was hydrophobic by measuring the contact angle and the improvement of the surface roughness of the sample manufactured through CNC machining was confirmed by measuring the surface roughness with SEM. Through the above results, it is thought that it will be effective in increasing usability and reducing pain in patients by minimizing friction when inserting medical devices and in contact with skin. In addition it can be applied to various application fields such as human implantable stents and catheters, and is expected to improve the performance and lifespan of medical parts.

Microstructural Characterization of Clad Interface in Welds of Ni-Cr-Mo High Strength Low Alloy Steel (Ni-Cr-Mo계 고강도 저합금강 용접클래드 계면의 미세조직 특성 평가)

  • Kim, Hong-Eun;Lee, Ki-Hyoung;Kim, Min-Chul;Lee, Ho-Jin;Kim, Keong-Ho;Lee, Chang-Hee
    • Korean Journal of Metals and Materials
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    • v.49 no.8
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    • pp.628-634
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    • 2011
  • SA508 Gr.4N Ni-Cr-Mo low alloy steel, in which Ni and Cr contents are higher than in commercial SA508 Gr.3 Mn-Mo-Ni low alloy steels, may be a candidate reactor pressure vessel (RPV) material with higher strength and toughness from its tempered martensitic microstructure. The inner surface of the RPV is weld-cladded with stainless steels to prevent corrosion. The goal of this study is to evaluate the microstructural properties of the clad interface between Ni-Cr-Mo low alloy steel and stainless weldment, and the effects of post weld heat treatment (PWHT) on the properties. The properties of the clad interface were compared with those of commercial Mn-Mo-Ni low alloy steel. Multi-layer welding of model alloys with ER308L and ER309L stainless steel by the SAW method was performed, and then PWHT was conducted at $610^{\circ}C$ for 30 h. The microstructural changes of the clad interface were analyzed using OM, SEM and TEM, and micro-Vickers hardness tests were performed. Before PWHT, the heat affected zone (HAZ) showed higher hardness than base and weld metals due to formation of martensite after welding in both steels. In addition, the hardness of the HAZ in Ni-Cr-Mo low alloy steel was higher than that in Mn-Mo-Ni low alloy steel due to a comparatively high martensite fraction. The hardness of the HAZ decreased after PWHT in both steels, but the dark region was formed near the fusion line in which the hardness was locally high. In the case of Mn-Mo-Ni low alloy steel, formation of fine Cr-carbides in the weld region near the fusion line by diffusion of C from the base metal resulted in locally high hardness in the dark region. However, the precipitates of the region in the Ni-Cr-Mo low alloy steel were similar to that in the base metal, and the hardness in the region was not greatly different from that in the base metal.

A study on breakthrough characteristics of ion exchange bed with H- and ETAH-form resins for cation exchange in NH3 and ETA solution including trace NaCl (미량의 NaCl을 포함하는 NH3 및 ETA 용액에서 H 및 ETAH 형 수지에 대한 이온교환 파과 특성 연구)

  • Ahn, Hyun-Kyoung;Kim, Youn-Su;Park, Byung-Gi;Rhee, In-Hyoung
    • Journal of Korean Society of Water and Wastewater
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    • v.35 no.6
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    • pp.533-544
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    • 2021
  • Ion exchange (IX) performance on the exchanger bed is essentially evaluated for the generation of ultrapure water in electronics and chemical industries and for the corrosion control in nuclear power plants. The breakthrough characteristics of IX bed with multi-component were investigated with both cation- and mixed-IX beds of H- and ETAH-form for four kinds of cation exchange resins by using the combined solution of ethanolamine (ETA) and ammonia (NH3) at trace NaCl. Unlike major components (ETAH+ and NH4+ ), the phenomena of breakthrough and overshooting at bed outlet were not observed by Na+ over the test period (> 3 times theoretical exchange capacity of IX bed). The breakthrough from H-form resin bed was sequentially reached by ETAH+ and NH4+, while the overshooting was observed for ETAH+ at the breakthrough of NH4+. NH4+ was 51.5% higher than ETAH+ in terms of the relative selectivity determined with the width of breakthrough zone. At the increased concentration of Na+ at bed inlet, the selectivity and the overshooting were decreased and increased, respectively. Na+ leakage was higher from ETAH-form resin bed and was not identical for four kinds of cation-exchange resins, which may be reduced by improving the intrinsic property of IX resin.

Strength and Durability Characteristics of Low-alkali Mortar for Artificial Reefs Produced by 3D Printers (인공어초 3D 프린터 출력을 위한 저알칼리 모르타르의 강도와 내구성능)

  • Lee, Byung-Jae;Kim, Bong-Kyun;Kim, Yun-Yong
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.26 no.1
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    • pp.67-72
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    • 2022
  • Concrete prevents corrosion of reinforcing bars due to its strong alkalinity. However, in the sea, strong alkali components with a pH of 12 to 13 are eluted, which adversely affects the ecological environment and growth of marine organisms. In this study, the mechanical properties and durability of the low alkali mortar were evaluated for the development of a low alkali mortar for the 3D printed artificial reefs. As a result of evaluation of strength characteristics, the α-35 mixture, which were produced with fly ash, silica fume and α-hemihydrate gypsum, satisfied the strength requirement 27 MPa in terms of compressive strength. As a result of pH measurement, it was found that mixing with alpha-type hemihydrate gypsum resulted in minimizing pH due to the the formation of calcium sulfate instead of calcium hydroxide production. As a result of the chloride ion penetration resistance test, the α-35 mixture exhibited the best performance, 3844C. As a result of measuring the length change over time, the α-35 mixture showed the shrinkage 33.5% less compared to the Plain mix.

Variation of Earth Pressure Acting on Cut-and-Cover Tunnel Lining with Settlement of Backfill (되메움토의 침하에 따른 개착식 터널 라이닝에 작용하는 토압의 변화)

  • Bautista F.E.;Park Lee-Keun;Im Jong-Chul;Lee Young-Nam
    • Journal of the Korean Geotechnical Society
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    • v.22 no.6
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    • pp.27-40
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    • 2006
  • Damage of cut-and-cover tunnel lining can be attributed to physical and mechanical factors. Physical factors include material property, reinforcement corrosion, etc. while mechanical factors include underground water pressure, vehicle loads, etc. This study is limited to the modeling of rigid circular cut and cover tunnel constructed at a depth of $1.0{\sim}1.5D$ in loose sandy ground and subjected to a vibration frequency of 100 Hz. In this study, only damages due to mechanical factors in the form of additional loads were considered. Among the different types of additional, excessive earth pressure acting on the cut-and-cover tunnel lining is considered as one of the major factors that induce deformation and damage of tunnels after the construction is completed. Excessive earth pressure may be attributed to insufficient compaction, consolidation due to self-weight of backfill soil, precipitation and vibration caused by traffic. Laboratory tunnel model tests were performed in order to determine the earth pressure acting on the tunnel lining and to investigate the applicability of existing earth pressure formulas. Based on the difference in the monitored and computed earth pressure, a factor of safety was recommended. Soil deformation mechanism around the tunnel was also presented using the picture analysis method.

Comparison of Catalyst Support Degradation of PEMFC Electrocatalysts Pt/C and PtCo/C (PEMFC 전극촉매 Pt/C와 PtCo/C의 촉매 지지체 열화비교)

  • Sohyeong Oh;Yoohan Han;Minchul Chung;Donggeun Yoo;Kwonpil Park
    • Korean Chemical Engineering Research
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    • v.61 no.3
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    • pp.341-347
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    • 2023
  • In PEMFC, PtCo/C alloy catalysts are widely used because of good performance and durability. However, few studies have been reported on the durability of carbon supports of PtCo/C evaluated at high voltages (1.0~1.5 V). In this study, the durability of PtCo/C catalysts and Pt/C catalysts were compared after applying the accelerated degradation protocol of catalyst support. After repeating the 1.0↔1.5V voltage change cycles, the mass activity, electrochemical surface area (ECSA), electric double layer capacitance (DLC), Pt dissolution and the particle growth were analyzed. After 2,000 cycles of voltage change, the current density per catalyst mass at 0.9V decreased by more than 1.5 times compared to the Pt/C catalyst. This result was because the degradation rate of the carbon support of the PtCo/C catalyst was higher than that of the Pt/C catalyst. The Pt/C catalyst showed more than 1.5 times higher ECSA reduction than the PtCo/C catalyst, but the corrosion of the carbon support of the Pt/C catalyst was small, resulting in a small decrease in I-V performance. In order to improve the high voltage durability of the PtCo/C catalyst, it was shown that improving the durability of the carbon support is essential.

Stress-strain Relations of Concrete Confined with Tubes Having Varying GFRP Layers (수적층 및 필라멘트 와인딩을 이용한 GFRP튜브로 구속된 콘크리트의 압축 거동)

  • Lee, Sung Woo;Choi, Sokhwan
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.28 no.6A
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    • pp.861-872
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    • 2008
  • Concrete-filled glass fiber reinforced polymer tubes are often used for marine structures with the benefit of good durability and high resistance against corrosion under severe chemical environment. Current research presents results of a comprehensive experimental investigation on the behavior of axially loaded circular concrete-filled glass fiber reinforced polymer tubes. This paper is intended to examine several aspects related to the usage of glass fiber fabrics and filament wound layers used for outer shell of piles subjected to axial compression. The objectives of the study are as follows: (1) to evaluate the effectiveness of filament winding angle of glass fiber layers (2) to evaluate the effect of number of GFRP layers on the ultimate load and ductility of confined concrete (3) to evaluate the effect of loading condition of specimens on the effectiveness of confinement and failure characteristics as well, and (4) to propose a analytical model which describes the stress-strain behavior of the confined concrete. Three different types of glass fiber layers were chosen; fabric layer, ${\pm}45^{\circ}$ filament winding layer, and ${\pm}85^{\circ}$ filament winding layer. They were put together or used independently in the fabrication of tubes. Specimens that have various L:D ratios and different diameters have also been tested. Totally 27 GFRP tube specimens to investigate the tension capacity, and 66 concrete-filled GFRP tube specimens for compression test were prepared and tested. The behavior of the specimens in the axial and transverse directions, failure types were investigated. Analytical model and parameters were suggested to describe the stress-strain behavior of concrete under confinement.