• Title/Summary/Keyword: corrosion sensitivity

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The effection of alloying elements on welding characteristics of stainless steel (스테인리스강의 용접 특성에 미치는 합금원소의 영향)

  • 정호신;배동수;엄동석
    • Journal of Ocean Engineering and Technology
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    • v.11 no.1
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    • pp.16-23
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    • 1997
  • Stainless steel are widely applicable in various engineering fields for its exellent corrosion and impact ressistance. Austenitic weld metal has some ferrite for preventing solidification cracking by ASME specification. Several family of austenic stainless steel contains varying ferrite contents. But ferrite in austenic stainless steels is adversely affect weld metal toughness and since fully austenic grades are known to have good toughness. Austenic stainless steel has various alloying addition for improving corrosion resistance, impact toughness and solidification crack resistance. The effect of various alloying elements are not found to be clear in present. From this view of point, this study tried to establish the criteria of alloy design for austenic stainless steel by controlling primary solidification mode and clarifying the effect of several alloying elements.

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Complex Leakage Probability Evaluation of Nuclear Pipes by Fatigue and Stress Corrosion Cracking (피로 및 응력부식균열에 의한 원전 배관의 복합누설확률 평가)

  • Kim, Seung Hyun;Goni, Nasimul;Chang, Yoon-Suk;Jang, Changheui
    • Transactions of the Korean Society of Pressure Vessels and Piping
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    • v.11 no.2
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    • pp.25-30
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    • 2015
  • In the present study, complex leakage probabilities of nuclear pipes due to fatigue and stress corrosion cracking are evaluated by using the PINTIN(Piping INTegrity INner flaws) that is developed based on the existing PRAISE(Piping Reliability Analysis Including Seismic Events) program. With regard to the aging and crack instability, small leak and big leak probabilities are calculated for several pipes in a reactor coolant system of domestic nuclear plant. Moreover, sensitivity analysis is also performed to find out the effect of parameters for the leakage of pipes, which shows the coolant temperature is the most influencing parameter.

Effect of Boundary Conditions on Failure Probability of Buried Steel Pile (매설된 강 파일의 경계조건이 파손확률에 미치는 영향)

  • 이억섭;편장식;김의상
    • Journal of the Korean Society for Precision Engineering
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    • v.20 no.4
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    • pp.204-213
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    • 2003
  • A survey for finding corrosion examples was performed on the underground steel piles buried for 19 years in the area of iron and steel making factory near Young-il bay. A failure probability model, which can be used to check the reliability of the corrosive mechanical element, based on Von-Mises failure criterion and the standard normal probability function is proposed. The effects of varying boundary conditions such as temperature change, soil-friction, internal pressure, earthquake, loading of soil, traffic loads and corrosion on failure probability of the buried steel piles are systematically investigated. To allow for the uncertainties of the design variables, a reliability analysis technique has been adopted; this also allows calculation of the relative contribution of the random variables and the sensitivity of the failure probability.

Electrochemical and Cavitation-Erosion Characteristics of Duplex Stainless Steels in Seawater Environment (해수 환경에서 듀플렉스 스테인리스강의 전기화학적 거동 및 캐비테이션 특성)

  • Heo, Ho-Seong;Kim, Seong-Jong
    • Corrosion Science and Technology
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    • v.20 no.6
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    • pp.466-474
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    • 2021
  • A wet type scrubber for merchant vessel uses super austenitic stainless steels with pitting resistance equivalent number (PREN) of 40 or higher for operation in a harsh corrosive environment. However, it is expensive due to a high nickel content. Thus, electrochemical behavior and cavitation erosion characteristics of UNS S32750 as an alternative material were investigated. Microstructure analysis revealed fractions of ferritic and austenitic phases of 48% and 52%, respectively, confirming the existence of ferritic matrix and austenitic island. Potentiodynamic polarization test revealed damage at the interface of the two phases because of galvanic corrosion due to different chemical compositions of ferritic and austenitic phases. After a cavitation test, a compressive residual stress was formed on the material surface due to impact pressure of cavity. Surface hardness was improved by water cavitation peening effect. Hardness value was the highest at 30 ㎛ amplitude. Scanning electron microscopy revealed wave patterns due to plastic deformation caused by impact pressure of the cavity. The depth of surface damage increased with amplitude. Cavitation test revealed larger damage caused by erosion in the ferritic phase due to brittle fracture derived from different strain rate sensitivity index of FCC and BCC structures.

Uncertainty evaluation in electrochemical noise resistance measurement (전기화학적 노이즈 저항 측정에서의 불확도 평가)

  • Kim, Jong Jip;Kang, Su Yeon
    • Corrosion Science and Technology
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    • v.12 no.5
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    • pp.220-226
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    • 2013
  • The uncertainty in statistical noise resistance measurement was evaluated for a type 316 stainless steel in NaCl solutions at room temperature. Sensitivity coefficients were determined for measurands or variables such as NaCl concentration, pH, solution temperature, surface roughness, inert gas flow rate and bias potential amplitude. The coefficients were larger for the variables such as NaCl concentration, pH, inert gas flow rate and solution temperature, and they were the major factors increasing the combined standard uncertainty of noise resistance. However, the contribution to the uncertainty in noise resistance measurement from the above variables was remarkably low compared to that from repeated measurements of noise resistance, and thus, it is difficult to lower the uncertainty in noise resistance measurement significantly by lowering the uncertainties related with NaCl concentration, pH, inert gas flow rate and solution temperature. In addition, the uncertainty in noise resistance measurement was high amounting to 17.3 % of the mean, indicating that the reliability in measurement of noise resistance is low.

Sensitivity Analyses of Finite Element Method for Estimating Residual Stress of Dissimilar Metal Multi-Pass Weldment in Nuclear Power Plant (원전 이종 금속 다층 용접부 잔류응력 예측을 위한 유한요소 변수 민감도 해석)

  • Song, Tae-Kwang;Bae, Hong-Yeol;Kim, Yun-Jae;Lee, Kyoung-Soo;Park, Chi-Yong
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.32 no.9
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    • pp.770-781
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    • 2008
  • In nuclear power plants, ferritic low alloy steel components were connected with austenitic stainless steel piping system through alloy 82/182 butt weld. There have been incidents recently where cracking has been observed in the dissimilar metal weld. Alloy 82/182 is susceptible to primary water stress corrosion cracking. Weld-induced residual stress is main factor for crack growth. Therefore exact estimation of residual stress is important for reliable operating. This paper presents residual stress computation performed by 6" safety & relief nozzle. Based on 2 dimensional and 3 dimensional finite element analyses, effect of welding variables on residual stress variation is estimated for sensitivity analysis.

The Effect of Alloying Elements on Weldability and Corrosion Resistance of Austenitic Stainless Steels(I) (오스테나이트계 스테인리스강의 용접성과 내식성에 미치는 합금원소의 영향(I) - 응고균열 감수성을 중심으로 -)

  • Jeong, Ho-Shin;Lee, Yun-Young;Bae, Dong-Soo
    • Journal of Welding and Joining
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    • v.30 no.3
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    • pp.57-65
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    • 2012
  • The interest of austenitic heat resistant stainless steels containing high Si has increased because they have higher resistance of oxidation and higher strength at high temperature than STS 310. This study carried out Varestraint test for evaluation of solidification cracking sensitivity of 14 different stainless steels. As a result of Varestraint test, all specimens solidified as primary ferrite, and solidification crack sensitivity increased with adding $N_2$ to shielding gas. Nb and W had beneficial effect on solidification crack resistance in case of less than FN 2 containing, but crack sensitivity increased with Nb and W in case of more than FN 2. Ce had beneficial effect on solidification crack resistance but impaired weld bead appearance.

Stress Corrosion Cracking Sensitivity of High-Strength 2xxx Series Aluminum Alloys in 3.5 % NaCl Solution (항공용 고강도 2xxx계 알루미늄 합금의 3.5 % 염수 환경에서의 응력부식균열 민감도)

  • Choi, Heesoo;Lee, Daeun;Ahn, Soojin;Lee, Cheoljoo;Kim, Sangshik
    • Korean Journal of Materials Research
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    • v.28 no.12
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    • pp.738-747
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    • 2018
  • For the aerospace structural application of high-strength 2xxx series aluminum alloys, stress corrosion cracking(SCC) behavior in aggressive environments needs to be well understood. In this study, the SCC sensitivities of 2024-T62, 2124-T851 and 2050-T84 alloys in a 3.5 % NaCl solution are measured using a constant load testing method without polarization and a slow strain rate test(SSRT) method at a strain rate of 10-6 /sec under a cathodic applied potential. When the specimens are exposed to a 3.5 % NaCl solution under a constant load for 10 days, the decrease in tensile ductility is negligible for 2124-T851 and 2050-T84 specimens, proving that T8 heat treatment is beneficial in improving the SCC resistance of 2xxx series aluminum alloys. The specimens are also susceptible to SCC in a hydrogen-generating environment at a slow strain rate of $10^{-6}/sec$ in a 3.5 % NaCl solution under a cathodic applied potential. Regardless of the test method, low impurity 2124-T851 and high Cu/Mg ratio 2050-T84 alloys are found to have relatively lower SCC sensitivity than 2024-T62. The SCC behavior of 2xxx series aluminum alloys in the 3.5 % NaCl solution is discussed based on fractographic and micrographic observations.

INTERGRANULAR CORROSION-RESISTANT STAINLESS STEEL BY GRAIN BOUNDARY ENGINEERING

  • Hiroyuki Kokawa;Masayuki Shimada;Wang, Zhan-Jie;Yutaka S. Sato
    • Proceedings of the KWS Conference
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    • 2002.10a
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    • pp.250-254
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    • 2002
  • Intergranular corrosion of austenitic stainless steels is a conventional and momentous problem during welding and high temperature use. One of the major reasons for such intergranular corrosion is so-called sensitization, i.e., chromium depletion due to chromium carbide precipitation at grain boundaries. Conventional methods for preventing sensitization of austenitic stainless steels include reduction of carbon content in the material, stabilization of carbon atoms as non-chromium carbides by the addition of titanium, niobium or zirconium, local solution-heat-treatment by laser beam, etc. These methods, however, are not without drawbacks. Recent grain boundary structure studies have demonstrated that grain boundary phenomena strongly depend on the crystallographic nature and atomic structure of the grain boundary, and that grain boundaries with coincidence site lattices are immune to intergranular corrosion. The concept of "grain boundary design and control", which involves a desirable grain boundary character distribution, has been developed as grain boundary engineering. The feasibility of grain boundary engineering has been demonstrated mainly by thermomechanical treatments. In the present study, a thermomechanical treatment was tried to improve the resistance to the sensitization by grain boundary engineering. A type 304 austenitic stainless steel was pre-strained and heat-treated, and then sensitized, varying the parameters (pre-strain, temperature, time, etc.) during the thermomechanical treatment. The grain boundary character distribution was examined by orientation imaging microscopy. The intergranular corrosion resistance was evaluated by electrochemical potentiokinetic reactivation and ferric sulfate-sulfuric acid tests. The sensitivity to intergranular corrosion was reduced by the thermomechanical treatment and indicated a minimum at a small roll-reduction. The frequency of coincidence-site-lattice boundaries indicated a maximum at a small strain. The ferric sulfate-sulfuric acid test showed much smaller corrosion rate in the thermomechanically-treated specimen than in the base material. An excellent intergranular corrosion resistance was obtained by a small strain annealing at a relatively low temperature for long time. The optimum parameters created a uniform distribution of a high frequency of coincidence site lattice boundaries in the specimen where corrosive random boundaries were isolated. The results suggest that the thermomechanical treatment can introduce low energy segments in the grain boundary network by annealing twins and can arrest the percolation of intergranular corrosion from the surface.

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AN ELECTROCHEMICAL STUDY ON THE CORROSION RESISTANCE OF THE VARIOUS IMPLANT METALS (수종 임플랜트 금속의 내식성에 관한 전기화학적 연구)

  • Jeon Jin-Young;Kim Yung-Soo
    • The Journal of Korean Academy of Prosthodontics
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    • v.31 no.3
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    • pp.423-446
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    • 1993
  • Titanium and its alloys are finding increasing use in medical devices and dental implants. The strong selling point of titanium is its resistance to the highly corrosive body fluids in which an implant must survive. This corrosion resistance is due to a tenacious passive oxide or film which exists on the metal's surface and renders it passive. Potentiodynamic polarization measurement is one of the most commonly used electro-chemical methods that have been applied to measure corrosion rates. And the potentiodynamic polarization test supplies detailed information such as open circuit, rupture, and passivation potential. Furthermore, it indicates the passive range and sensitivity to pitting corrosion. This study was designed to compare the corrosion resistance of the commonly used dental implant materials such as CP Ti, Ti-6A1-4V, Co-Cr-Mo alloy, and 316L stainless steel. And the effects of galvanic couples between titanium and the dental alloys were assessed for their useful-ness-as. materials for superstructure. The working electrode is the specimen , the reference electrode is a saturated calomel electrode (SCE), and the counter electrode is made of carbon. In $N_2-saturated$ 0.9% NaCl solutions, the potential scanning was performed starting from -800mV (SCE) and the scan rate was 1 mV/sec. At least three different polarization measurements were carried out for each material on separate specimen. The galvanic corrosion measurements were conducted in the zero-shunt ammeter with an implant supraconstruction surface ratio of 1:1. The contact current density was recorded over a 24-hour period. The results were as follows : 1. In potential-time curve, all specimens became increasingly more noble after immersion in the test solution and reached between -70mV and 50mV (SCE) respectively after 12 hours. 2. The Ti and Ti alloy in the saline solution were most resistant to corrosion. They showed the typical passive behavior which was exhibited over the entire experimental range. Therefore no breakdown potentials were observed. 3. Comparing the rupture potentials, Ti and Ti alloy had the high(:st value (because their break-down potentials were not observed in this study potential range ) followed by Co-Cr-Mo alloy and stainless steel (316L). So , the corrosion resistance of titanium was cecellent, Co-Cr-Mo alloy slightly inferior and stainless steel (316L) much less. 4. The contact current density sinks faster than any other galvanic couple in the case of Ti/gold alloy. 5. Ag-Pd alloy coupled with Ti yielded high current density in the early stage. Furthermore, Ti became anodic. 6. Ti/Ni-Cr alloy showed a relatively high galvanic current and a tendency to increase.

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