• Title/Summary/Keyword: corrosion rates

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A Study on the Influences of Recirculated Exhaust Gas upon Wear of Cylinder and Piston in Diesel Engines with EGR System (EGR시스템 디젤기관의 실린더 및 피스톤 마모에 미치는 재순환 배기의 영향에 관한 연구)

  • 하정호
    • Journal of Advanced Marine Engineering and Technology
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    • v.22 no.6
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    • pp.827-835
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    • 1998
  • The effects of recirculated exhaust gas on the wear of cylinder liner piston and piston rings have been investigated by the experiment with a two-cylinder four cycle indirect injection diesel engine operating at 75% load and 1600 rpm speed For the purpose of comparison between the rates of two cylinders with and without EGR the recirculated exhaust gas is sucked into one of two cylinders after the soot among exhaust emissions is removed by an intntionally designed cylinder-type scrubber equipped with 6 water injectors(A water injector has 144 nozzles of 1.0 mm diame-ter) while only the fresh air into another cylinder. These experiments are carried out on the fuel injection at a fixed $15.3^{\circ}$ BTDC timing. It is found that firstly the mean wear amount of cylinder liner with EGR is more increased in the measurement positions of the second half than of the first half and the mean wear amount without EGR is almost uniform regardless of measurement posi-tions secondly the wear rates of the first and second piston ring(compression ring)thickness with EGR are more than twice but the wear rate of oil ring thickness without EGR is more increased than that with EGR and finally the wear rate of piston skirt with EGR is a little bit increased but the piston hed diameter is rather increased owing to soot adhesion and corrosion wear and espe-cially larger with EGR.

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Dry Etching of NiFe, NiFeCo, and Ta in Cl2/Ar Inductively Coupled Plasma (Cl2/Ar 유도 결합 플라즈마를 이용한 NiFe, NiFeCo, Ta의 건식식각)

  • Ra, Hyun-Wook;Park, HyungJo;Kim, Ki Ju;Kim, Wan-Young;Hahn, Yoon-Bong
    • Korean Chemical Engineering Research
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    • v.43 no.1
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    • pp.76-79
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    • 2005
  • Dry etching of NiFe, NiFeCo, and Ta for magnetic random access memory (MRAM) by inductively coupled plasmas (ICPs) of $Cl_2/Ar$ has been carried out. NiFe and NiFeCo showed maximum etch rates at a particular ICP source power, but the etch rate of Ta increased with the ICP source power. The etch rates of the magnetic thin films increased with the RF chuck power, but decreased with the operating pressure and the $Cl_2$ concentration. To avoid a corrosion problem by chlorine, the etched samples were rinsed with de-ionized water for 5 minutes after etching. The etch profile showed a clean and smooth surface at 50% $Cl_2$ concentration.

Numerical Study of the Averaging BDFT(bidirectional flow tube) Flow Meter on the Applicability in the Fouling Condition (수치해석을 이용한 평균 양방향 유동 튜브 유량계의 파울링 환경 적용성 연구)

  • Park, JongPil;Jeong, JiHwan;Kang, KyongHo;Baek, WonPil;Yun, ByongJo
    • The KSFM Journal of Fluid Machinery
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    • v.16 no.4
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    • pp.35-43
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    • 2013
  • Most of the nuclear power plants(NPPs) adopts pressure difference type flow meters such as venturi and orifice meters for the measurement of feedwater flow rates to calculate reactor thermal power. However, corrosion products in the feedwater deposits on the flow meter by fouling as operating time goes. These effects lead to severe errors in the flow indication and then determination of reactor thermal power. The averaging BDFT, which has developed by Yun et al., has a potentiality to minimize this problem thanks to its inherent measurement principle. Therefore, it is expected that the averaging BDFT can replace the venturi meter for the feedwater pipe of steam generator of NPPs. The present work compares the amplification factor, K, based on CFD calculation against the K obtained from experiments in order to confirm whether a commercial CFD code can be applicable to the evaluation of characteristic for the averaging BDFT. In addition to this, the simulations to take into account of fouling effect are also carried out by rough wall option. The results show that the averaging BDFT is a promising flow meter for the accurate measurement of flow rates in the fouling condition of the NPPs.

Halogen-based Inductive Coupled Plasma에서의 W 식각시 첨가 가스의 효과에 관한 연구

  • 박상덕;이영준;염근영;김상갑;최희환;홍문표
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2003.05a
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    • pp.41-41
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    • 2003
  • 텅스텐(W)은 높은 thermal stability 와 process compatibility 및 우수한 corrosion r resistance 둥으로 integrated circuit (IC)의 gate 및 interconnection 둥으로의 활용이 대두되고 있으며, 차세대 thin film transistor liquid crystal display (TFT-LCD)의 gate 및 interconnection m materials 둥으로 사용되고 았다. 그러나, 이러한 장점을 가지고 있는 팅스텐 박막이 실제 공정상에 적용되가 위해서는 건식 식각이 주로 사용되는데, 이는 wet chemical 을 이용한 습식 식각을 사용할 경우 낮은 etch rate, line width 의 감소 및 postetch residue 잔류 동의 문제가 발생하기 때문이다. 또한 W interconnection etching 을 하기 위해서는 높은 텅스텐 박막의 etch rate 과 하부 layer ( (amorphous silicon 또는 poly-SD와의 높은 etch selectivity 가 필수적 이 라 할 수 있다. 그러 나, 지금까지 연구되어온 결과에 따르면 텅스탠과 하부 layer 와의 etch selectivity 는 2 이하로 매우 낮게 관찰되고 았으며, 텅스텐의 etch rate 또한 150nm/min 이하로 낮은 값을 나타내고 있다. 따라서 본 연구에서는 halogen-based inductively coupled plasma 를 이용하여 텅스텐 박막 식각시 여러 가지 첨가 가스에 따른 높은 텅스탠 박막의 etch rate 과 하부 layer 와의 높은 etch s selectivity 를 얻고자 하였으며, 그에 따른 식각 메커니즘에 대하여 알아보고자 하였다. $CF_4/Cl_2$ gas chemistry 에 첨 가 가스로 $N_2$와 Ar을 첨 가할 경 우 텅 스텐 박막과 하부 layer 간의 etch selectivity 증가는 관찰되지 않았으며, 반면에 첨가 가스로 $O_2$를 사용할 경우, $O_2$의 첨가량이 증가함에 따라 etch s selectivity 는 계속적으로 증가렴을 관찰할 수 있었다. 이는 $O_2$ 첨가에 따라 형성되는 WOF4 에 의한 텅스텐의 etch rates 의 감소에 비하여, $Si0_2$ 등의 형성에 의한 poly-Si etch rates 이 더욱 크게 감소하였기 때문으로 사료된다. W 과 poly-Si 의 식각 특성을 이해하기 위하여 X -ray photoelectron spectroscopy (XPS)를 사용하였으며, 식각 전후의 etch depth 를 측정하기 위하여 stylus p pmfilometeT 를 이용하였다.

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A Study on the Significance of Unit Capacity Factor (Utilization Rate) of Nuclear Power Plants and Measures for Increasing (원전 이용률의 의의 및 증진방안 고찰)

  • Don Kug Lee;Chi Bum Bahn
    • Transactions of the Korean Society of Pressure Vessels and Piping
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    • v.18 no.2
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    • pp.87-100
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    • 2022
  • Unit capacity factor (utilization rate) of nuclear power plants (NPPs) is an important performance indicator. Since the first commercial operation of Kori Unit 1 began in April 1978, the utilization rate of domestic NPPs has gradually increased, reaching 90% from the end of the 1990s. However, due to various issues such as the Fukushima accident in 2011, corrosion of the CLP, the utilization rate dropped to 65~80%. In the early 1980s, the utilization rate of the U.S. NPPs was around 60%. However, since 2004, it has been consistently maintained above 90%. Therefore, in this study, we first examined the causes of declining the utilization rate in domestic NPPs. Next, the significances of the utilization rates are reviewed in five aspects: investment capability, electricity rate, safety and export, etc., with discussion on the current status of the utilization rates in the U.S. Based on this, three key factors are derived as the reasons of the increasing: equipment reliability program, on-line maintenance and the pursuit of institutional rationality. And finally, by synthesizing above results, the measures for increasing the utilization rate of domestic NPPs are proposed in terms of equipment management, institutional improvements, and personnel resources.

Influence of Safety Valve Pressure on Gelled Electrolyte Valve-Regulated Lead/Acid Batteries Under Deep Cycling Applications

  • Oh, Sang-Hyub;Kim, Myung-Soo;Lee, Jin-Bok;Lee, Heung-Lark;, Myung-Soo
    • Bulletin of the Korean Chemical Society
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    • v.23 no.1
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    • pp.75-80
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    • 2002
  • Cycle life tests have been carried out to evaluate the influence of safety valve pressure on valve regulated lead/acid batteries under deep cycling applications. Batteries were cycled at 5 hour rates at 100% DOD, and safety valve pressure was set to 1.08 and 2.00 bar, respectively. The batteries lost 248.3 g and 235.3 g of water for each case after about 1,200 cycles, but the cyclic performances of the batteries were comparable. Most of the gas of the battery during discharging was hydrogen, and the oxygen concentration increased to 18% after 3 hours of charging. The micro structure of the positive active materials was completely changed and the corrosion layer of the positive grid was less than $50{\mu}m$, regardless of the pressure of the safety valve after cycle life tests. The cause of discharge capacity decrease was found to be water loss and the shedding of the positive active materials. The pressure of safety valve does not give little effect to the cyclic performances and the failure modes of the gelled electrolyte valve-regulated lead acid batteries.

Production of Hydrogen Sulfide Gas from Sediments in Concrete Sewer (하수관내 침전물의 황화수소가스 발생에 관한 연구)

  • Cho, Sun-Hyoung;Ko, Young-Song;Nam, Sang-Ho
    • Journal of Korean Society of Water and Wastewater
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    • v.10 no.3
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    • pp.83-91
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    • 1996
  • The pulverized wastes originated from kitchen garbage grinder cause an additional load in sewage treatment plant and water environment. Therefore, several problems occur in sewer, such as microbial corrosion, odor, psychoda and fly interrupting flow of sewage etc. by their precipitation with earth and sand. This study was conducted on two experiments: hydrogen sulfide gas generation from sediments in sewer and anaerobic batch test. In anaerobic batch test, gas generation was increased when organic compounds were increased in concentration. Sulfide was decreased upon decreasing in sulfate concentration. In $H_2S$ gas generation test along the depth of sediments there were two different sampling sites which are apart from about 50 cm each other in a menhole. The one has the thickness of 55 cm from the surface, the other, of 60 cm. The hydrogen sulfide gas production rates were measured based on ranges from 0 to 10 cm, 10 to 20 cm, 20 to 30 cm for two samples. The results obtained were 1.08, between 0 to 10 cm in depth for the sample thickness of 55 cm and 3.07, 5.36, $5.42{\mu}g/g-VS{\cdot}hr$ in order of depth for the sample thickness of 60 cm, respectively.

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The assessment of self cleaning velocity and optimal flushing velocity in water distribution system (상수관망의 자가세척 유속과 적정 플러싱 유속 평가)

  • Bae, Cheol-Ho;Choi, Doo Yong;Kim, Ju-Hwan;Kim, Do-Hwan
    • Journal of Korean Society of Water and Wastewater
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    • v.28 no.4
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    • pp.441-451
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    • 2014
  • The flushing is important to maintain good water quality in water main. It is a technique of using water velocity to remove sediments in water distribution system. The variety of water quality problems can occur in a distribution system, so too can a variety of benefits be gained by system flushing. In order to effectively perform the flushing, the contaminants to be removed to set up and it can be solved, it is necessary to ensure the proper flow rate. In this study, the removal of contaminants present in the inner water pipe attached loose deposits such as fine particles of granular activated carbon, sand and iron corrosion product sought to derive flow rates. Thus, the constant observation of using pilot plant scale water distribution plant for the movement of floating characteristics of particles were assessed.

An Experimental Study on Mode Switching from Air-firing to Oxy-firing in Pilot-scale Combustion Systems (미분탄 순산소 연소 운전 모드 전환 과정에 대한 Pilot 규모 설비에서의 실험적 연구)

  • Choi, Chong-Gun;Na, Ik-Hwan;Lee, Jae-Wook;Chae, Tae-Young;Yang, Won;Kim, Young-Ju;Kim, Jong-An;Seo, Sang-Il
    • Journal of the Korean Society of Combustion
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    • v.16 no.3
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    • pp.12-20
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    • 2011
  • Oxy-coal combustion for $CO_2$ capture in coal power plants entails a mode switching from air-firing to oxyfiring. In this study, procedure of the mode switching was investigated and discussed through experiments in pilot scale facilities: (1) a 0.3 $MW_{th}$ furnace with a vertical single burner and a FGR(Flue Gas Recirculation) system (2) a 1 $MW_{th}$ furnace with horizontal 4 burners and a FGR system. Principle of the mode switching was established and performed with control of FD fan, FGR fan, ID fan and oxygen flow rates. We have found that equivalence ratio in the oxy-firing mode should be increased more than that in the air-firing to achieve stable mode switching. Control of FD, ID and FGR fans should be performed carefully in the mode switching, in the sense of complete combustion and flame attachment. Moisture contents in the ash and the flue gas recycled to the primary oxidizer stream should be removed to prevent condensation, corrosion and duct clogging.

Fabrication and Characterization of Novel Electrospun PVPA/PVA Nanofiber Matrix for Bone Tissue Engineering

  • Franco, Rose-Ann;Nguyen, Thi Hiep;Lee, Byong-Taek
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2011.05a
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    • pp.51.2-51.2
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    • 2011
  • A novel electrospun nanofiber membrane was fabricated using combined poly (vinylphosphonic acid) (PVPA) and polyvinyl alcohol (PVA) intended for bone tissue engineering applications. PVPA is a proton-conducting polymer used as primer for bone implants and dental cements to prevent corrosion and brush abrasion. The phosphonate groups of PVPA have the ability to crosslink and attach itself to the hydroxyapatite surface facilitating faster integration of the biomaterial to the bone matrix. PVA was combined with PVPA to provide hydrophilicity, biocompatibility and improve its spinnability. To improve its mechanical strength, PVPA/PVA and neat PVA mixtures were combined to produce a multilayer scaffold. The physical and chemical properties of the of the fabricated matrix was investigated by SEM and TEM morphological analyses, tensile strength test, XRD, FT-IR spectra, swelling behavior and biodegradation rates, porosity and contact angle measurements. Biocompatibility was also examined in vitro by cytotoxicity and cell proliferation studies with MTT assay and cell adhesion behavior by SEM and confocal microscopy.

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