• 제목/요약/키워드: corrosion phenomenon

검색결과 134건 처리시간 0.031초

유속에 따른 ERW 탄소강관의 홈부식 특성에 관한 연구 (A study on the characteristic of the Groove corrosion of ERW carbon steel according to water speed)

  • 김재성;이영기;김용;이보영
    • 대한용접접합학회:학술대회논문집
    • /
    • 대한용접접합학회 2009년 추계학술발표대회
    • /
    • pp.82-82
    • /
    • 2009
  • 강관은 물, 유류, 천연 가스 등을 운송하는 배관용 및 건물의 골조, 유압 및 공압 실린더, 가이드 레일 등 의 기계적 부품으로도 널리 사용되기도 한다. 이렇게 사용되는 강관의 70% 이상은 고주파 전기저항용접(High Frequency Electrical Resistance Welding,이하 ERW)으로 제조되고 있다. 아파트 등 실제 현장에서 ERW 강관에 흐르는 유체는 비드가 제거된 내면 부위에서 와류 (vortex)를 일으켜 기계적 침식(erosion)을 수반할 가능성이 있으며, 수격현상으로 인해 부식 부위에서 반복피로 하중을 받아 부식의 전파속도가 증가되어 최종적 으로 파손되는 경우도 예상할 수 있다. 이에 본 연구에서는 입열량을 달리하여 제조된 ERW 강관을 대상으로 강관 내부에서의 유속에 따라 홈부식 감수성에 미치는 영향을 확인하고자 하였다. 이를 위해 실제 사용 환경을 모사할 수 있는 장치를 제작하고 경계 조건을 선정하여 실험을 실시하였다. ERW 강관의 내부에서 유속이 빨라질 경우 부식속도는 증가를 하였고, 입열을 많이 받은 강관의 경우 부식속도가 감소하는 경향을 가졌다. 이러한 결과를 바탕으로 하여 ERW 강관에서 발생하고 있는 결함발생에 의한 피해를 극소화시킴으로서 안전하고 효율적인 관리에 기여하고자 한다.

  • PDF

Al-Alloy 7075-T651의 부식피로균열 성장거동에 관한 연구(I) (A Study on Corrosion Fatigue Crack Growth Behavior in Al-Alloy 7075-T651 (I))

  • 김봉철;한지원;우흥식
    • 한국안전학회지
    • /
    • 제13권4호
    • /
    • pp.113-120
    • /
    • 1998
  • Fatigue crack growth rates(i.e. crack initiation and crack growth of short and long crack) are investigated using commercial plates of high strength Al alloy 7075-T651 for the transverse-longitudinal(T-L) direction in air, water and sea water. Also, the evaluation direct current potential drop(D.C.P.D) method and the fractographical analysis by SEM are carried out. Near threshold region, short crack growth rates were much faster than those of comparable long cracks, and these short crack growth rates actually decrease with increasing crack growth and eventually merge with long crack data. Fatigue crack propagation rates in aggressive media(i.e. sea water) increase noticeably over three times those in air. One of the most significant characters in this phenomenon as a corrosion-fatigue causes an acceleration in crack growth rates. Sea water environment, particularly Cl$^{[-10]}$ solution brings the most detrimental effects to aluminum alloy. The result of fractographical morphology in air, water and sea water by SEM shows obvious dimpled rupture and typical striation in air, but transgranular fracture surface in water and sea water.

  • PDF

실리콘 태양전지 모듈의 two-mode failure 모델의 연구 (A Study of Two-Mode Failure Model for Crystalline Si Photovoltaic Module)

  • 최기영;오원욱;강병준;김영도;탁성주;김동환
    • 한국신재생에너지학회:학술대회논문집
    • /
    • 한국신재생에너지학회 2011년도 추계학술대회 초록집
    • /
    • pp.62.2-62.2
    • /
    • 2011
  • To guarantee 20-25 years to the lifetime of the PV modules without failure, reliability test of the module is very important. Field-aged test of the outdoor environment is required. However, due to time constraints, accelerated testing is required to predict the lifetime of PV modules and find causes of failure. Failure is caused by many complex phenomena. In this study, we experimented two accelerated tests about corrosion and fatigue, respectively. First, temperature cycling test for fatigue were tested and Coffin-Manson equation was analyzed. Second, damp heat test for corrosion were tested and Eyring equation were analyzed. Finally, using two-mode failure model, we suggest a new lifetime model that analyze the phenomenon by combining two kinds of data.

  • PDF

Cause Analysis for a Lining Damage in Sea Water System Piping Installed in a Korean Industrial Plant

  • Hwang, K.M.;Park, S.K.
    • Corrosion Science and Technology
    • /
    • 제20권1호
    • /
    • pp.1-6
    • /
    • 2021
  • Many Korean industrial plants including nuclear and fossil power plants use seawater as the ultimate heat sink to cool the heat generated by various facilities. Owing to the high corrosivity of seawater, facilities and piping made of metal material in contact with seawater are coated or lined with polymeric materials to avoid direct contact with seawater. However, polymeric materials used as coating and lining have some level of permeability to water and are degraded over time. Korean industrial plants have also experienced a gradual increase in the frequency of damage to pipes in seawater systems due to prolonged operating periods. In the event of a cavitation-like phenomenon, coating or lining inside the piping is likely to be damaged faster than expected. In this paper, the cause of water leakage due to base metal damage caused by the failure of the polyester lining in seawater system piping was assessed and the experience with establishing countermeasures to prevent such damage was described.

복합소재를 이용한 저가형 3kW 소수력 발전시스템 개발 (Developed Low-priced 3kW Small Hydro Power Generation System using Composite Material)

  • 소병문;김성희;한우용
    • 반도체디스플레이기술학회지
    • /
    • 제17권1호
    • /
    • pp.84-87
    • /
    • 2018
  • As the propeller end speed increases, the propeller surface is damaged in the process of bubble formation and dropout. It is intended to prevent the corrosion of the propeller by modifying the shape of the end through the winglet structure to mitigate the cavitation phenomenon. In the case of conventional SUS materials, the cost of production is so high that plastic materials are used to prevent corrosion. This paper aims to mitigate the cavitation by deforming the shape of the end through the winglet structure by using the SMC composite material of the propeller using the existing SUS.

Corrosion Behavior of Stainless Steel 316 for Carbon Anode Oxide Reduction Application

  • Jeon, Min Ku;Kim, Sung-Wook;Choi, Eun-Young
    • 방사성폐기물학회지
    • /
    • 제18권2호
    • /
    • pp.169-177
    • /
    • 2020
  • Here, the stability of stainless steel 316 (SS-316) was investigated to identify its applicability in the oxide reduction process, as a component in related equipment, to produce a complicated gas mixture composed of O2 and Cl2 under an argon (Ar) atmosphere. The effects of the mixed gas composition were investigated at flow rates of 30 mL/min O2, 20 mL/min O2 + 10 mL/min Cl2, 10 mL/min O2 + 20 mL/min Cl2, and 30 mL/min Cl2, each at 600℃, during a constant argon flow rate of 170 mL/min. It was found that the corrosion of SS-316 by the chlorine gas was suppressed by the presence of oxygen, while the reaction proceeded linearly with the reaction time regardless of gas composition. Surface observation results revealed an uneven surface with circular pits in the samples that were fed mixed gases. Thermodynamic calculations proposed the combination of Fe and Ni chlorination reactions as an explanation for this pit formation phenomenon. An exponential increase in the corrosion rate was observed with an increase in the reaction temperature in a range of 300 ~ 600℃ under a flow of 30 mL/min Cl2 + 170 mL/min Ar.

CO2 양생을 이용한 시멘트계 재료의 압축강도 발현에 관한 실험적 연구 (The experimental study on the compressive strength for cementitious material using CO2 curing)

  • 성명진;류화성;신상헌;이한승
    • 한국건축시공학회:학술대회논문집
    • /
    • 한국건축시공학회 2014년도 춘계 학술논문 발표대회
    • /
    • pp.264-265
    • /
    • 2014
  • Currently, CO2 existed in the air usually reacts concrete, and then CaCO3 can be appeared. As time goes by, pH of concrete is decreased and corrosion of steel can be happened. This phenomenon is called carbonation. For preventing carbonation of concrete, various methods like using corrosion inhibitor, high compressive strength concrete, and enough covering depth are adopted. But these method are usually passive methods focused on corrosion of steel and have limitation on economic. Thus, as basic study for active method of carbonation, cement pastes with CO2 reactive material (γ-C2S, MgO) and GBFS were in accelerated carbonation, and the compressive strengths were measured. On the result, the compressive strength was improved better than non-carbonation. Through measuring the weight change using TG-DTA, as specimens were carbonated, according to decreasing of Ca(OH)2 and Mg(OH)2, CaCO3 and MgCO3 were increased. Therefore it can be shown that carbonation curing can be realized.

  • PDF

Use of Local Electrochemical Methods (SECM, EC-STM) and AFM to Differentiate Microstructural Effects (EBSD) on Very Pure Copper

  • Martinez-Lombardia, Esther;Lapeire, Linsey;Maurice, Vincent;De Graeve, Iris;Klein, Lorena;Marcus, Philippe;Verbeken, Kim;Kestens, Leo;Gonzalez-Garcia, Yaiza;Mol, Arjan;Terryn, Herman
    • Corrosion Science and Technology
    • /
    • 제16권1호
    • /
    • pp.1-7
    • /
    • 2017
  • When aiming for an increased and more sustainable use of metals a thorough knowledge of the corrosion phenomenon as function of the local metal microstructure is of crucial importance. In this work, we summarize the information presented in our previous publications[1-3] and present an overview of the different local (electrochemical) techniques that have been proven to be effective in studying the relation between different microstructural variables and their different electrochemical behavior. Atomic force microscopy (AFM)[1], scanning electrochemical microscopy (SECM)[2], and electrochemical scanning tunneling microscopy (EC-STM)[3] were used in combination with electron backscatter diffraction (EBSD). Consequently, correlations could be identified between the grain orientation and grain boundary characteristics, on the one hand, and the electrochemical behavior on the other hand. The grain orientation itself has an influence on the corrosion, and the orientation of the neighboring grains also seems to play a decisive role in the dissolution rate. With respect to intergranular corrosion, only coherent twin boundaries seem to be resistant.

고온부재의 재질열화에 따른 응력부식균열 평가에 관한 연구 (A Study on Stress Corrosion Cracking Evaluation with Material Degradation of High Temperature Components)

  • 박종진;유호선;정세희
    • 대한기계학회논문집A
    • /
    • 제20권4호
    • /
    • pp.1123-1132
    • /
    • 1996
  • It has been reported that high temperature structural components represent the phenomenon of material degradation according to a long term service under high temperature and pressure. Especially, fossile power plant components using the fossil fuel and heavy oil are affected by dewpoint corrosion of $H_2SO_4$produced during a combustion. Therefore, the service materials subjected to high temperature and pressure may occur the stress corrosion cracking. The object of this paper is to investigate SCC susceptibility according to the material degradation of the high temperature structural materials in dewpoint corrosive environment-$H_2SO_4$.The obtained results are summarized as follows : 1) In case of secondary superheater tube, the fractograph of dimple is observed at the concentration of $H_2SO_4$-5%. When the concentration of $H_2SO_4$ is above 10%, the fracture mode is shifted from a transgranular fracture to an quasi-intergranular fracture according to the increment of concentration. 2) In the relationship between [$\Delta$DBTT]$_sp$ and SCC susceptibility, it is confirmed that the greater material degradation degree is, the higher SCC susceptibility is. In addition, it can be known that SP test is useful test method to evaluate SCC susceptibility for high temperature structural components. 3) When [$\Delta$DBTT]$_sp$ is above 17$17^{\circ}C$ the SCC fracture behavior is definitely observed with SCC susceptibility of above 0.4.

질산과 황산 용액중의 철강의 전기방식도에 관한 연구 (A study on electrochemical protection diagrams of steel in nitric and sulfuric acid solutions)

  • 전대희;김진경
    • Journal of Advanced Marine Engineering and Technology
    • /
    • 제13권2호
    • /
    • pp.43-63
    • /
    • 1989
  • Various kinds of corrosion prevention methods have been developed. It is known that the method of electrochemical protection is more effective and economical than any other method on the large scale metal structures in corrosive solutions. Strong acid solutions such as nitric and sulfuric acid solutions are often used in industries, and the expensive stainless steel is almost exclusively used for the equipment that comes in contact with such acid solutions. However, it is more reasonable that carbon steel is used rather than stainless steel depending upon concentration of those acid solutions from the economical viewpoint. In this study, the typical strong acid solution such as nitric and sulfuric acid solutions are chosen for the experiment and the selected materials of specimen are the stainless steels of SUS 304L and SUS 316L, the carbon steels of SS 41, SM 50 and RA 32, and highly pure lead. Electrochemical protection diagrams can be drawn with data from the external cathodic and anodic polarization curves of SUS 304L, SUS 316L and SM 50 steels in 5-60% nitric acid solutions and from those polarization curves of SS 41, RA 32, SM 50 and SUS 316L steels, and highly pure lead in 2.5-98% sulfuric acid solutions at the slow scanning rate. The data obtained with using the determination method of the optimum cathodic protection potential, the Tafel extrapolation method and the characteristics of anodic polarization curves. The main results obtained from the diagrams are as follows: 1) In nitric acid solution : (1) Corrosion potentials exist in each of those corrosion zones on the stainless steels in the lower concentration than about 12% solutions and on the high tensile strength steels in the lower concentration than about 30% solutions, but the corrosion current (density) in each zone is small on the above mentioned former steels and large on the latter ones. (2) The stainless steels can be self-passivated in the higher concentration than 15% solutions, and the high tensile strength steels gives rise to the same phenomenon in the higher concentration than 35% solutions. (3) The stainless steels in the lower concentration than 60% solutions and the high tensile strength steels in the higher concentration than 35% solutions can be used without protection, but the latter steels must ve protected anodically in the lower conccentration than about 30% solutions. 2) In sufuric acid solution : (1) The carbon steels can be self-passivated in the higher concentration than 45% solutions, and the SUS 316L steel in higher concentration than 75% solutions and the lead in all concentration solutions also gives rise to the same phenomenon. (2) The lead in the lower concentration than 80% solutions and the SUS 316L steel in the higher concentration than 80% solutions can be used without protection. (3) The carbon steels in the higher concentration than 50% solutions also can be used without protecting economically, but the SUS 316L steel in the 20-70% solutions are considerably corrosive without protecting anodically.

  • PDF