• Title/Summary/Keyword: corrosion modeling

검색결과 120건 처리시간 0.027초

유동가속부식에 대한 통계적 모델링 해석방법 개발: 유속, 온도, pH 및 Cr 함량의 효과 (Development of Statistical Modeling Methodology for Flow Accelerated Corrosion: Effect of Flow Rate, Water Temperature, pH, and Cr Content)

  • 이경근;이은희;김성우;김동진
    • 한국압력기기공학회 논문집
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    • 제12권2호
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    • pp.40-49
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    • 2016
  • Flow accelerated corrosion (FAC) of the carbon steel piping has been a significant problem in nuclear power plants. FAC occurs under certain hydrodynamic, environmental, and material conditions, and extensive research into the factors of FAC has been conducted. The basic process of FAC is now relatively well understood; however, a full mechanistic model has not yet been established. Recently, the Korea Atomic Energy Research Institute (KAERI) has built a large experiment loop system for FAC. To produce significant experimental results using this system, the factors affecting on FAC should be analyzed quantitatively, and a model needs to be developed. In this work, a statistical modeling methodology to develop an empirical model is described in detail, and a preliminary model is suggested. Firstly, FAC data were collected from the research literature in Japan and the results of domestic experiments. The flow rate, water temperature, pH at room temperature, and the Cr content are selected as major factors, and nonlinear regression is used to find the best fit of the available data. An iterative procedure between suggesting and evaluating a model is used until an optimum model is obtained. The developed model gives the FAC rate comparable to the measured FAC rate. The developed model is going to be refined using additional laboratory data in the future.

음극방식 시스템에서의 압입관과 배관의 부식거동에 관한 수학적 모델링 (Mathematical Modeling on the Corrosion Behavior of the Steel Casing and Pipe in Cathodic Protection System)

  • 김영석;이선엽;박경완;전경수;고영태
    • 한국가스학회지
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    • 제2권1호
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    • pp.40-46
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    • 1998
  • 음극방식 시스템의 방식전류에 의한 압입구간내의 압입관과 배관의 부식거동에 관한 수학적 모델링을 경계요소법을 이용하여 수행하였다. 모델은 비선형 경계조건(Tafel 방정식)을 가진 라플라스 방정식으로 이루어져 있으며 압입관의 혼합전위를 구하기 위하여 혼합전위 이론을 응용한 반복법을 사용하였으며 그위에 비선형 경계조건에 대한 해석을 위하여 이중 반복법을 사용하였다. 모델은 정상적인 압입구간 뿐만 아니라 압입관과 배관과의 금속간 접촉(metal touch)이나 외부환경과 압입구간 내부를 격리시키는 절연부위의 손상과 같은 결함들을 가진 비정상적인 압입구간들에 대해서 적용되었다. 수학적 모델링의 결과로부터 압입구간에의 전위분포와 전류분포를 계산할 수 있었다. 모델링의 타당성을 증명하기 위하여 모사실험을 수행하였으며 실험조건내에서 이론적인 결과와 실험결과는 정성적으로 잘 일치하였다.

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부식을 고려한 판형교의 LCC 분석 데이터구조 설계 (Data Structure Modeling for the LCC Analysis of the Plate Girder Bridge Considering Corrosion)

  • 김동현;김봉근;이상호
    • 한국방재학회:학술대회논문집
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    • 한국방재학회 2007년도 정기총회 및 학술발표대회
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    • pp.497-500
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    • 2007
  • Data structure was designed not only to estimate LCC but also to analyze time-variant reliability index of plate girder bridges. Information model for data structure was categorized into cost information, cost variable information, user cost information, and reliability analysis information according to the characteristic of data. EXPRESS language of STEP was adopted to describe the data structure for the electronic representation of LCC information. The suitability of the developed data structure was verified by estimating LCC and analyzing time-variant reliability index of a plate girder bridge considering corrosion on the basis of the constructed test database.

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원유 증류 공정 탑 상부의 부식 예측 모델 개발 (Development of a Forecasting Model for Refinery Crude Column Overhead Corrosion Control)

  • 김승남;김정환;문일
    • 대한기계학회논문집A
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    • 제35권2호
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    • pp.143-148
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    • 2011
  • 정유 석유화학 플랜트에서 탑 상부의 부식은 현장에서 자주 발생되는 심각한 문제이다. 특히 정유 공정 탑 상부에는 황화수소, 염소 등의 부식 물질들로 인하여 그 피해 정도가 심각하다. 따라서 본 연구에서는 정유 공정 탑 상부의 부식 메커니즘을 분석하고, 부식률을 예측하는 모델을 개발하였다. 정유 공정 탑 상부의 부식 메커니즘을 분석한 결과, 부식에 가장 큰 영향을 미치는 네 가지 성분인 $H_2S$, $CO_2$, $H^+$, $Cl^-$을 고려하여 예측 모델을 개발하였다. 부식 메커니즘을 해석하는 데에 이동 현상 및 반응 공학의 관점으로 접근하여 모델을 개발 하였다. 또한 실제 정유공장에서 측정된 데이터들을 토대로 그 신뢰성을 검증하였다.

Assessment of some parameters of corrosion initiation prediction of reinforced concrete in marine environments

  • Moodi, Faramarz;Ramezanianpour, Aliakbar;Jahangiri, Ehsan
    • Computers and Concrete
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    • 제13권1호
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    • pp.71-82
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    • 2014
  • Chloride ion ingress is one of the major problems that affect the durability of concrete structures such as bridge decks, concrete pavements, and other structures exposed to harsh saline environments. Therefore, durability based design of concrete structures in severe condition has gained great significance in recent decades and various mathematical models for estimating the service life of rein-forced concrete have been proposed. In spite of comprehensive researches on the corrosion of rein-forced concrete, there are still various controversial concepts in quantitation of durability parameters such as chloride diffusion coefficient and surface chloride content. Effect of environment conditions on the durability of concrete structures is one of the most important issues. Hence, regional investigations are necessary for durability based design and evaluation of the models. Persian Gulf is one of the most aggressive regions of the world because of elevated temperature and humidity as well as high content of chloride ions in seawater. The aim of this study is evaluation of some parameters of durability of RC structures in marine environment from viewpoint of corrosion initiation. For this purpose, some experiments were carried out on the real RC structures and in laboratory. The result showed that various uncertainties in parameters of durability were existed.

Toward the multiscale nature of stress corrosion cracking

  • Liu, Xiaolong;Hwang, Woonggi;Park, Jaewoong;Van, Donghyun;Chang, Yunlong;Lee, Seung Hwan;Kim, Sung-Yup;Han, Sangsoo;Lee, Boyoung
    • Nuclear Engineering and Technology
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    • 제50권1호
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    • pp.1-17
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    • 2018
  • This article reviews the multiscale nature of stress corrosion cracking (SCC) observed by high-resolution characterizations in austenite stainless steels and Ni-base superalloys in light water reactors (including boiling water reactors, pressurized water reactors, and supercritical water reactors) with related opinions. A new statistical summary and comparison of observed degradation phenomena at different length scales is included. The intrinsic causes of this multiscale nature of SCC are discussed based on existing evidence and related opinions, ranging from materials theory to practical processing technologies. Questions of interest are then discussed to improve bottom-up understanding of the intrinsic causes. Last, a multiscale modeling and simulation methodology is proposed as a promising interdisciplinary solution to understand the intrinsic causes of the multiscale nature of SCC in light water reactors, based on a review of related supporting application evidence.

LIFE-SPAN SIMULATION AND DESIGN APPROACH FOR REINFORCED CONCRETE STRUCTURES

  • An, Xuehui;Maekawa, Koichi;Ishida, Tetsuya
    • 한국전산구조공학회:학술대회논문집
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    • 한국전산구조공학회 2007년도 정기 학술대회 논문집
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    • pp.3-17
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    • 2007
  • This paper provides an introduction to life-span simulation and numerical approach to support the performance design processes of reinforced concrete structures. An integrated computational system is proposed for life-span simulation of reinforced concrete. Conservation of moisture, carbon dioxide, oxygen, chloride, calcium and momentum is solved with hydration, carbonation, corrosion, ion dissolution. damage evolution and their thermodynamic/mechanical equilibrium. Coupled analysis of mass transport and damage mechanics associated with steel corrosion is presented for structural performance assessment of reinforced concrete. Multi-scale modeling of micro-pore formation and transport phenomena of moisture and ions are mutually linked for predicting the corrosion of reinforcement and volumetric changes. The interaction of crack propagation with corroded gel migration can also be simulated. Two finite element codes. multi-chemo physical simulation code (DuCOM) and nonlinear dynamic code of structural reinforced concrete (COM3) were combined together to form the integrated simulation system. This computational system was verified by the laboratory scale and large scale experiments of damaged reinforced concrete members under static loads, and has been applied to safety and serviceability assessment of existing structures. Based on the damage details predicted by the nonlinear finite element analytical system, the life-span-cost of RC structures including the original construction costs and the repairing costs for possible damage during the service life can be evaluated for design purpose.

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Utilization of EPRI ChemWorks tools for PWR shutdown chemistry evolution modeling

  • Jinsoo Choi;Cho-Rong Kim;Yong-Sang Cho;Hyuk-chul Kwon;Kyu-Min Song
    • Nuclear Engineering and Technology
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    • 제55권10호
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    • pp.3543-3548
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    • 2023
  • Shutdown chemistry evolution is performed in nuclear power plants at each refueling outage (RFO) to establish safe conditions to open system and minimize inventory of corrosion products in the reactor coolant system (RCS). After hydrogen peroxide is added to RCS during shutdown chemistry evolution, corrosion products are released and are removed by filters and ion exchange resins in the chemical volume control system (CVCS). Shutdown chemistry evolution including RCS clean-up time to remove released corrosion products impacts the critical path schedule during RFOs. The estimation of clean-up time prior to RFO can provide more reliable actions for RCS clean-up operations and transients to operators during shutdown chemistry. Electric Power Research Institute (EPRI) shutdown calculator (SDC) enables to provide clean-up time by Co-58 peak activity through operational data from nuclear power plants (NPPs). In this study, we have investigated the results of EPRI SDC by shutdown chemistry data of Co-58 activity using NPP data from previous cycles and modeled the estimated clean-up time by EPRI SDC using average Co-58 activity of the NPP. We selected two RFO data from the NPP to evaluate EPRI SDC results using the purification time to reach to 1.3 mCi/cc of Co-58 after hydrogen peroxide addition. Comparing two RFO data, the similar purification time between actual and computed data by EPRI SDC, 0.92 and 1.74 h respectively, was observed with the deviation of 3.7-7.2%. As the modeling the estimated clean-up time, we calculated average Co-58 peak concentration for normal cycles after cycle 10 and applied two-sigma (2σ, 95.4%) for predicted Co-58 peak concentration as upper and lower values compared to the average data. For the verification of modeling, shutdown chemistry data for RFO 17 was used. Predicted RCS clean-up time with lower and upper values was between 21.05 and 27.58 h, and clean-up time for RFO 17 was 24.75 h, within the predicted time band. Therefore, our calculated modeling band was validated. This approach can be identified that the advantage of the modeling for clean-up time with SDC is that the primary prediction of shutdown chemistry plans can be performed more reliably during shutdown chemistry. This research can contribute to improving the efficiency and safety of shutdown chemistry evolution in nuclear power plants.

환경피로균열 열화특성 예측을 위한 확률론적 접근 (Probabilistic Approach for Predicting Degradation Characteristics of Corrosion Fatigue Crack)

  • 이태현;윤재영;류경하;박종원
    • 한국신뢰성학회지:신뢰성응용연구
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    • 제18권3호
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    • pp.271-279
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    • 2018
  • Purpose: Probabilistic safety analysis was performed to enhance the safety and reliability of nuclear power plants because traditional deterministic approach has limitations in predicting the risk of failure by crack growth. The study introduces a probabilistic approach to establish a basis for probabilistic safety assessment of passive components. Methods: For probabilistic modeling of fatigue crack growth rate (FCGR), various FCGR tests were performed either under constant load amplitude or constant ${\Delta}K$ conditions by using heat treated X-750 at low temperature with adequate cathodic polarization. Bayesian inference was employed to update uncertainties of the FCGR model using additional information obtained from constant ${\Delta}K$ tests. Results: Four steps of Bayesian parameter updating were performed using constant ${\Delta}K$ test results. The standard deviation of the final posterior distribution was decreased by a factor of 10 comparing with that of the prior distribution. Conclusion: The method for developing a probabilistic crack growth model has been designed and demonstrated, in the paper. Alloy X-750 has been used for corrosion fatigue crack growth experiments and modeling. The uncertainties of parameters in the FCGR model were successfully reduced using the Bayesian inference whenever the updating was performed.

폴리머 시멘트 모르타르의 철근부착력 평가를 위한 인발실험과 모델링 (Bonding Properties of Steel-reinforced Polymer Cement Mortar Evaluated by Pull-off Test and FEM Modeling)

  • 박동천;노부토시 요네다;조봉석
    • 한국건축시공학회지
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    • 제14권3호
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    • pp.216-222
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    • 2014
  • 단면수복 보수를 실시한 RC조 부재의 내하성능 회복을 예측 평가하기 위하여 FEM해석이 빈도 높게 사용되고 있으나 부착에 대한 정보가 부족하여 정확도 있는 예측이 힘든 실정이다. 수치해석의 입력데이터가 되는 철근과 폴리머 시멘트 모르타르의 부착특성을 평가하기 위하여 폴리머 시멘트 모르타르를 이용한 일련의 인발실험을 실시하였다. 동시에 범용성있는 해석결과 활용을 위하여 부착특성을 부착강성과 부착강도로 정의하고 비선형 FEM 감도 역해석을 실시하였다. 결과를 요약하면 보수재료의 화학적 부착보다 물리적 부착이 지배적이며 폴리머 분말수지의 함유에 의해 다소 부착계면의 성능이 저하하는 것을 알 수 있었다. 부착계면의 물성은 강성과 강도로 구분하여 모델화하는 것이 합리적인 것으로 사료된다.