• Title/Summary/Keyword: corrosion evaluation

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Damage Characteristics of Metal Materials According to the SO2 Concentration (이산화황 농도에 따른 금속시편의 손상 특성)

  • Kim, Myoung Nam;Lim, Bo A;Shin, Eun Jeong;Lee, Sun Myung
    • Korean Journal of Heritage: History & Science
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    • v.46 no.1
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    • pp.176-187
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    • 2013
  • A study has been carried out on metal materials in order to identify the quantitative relation between the concentration and damage characteristics after evaluation of the damage characteristics according to the $SO_2$ concentration. The prepared metal samples, which were categorized according to the material (silver, copper, iron, lead, brass) were exposed to 0.01, 0.12, 1, 10, 100, 1,000, and 5,000ppm of $SO_2$ for 24 hours and the optical, physical, chemical deterioration rates both before and after testing were evaluated. The results showed optical deterioration, a loss of gloss on silver specimen with $SO_2$ 100ppm, an increase of color difference on brass, iron, copper and lead specimens with $SO_2$ 5,000ppm, as well as physical changes such as an increase of thickness and corrosion rate on iron sample with $SO_2$ 5,000ppm. In the case of chemical changes such as an increase sulfate ion ($SO{_4}^{2-}$) concentration and decrease of pH on iron and brass specimens were identified. These results suggest that $SO_2$ 100ppm caused clear optical deterioration on some metals such as silver and physicochemical and optical deterioration were identified at $SO_2$ 5,000ppm regardless of metal type. Also, It was concluded that iron and brass are the most susceptible of the metal specimens to $SO_2$.

Evaluation of Ozone Resistance and Anti-Corrosion Performance of Water Treatment Concrete according to Types of Metal Spray Coating (수처리시설용 콘크리트의 금속용사 피막 종류에 따른 내오존성 및 전기화학적 방식 성능 평가)

  • Park, Jin-Ho;Choi, Hyun-Jun;Lee, Han-Seung;Kim, Sang-yeol;Jang, Hyun-O
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.23 no.4
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    • pp.61-68
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    • 2019
  • As the pollution of water resources deteriorates due to industrialization and urbanization, it is difficult to supply clean water through a water treatment method using chlorine. Therefore, the introduction of advanced water treatment facilities using ozone is on the increase. However, epoxy which is used as waterproofing and anticorrosives and stainless steel used in conventional waterproofing and anti-corrosive methods have deteriorated because of the strong oxidizing power of ozone, causing problems such as leaking. Moreover, it even causes the durability degradation of a concrete. Therefore, in this study, metal spraying system was used as the means of constructing a metal panel with excellent ozone resistance and chemical resistance which is an easier method than an existing construction method. Ozone resistance was evaluated in accordance with the type of metal sprayed coatings to develop a finishing method which can prevent the concrete structure of water treatment facilities from deterioration. Furthermore, electrochemical stability in actual sewage treatment plant environment was evaluated. Experimental results showed that Ti has superior ozone resistance after spraying and the electrochemical stability in the sewage treatment plant environment showed that Ti has the highest polarization resistance of $403.83k{\cdot}{\Omega}{\cdot}cm^2$, which ensures high levels of durability.

Estimation of Structural Safety for PolyEthylene (PE) Floating Platforms with API & AISC Standards (API & AISC 기준을 적용한 PolyEthylene (PE) 부유식 플랫폼의 구조 안전성 검토)

  • Seo, Kwang-Cheol;Nam, Taek-Kun;Park, Joo-Shin
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.25 no.2
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    • pp.237-243
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    • 2019
  • Floating platforms made of PE (PolyEthylene) are often located in shallows of seas, rivers or lakes. They are widely used for marine pensions, marine pontoons, marine bridges, etc. These products are characterized by good flexibility, recyclability, chemical resistance and weatherability with corrosion resistance. Existing PE floating platforms have a simple structure in which one pipe is fastened to one bracket, but this has limited application, even if a user modifies the arrangement. Therefore, we developed a structure that allows buoyancy pipes of various sizes to be fastened to one bracket and verified the structural safety of the product using the finite element method. From the results of structural analysis for buoyancy pipes of different diameters, the maximum stress ratio was 0.78 compared with allowable criteria of 1.0, which represented sufficient safety for a model with 500 mm diameter pipes. Based on the results of this study, further research to evaluate the structural safety of various floating platforms can be carried out in the further; it will also be necessary to establish related evaluation criteria.

Strength and Durability Characteristics of Low-alkali Mortar for Artificial Reefs Produced by 3D Printers (인공어초 3D 프린터 출력을 위한 저알칼리 모르타르의 강도와 내구성능)

  • Lee, Byung-Jae;Kim, Bong-Kyun;Kim, Yun-Yong
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.26 no.1
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    • pp.67-72
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    • 2022
  • Concrete prevents corrosion of reinforcing bars due to its strong alkalinity. However, in the sea, strong alkali components with a pH of 12 to 13 are eluted, which adversely affects the ecological environment and growth of marine organisms. In this study, the mechanical properties and durability of the low alkali mortar were evaluated for the development of a low alkali mortar for the 3D printed artificial reefs. As a result of evaluation of strength characteristics, the α-35 mixture, which were produced with fly ash, silica fume and α-hemihydrate gypsum, satisfied the strength requirement 27 MPa in terms of compressive strength. As a result of pH measurement, it was found that mixing with alpha-type hemihydrate gypsum resulted in minimizing pH due to the the formation of calcium sulfate instead of calcium hydroxide production. As a result of the chloride ion penetration resistance test, the α-35 mixture exhibited the best performance, 3844C. As a result of measuring the length change over time, the α-35 mixture showed the shrinkage 33.5% less compared to the Plain mix.

Characteristics of defect on segmental lining of TBM tunnel in operational subway (운용중인 국내 지하철 TBM터널의 세그먼트라이닝 결함특성 분석)

  • Choo, Jinho;Lee, DongHun;Noh, EunChul
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.24 no.1
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    • pp.109-128
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    • 2022
  • The precise inspection for safety and diagnosis (PISD) of tunnel has been conducted by the special act on safety control of public structures. However, the present assessment for the segmental lining of TBM tunnel has limitation such as: NDTs for integrity, segmental configuration for field inspection, and consideration for jacking system. Even if the number of TBM tunnel is less than 1% of enrolled facility in FMS, more attention to maintenance should be necessary due to its usage such as multi-use facility and national important facility. Compared to NATM tunnel, excavated by drilling and blasting and then installed lining by cast-in-place within 6~12 m, TBM tunnel is cut out ground by disk and cutter-bit and then assembled 7 pieces of precast segment, 1.2~1.4 m wide. Different features of design, construction, and maintenance should be considered to be more exact evaluation of TBM tunnel. The characteristics of defect is categorized and analyzed with 11 operational TBM tunnels in domestic subway. To be more comprehend various particular defects, foreign studies have been also adapted. Crack and leakage are categorized in 7 patterns. Breakage/spalling and corrosion are also grouped into 3 patterns. Patterned defects or damages are fed back in design, construction, and are useful guidelines for maintenance stage in future.

Evaluation of Chloride Extraction under Electrochemical Chloride Extraction (전기화학적 염화물 추출법에 따른 염소이온 제거 성능 평가)

  • Jiseok, Kim;Ki-Yong, Ann
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.10 no.4
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    • pp.553-557
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    • 2022
  • The present study evaluate the chloride extracion under electrochemical chloride extraction method. Chloride was penetrated into the concrete from external reservoir using a 4M NaCl solution, and an electrochemical chloride extraction method was applied after the curing period of 1 year. The current density was constantly kept 1000 mA/m2 for coulostatic application with the variation in potential difference. The duration of the ECE treatment was 2, 4, 8 weeks, respectively. The residual chloride concentration at all depths decreased, and the chloride concentration decreased as the application period increased. After the application period of 8 weeks, 62.9 to 77.6 % of chloride extracted in the total chloride profile, and 77.7 to 99.5 % of chloride extracted in the free chloride profile. In particular, the concentration of free chloride at a depth of 7 mm or more from the concrete surface was 0.01 % or less by cement. In addition, it was confirmed that the bound chloride could be extracted by the electrochemical chloride extraction.

The Case Study of Design on Steel Pipe Sheet Pile for Earth Retaining Wall on Deep Excavation (대심도 지반굴착을 위한 벽강관말뚝 흙막이공법의 설계 사례 연구)

  • Byung-Il Kim;Jong-Ku Lee;Kyoung-Tae Kim;Kang-Han Hong;Sang-Jae Han
    • Journal of the Korean Geosynthetics Society
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    • v.22 no.1
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    • pp.53-66
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    • 2023
  • In this study, the results of the elasto-plastic beam analysis, finite element analysis and optimization design of the steel pipe sheet pile applied as an earth retaining wall under the deep excavation were presented. Through this study, it was found that the high-strength and sea resistant steel pipe has high allowable stress, excellent structural properties, favorable corrosion, and high utilization as an earth retaining wall, and the C-Y type joint has significantly improved the tensile strength and stiffness compared to the traditional P-P type. In addition, it was investigated that even if the leak or defect of the wall occurs during construction, it has the advantage of being able to be repaired reliably through welding and overlapping. In the case of steel pipe wall, they were evaluated as the best in views of the deep excavation due to the large allowable bending stress and deformation flexibility for the same horizontal displacement than CIP or slurry wall. Elasto-plastic and finite element analysis were conducted in consideration of ground excavation under large-scale earth pressure (uneven pressure), and the results were compared with each other. Quantitative maximum value were found to be similar between the two methods for each item, such as excavation behavior, wall displacement, or member force, and both analysis method were found to be applicable in design for steel pipe sheet pile wall. Finally, it was found that economical design was possible when determining the thinnest filling method with concrete rather than the thickest hollow shape in the same diameter, and the depth (the embedded length through normality evaluation) without rapidly change in displacement and member force.

Uplift Capacity for Bond Type Anchored Foundations in Rock Masses (부착형 암반앵커기초의 인발지지력 평가)

  • Kim, Dae-Hong;Lee, Yong-Hee
    • Journal of the Korean Geotechnical Society
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    • v.24 no.10
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    • pp.147-160
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    • 2008
  • This paper presents the results of full-scale loading tests performed on 54 passive anchors and 4 group anchored footings grouted to various lengths at several sites in Korea. The test results, the failure mechanisms as well as uplift capacities of rock anchors depend mostly on rock type and quality, embedded fixed length, properties of the discontinuities, and the strength of rebar. Anchors in poor quality rocks generally fail along the grout/rock interfaces when their depths are very shallow (a fixed length of less than 1 m). However, even in such poor rocks, we can induce a more favorable mode of rock pull-up failure by increasing the fixed length of the anchors. On the other hand, anchors in good quality rocks show rock pull-up failures with high uplift resistance even when they are embedded at a shallow depth. Laboratory test results revealed that a form of progressive failure usually occurs starting near the upper surface of the grout, and then progresses downward. The ultimate tendon-grout bond strength was measured from $18{\sim}25%$ of unconfined compressive strength of grout. One of the important findings from these tests is that the measured strains along the corrosion protection sheath were so small that practically the reduction of bond strength by the presence of sheath would be negligible. Based on test results, the main parameters governing the uplift capacity of the rock anchor system were determined. By evaluation of the ultimate uplift capacity of anchor foundations in a wide range of in situ rock masses, rock classification suitable for a transmission tower foundation was developed. Finally, a very simple and economical design procedure is proposed for rock anchor foundations subjected to uplift tensile loads.

Interpretation of Making Techniques through Surface Characteristic Analysis and Non-destructive Diagnosis for the Gilt-bronze Seated Buddha in Dangjin Sinamsa Temple, Korea (당진 신암사 금동여래좌상의 표면특성 분석과 비파괴 정밀진단을 통한 제작기술 해석)

  • CHOI Ilkyu ;YANG Hyeri ;HAN Duru;LEE Chan Hee
    • Korean Journal of Heritage: History & Science
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    • v.56 no.1
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    • pp.100-116
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    • 2023
  • The Sinamsa Temple was built in the late Goryeo Dynasty and a gilt-bronze seated Buddha is enshrined in Geungnakjeon hall in the precinct. Various damages occurred in the gilt layer of the Buddha, such as peeling of the gilt layer and deteriorating gloss. In the study, the conservation conditions of the inside and outside on the statue were accurately investigated, and the making technique was interpreted through the material characteristics and non-destructive diagnosis of the statue. As a result, it is estimated that gold-gilding layer is pure gold, coloration pigment of black is carbon, green is malachite, atacamite and verdigris, red is red lead and cinnabar, respectively. In the deterioration evaluation, peeling, cracking, break out and exfoliation of the gilt layer are confirmed as damages, but the conservation condition is relatively wholesome. However, the gloss of the gilt layer is calculated to be wider in the poorer part than the maintenance part. The ultrasonic velocity of the statue was calculated to be 1,230 to 3,987 (mean 2,608) m/s and showed a relatively wide range. In infrared thermography, peeling was not confirmed, and no special bonding marks were found. In endoscope, some biological damage and corrosion were observed on the surface of the internal metal, and sealed artifacts were identified. Manufacturing technique based on the study, it is considered that the gilt-bronze seated Buddha was cast at once, and the mold was inverted to inject molten metal.

Evaluation of Physical Properties and Material Characterization for Structural Frame at the Stained Glass Windows to Gongju Jeil Church of the Registered Cultural Heritage in Korea (국가등록문화재 공주제일교회 스테인드글라스 구조재의 재질특성과 물성 평가)

  • Bo Young Park;Hye Ri Yang;Chan Hee Lee
    • Economic and Environmental Geology
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    • v.56 no.1
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    • pp.103-114
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    • 2023
  • The Christian Museum of Gongju Jeil Church was first built in 1931 and was largely damaged during the Korean War, but the walls and chimneys have been preserved. This building has a high architectural values in that the chapel was reconstructed in 1956, and maintains its original form through repair of damaged parts rather than new construction. The stained glass windows were as installed in 1979 and has a great significance in the Dalle de Verre method using lump glass. However, some of the stained glass damaged partially, such as various cracks and splits, and vertical and horizontal cracks in the joint fillers of supporting the colored glass. As the structural materials of the stained glass window, an iron frame and cement mortar filled with it were used, and corrosion of iron, cracking of mortar and granular decomposition appear partially due to weathering. In the joint fillers, the content of Ca and S is very high, indicating that gypsum were used as admixtures, and the gypsums grow in a rhombohedral and forms a bundle, which is investigated to have undergone recrystallization. As a result of modeling the ultrasonic velocity at the joint fillers, the left and right windows at the entrance show relatively weak in the range of 800 to 1,600m/s, and the lower right corner of the altar window and the upper left corner of the center window were also 1,000 to 1,800m/s, showing relatively low physical properties. And gypsums produced during the neutralization of lime mortar were detected in the joint fillers and contaminants on the surface. Such salts may cause damage to the joint material due to freezing and thawing, so appropriate preventive conservation is required. Also, since various damage types are complexly appearing in stained glass window and joint filler, customized conservation treatment should be reviewed through clinical tests.