• 제목/요약/키워드: corrosion current

검색결과 1,103건 처리시간 0.03초

Monitoring Cathodic Shielding and Corrosion under Disbonded Coatings

  • Varela, F.;Tan, M. YJ;Hinton, B.;Forsyth, M.
    • Corrosion Science and Technology
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    • 제16권3호
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    • pp.109-114
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    • 2017
  • Monitoring of corrosion is in most cases based on simulation of environmental conditions on a large and complex structure such as a buried pipeline using a small probe, and the measurement of thermodynamics and kinetics of corrosion processes occurring on the probe surface. This paper presents a hybrid corrosion monitoring probe designed for simulating deteriorating conditions wrought by disbonded coatings and for measuring current densities and distribution of such densities on a simulated pipeline surface. The concept of the probe was experimentally evaluated using immersion tests under cathodic protection (CP) in high resistivity aqueous solution. Underneath the disbonded area, anodic currents and cathodic currents were carefully measured. Anodic current densities were used to calculate metal loss according to Faraday's law. Calculated corrosion patterns were compared with corrosion damage observed at the surface of the probe after a series of stringent tests. The capability of the probe to measure anodic current densities under CP, without requiring interruption, was demonstrated in high resistivity aqueous solution. The pattern of calculated metal loss correlated well with corrosion products distribution observed at the array surface. Working principles of the probe are explained in terms of electrochemistry.

철근콘크리트 보의 철근부식에 미치는 하중의 영향에 관한 연구 (Influence of Loading on the Corrosion of Reinforcing Bar)

  • 김형래;윤상천;지남용
    • 콘크리트학회논문집
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    • 제11권3호
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    • pp.171-179
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    • 1999
  • The present research investigated the interaction among loading level, corrosion rate and flexural deflection of reinforced concrete beams. 10cm$\times$15cm$\times$110cm reinforced concrete beams were prepared and subjected to different levels of flexural loading, including 0%, 45% and 75% of the ultimate load. The beams with either a pre-load or a sustained load were also exposed to a laboratory environment with ponding and wetting/drying cycling at room temperature. Half cell potential and galvanized current measurements were taken to monitor corrosion process of reinforcing steel. After corrosion initiation, external current was applied to some of the beams to accelerate corrosion propagation. The beam deflections were recorded during the entire tests. The results indicate that loading level has significant effect on corrosion rate. The beams under a sustained load had much higher corrosion rate than the pre-loaded and then unloaded beams. Significant corrosion may result in an increase in beam deflection and affect serviceability of the structure. The present research may provide an insight into structural condition evaluation and service life predictions of reinforced concrete.

선박의 해양 부식과 부식방지 장치 (Apparatus on Corrosion Protection and Marine Corrosion of Ship)

  • 김성종
    • 한국표면공학회지
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    • 제44권3호
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    • pp.105-116
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    • 2011
  • Ships and offshore structures are exposed to harsh marine environments, and maintenance and repair are becoming increasingly important to the industry and the economy. The major corrosion phenomenons of metals and alloys in marine environment are pitting corrosion, stress corrosion cracking, crevice corrosion, fatigue corrosion, cavitation-erosion and etc. due to the effect of chloride ions and is quite serious. Methods of protection against corrosion can generally be divided into two groups: anodic protection and cathodic protection. Anodic protection is limited to the passivity characteristics of a material in its environment, while cathodic protection can apply methods such as sacrificial anode cathodic protection and impressed current cathodic protection. Sacrificial anode methods using Al and Zn alloys are widely used for marine structures and vessels intended for use in seawater. Impressed current cathodic protection methods are also widely used in marine environments, but tend to generate problems related to hydrogen embrittlement caused by hydrogen gas generation. Therefore, it is important to the proper maintenance and operation of the various corrosion protection systems for ship in the harsh marine environment.

촉진부식실험을 이용한 OPC 및 슬래그 콘크리트의 부식-부착강도 평가 (Corrosion-bond Strength Evaluation in OPC and Slag Concrete using Accelerated Corrosion Test)

  • 오상진;이현우;권성준
    • 한국건설순환자원학회논문집
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    • 제12권1호
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    • pp.1-7
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    • 2024
  • 다공성인 콘크리트에서는 외부의 수분 및 염화물 유입이 발생하며, 이는 매립된 철근의 부식을 야기한다. 본 연구에서는 촉진부식실험(ICM: Impressed Current Method)를 이용하여 10 V의 전압을 인가하였으며, 이에 따라 10 % 수준까지 부식량을 조절하였다. 부식량은 부식전류량 누계와 선형적인 관계가 도출되었으며, 균열의 영향으로 부식 유도 시간에 따라 2차 함수의 형태로 증가하였다. 부착응력에 대해서는 OPC 콘크리트에 대해서는 부식량 3.0 % 이후 급격한 부착응력의 감소가 발생하였다. 또한 치환률 30 %의 슬래그 콘크리트에서는 일반 콘크리트에 비하여 51.4~71.6 %의 낮은 부식량을 나타내었으며 5일간의 촉진실험에도 일정 수준의 부착강도를 유지하였다.

Affecting of Corrosion Potential and Current Density on Variation Polarization Curves with Polyvinylchloride (I)

  • Choi, Chil-Nam;Yang, Hyo-Kyung;Jung, Oh-Jin
    • Environmental Sciences Bulletin of The Korean Environmental Sciences Society
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    • 제2권2호
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    • pp.91-98
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    • 1998
  • In this study, we carried out the experiments for measuring the variations of corrosion potential and current density for polarization curves with polyvinylchloride. The results exhibited especially the influence affecting the corrosion potential and various conditions (temperature, day, pH, bacteria, and added salt). The second anodic current density peak and the minimum passive current density are designated $I_P/I_0,$ respectively. The value of $I_P/I_O$ is used as a measurement for the extent of degradation of the polyvinylchloride. The potentiodpnamics parameters of the corrosion were obtained using Tafel equation.

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Redox Reaction of Poly(ethyleneterephthalate) Polymer in Aprotic Solvent

  • Choi, Chil-Nami
    • Environmental Sciences Bulletin of The Korean Environmental Sciences Society
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    • 제10권S_1호
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    • pp.47-53
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    • 2001
  • We carroed our to measure the variations of potential with current density (polarization curves) for poly(ethyleneterephthalate). The results were particularly examined to identify the influences on corrosion potential and corrosion rate of various factors including temperature, pH, exposure time, salt, and enzyme. The Tafel slope for anodic dissolution was determined by the polarization effect depending on these conditions. The optimum conditions were established for each case. The second anodic current density peak and maximum passive current density were designated as the relative corrosion sensitivity$(I_r/I_f)$. The mass transfer coefficient value$(\alpha)$ was determined with the Tafel slope for anodic dissolution based on the polarization effect with optimum conditions.

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전선 부식에 따른 와전류특성 조사 (A Study of Eddy Current Characteristics which Follows in the Corrosion of Power line)

  • 오용철;정한석;이재봉;임주혁;손기정;김진사;김충혁
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2010년도 하계학술대회 논문집
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    • pp.77-77
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    • 2010
  • We used eddy current sensor for diagnosis of power line. The power line according to the cross section has 6~18 element wires. The corrosion of power line was made by sodium hydroxide. The corrosion time of power line was from 18 hours to 27 hours. We obtained physical characteristics from tensile and torsion tests of power line. The eddy current Characteristics of power line according to the corrosion appeared change of amplitude 200 ~ 800 mV.

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해양환경 하에서 동합금의 캐비테이션-부식손상 방지를 위한 방식정전류 기법 연구 (Investigation on Galvanostatic Method to Protect Cavitation-corrosion Damage for Cu Alloy in Sea Water)

  • 박재철;김성종
    • 한국표면공학회지
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    • 제45권1호
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    • pp.25-30
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    • 2012
  • The galvanostatic tests for corrosion protection are conducted at various applied current densities during 93,600 sec, and evaluated in terms of the variations in current density with time and in the potential at the applied current density. In addition, the corrosion damage depth is analyzed with 3D analysis optical microscope after galvanostatic tests. In this study, it was investigated to decide condition of the corrosion protection gavalnostatic method for Cu-Al alloy that has an excellent corrosion resistance. In the galvanostatic test under the cavitation environment, the energy was reflected or cancelled out by the collision with the oxygen gas generated by the oxygen reduction action. The surface observation showed neither the cavitation damage nor the electrochemical damage in the current density over 0.01 $A/cm^2$ in the dynamic state under the cavitation environment.

콘크리트 중의 철근부식 방지를 위한 외부전원법의 적용 (The Application of Impressed Current System for the Corrosion Control of Reinforcing Steel in Concrete)

  • 문한영;김성수;김홍삼
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 1997년도 봄 학술발표회 논문집
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    • pp.197-202
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    • 1997
  • Recently the interest in the reinforcing steel corrosion due to the use of sea-sand and deicing salt, marine environment, and carbonation in RC structures is increasing, therefore the studies on the corrosion control of reinforcing steel in concrete are vigorously proceeding. In this study, from the viewpoint of electrochemical process of steel corrosion in concrete we applied the impressed current system among the cathodic protections to reinforcing steel in concrete and ascertained the protection effect by half-cell potential, corrosion rate, and depolarization.

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Prediction of steel corrosion in magnesium cement concrete based on two dimensional Copula function

  • Feng, Qiong;Qiao, Hongxia;Wang, Penghui;Gong, Wei
    • Computers and Concrete
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    • 제21권2호
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    • pp.181-187
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    • 2018
  • In order to solve the life prediction problem of damaged coating steel bar in magnesium cement concrete, this study tries to establish the marginal distribution function by using the corrosion current density as a single degradation factor. Representing the degree of steel corrosion, the corrosion current density were tested in electrochemical workstation. Then based on the Copula function, the joint distribution function of the damaged coating was established. Therefore, it is indicated that the corrosion current density of the bare steel and coated steel bar can be used as the boundary element to establish the marginal distribution function. By using the Frank-Copula function of Copula Archimedean function family, the joint distribution function of the damaged coating steel bar was successfully established. Finally, the life of the damaged coating steel bar has been lost in 7320d. As a new method for the corrosion of steel bar under the multi-dimensional factors, the two-dimensional Copula function has certain practical significance by putting forward some new ideas.