• 제목/요약/키워드: corrosion current

검색결과 1,103건 처리시간 0.033초

Elucidation of the Noise in Corrosion of Aluminum Foil

  • Chiba, Atsushi;Hattori, Atsushi;Wu, Weng-Chang
    • Corrosion Science and Technology
    • /
    • 제3권3호
    • /
    • pp.102-106
    • /
    • 2004
  • Al foil used was 99.9 and 99.99 %. Test solution used was NaCl solution. The noise was determined using controlled potential electrolysis at -200 and -700 mV vs. NHE. The current fluctuation was caused by breakdown and repaired process of aluminum oxide film. The current fluctuation value of noise was proportion to degree of growth. The number of noise was proportion to the number of pit. The examining of current flutulation value and number of noise could be evaluated corrosion. A 99.99 % Al foil was the mostly crystal of {100} plane, and showed three-dimensional, as azimuth pit with along the direction of this place piled up. A 99.9 % Al foil was polycrystal, and in order of (311) >(222) >(200) >(111) plane. The azimuth pit did not occurred as the dissolution was occurred from each plane.

교류 임피던스기법을 이용한 철근부식 측정에 관한 실험적 연구 (Electrical Impedance Spectroscopy(EIS) Measurements to Evaluate Corrosion of Steel/Concrete System)

  • 정시영;김병국;최완철
    • 한국콘크리트학회:학술대회논문집
    • /
    • 한국콘크리트학회 2005년도 추계 학술발표회 제17권2호
    • /
    • pp.659-662
    • /
    • 2005
  • Electrochemical impedance spectroscopy (EIS) has been extensively used to try to evaluate the corrosion state of the steel/concrete system. This technique is attractive because, in theory, used in a wide range of frequencies, it can give detailed information about the mechanisms and kinetics of the electrochemical reactions. Impedance measurements were performed using potential control and measuring the corresponding current response. One-year-old southern exposure test. specimens were used in the current study. The effectiveness of corrosion inhibiting additives was evaluated. The corrosion current densities estimated by impedance measurements were confirmed by those determined using linear polarization techniques. The purpose of this study was to evaluate the long-term-performance potential of the corrosion inhibitors in chloride contaminated reinforce concrete.

  • PDF

온도변화에 따른 AISI 304SS의 틈내 전위강하에 관한 연구 (A Study on the IR Drop in Crevice of AISI 304 Stainless Steel by Temperature Variation)

  • 나은영
    • Journal of Advanced Marine Engineering and Technology
    • /
    • 제27권7호
    • /
    • pp.872-878
    • /
    • 2003
  • As the results of recent industrial development, many industrial plants and marine structures are exposed to severe corrosion environment than before. Especially, under the wet environment, crevice corrosion damage problems necessarily occur and encourage many interests to prevent them. In this study, the electrochemical polarization test was carried out to study characteristics of crevice corrosion for AISI 304 stainless steel in various solution temperatures. The results are as follows ; 1) as the solution temperature increased in IN $\textrm{H}_2\textrm{SO}_4$, the passive current density and critical current density were increased, whereas corrosion potential and break down potential were nearly constant, 2) as the solution temperature increased. the induced time for initiation of crevice corrosion was shortened. 3) The potential range in the crevice was -220mV/SCE to -380mV/SCE according to the distance from the crevice opening, which is lower than that of external surface of -200mV/SCE.

선박재료용 SS400강의 내식성에 대한 용접후열처리효과에 관한 전기화학적 연구(I) (A Electrochemical Study on the Effect of Post-Weld Heat Treatment about Corrosion Resistance Property of SS400 Steel for Ship's Materials)

  • 김진경
    • Journal of Advanced Marine Engineering and Technology
    • /
    • 제23권6호
    • /
    • pp.806-813
    • /
    • 1999
  • The effect of Post-Weld Heat Treatment(PWHT) of SS400 Steel was investigated with parameters such as micro vickers hardness corrosion potential polarization behaviors galvanic current Al anode generating current Al anode weight loss etc. Hardness of each parts(HAZ, BM, WM)by PWHT is lower than that of each parts by Non Post-Weld Heat Treatment(NPWHT) However hardness of WM of HAZ part was the highest among those three parts and HAZ area were also acted as cathode without any case of heat treatment. Potential difference between each three parts by PWHT was also smaller compared to NPWHT. Therefore it is suggested that Corrosion resistance property is increased by PWHT. However both Al anode generating current and anode weight loss was also decreased by PWHT compared to NPWHT when SS400 steel is cathodically protected by Al anode.

  • PDF

The Enhancement of Corrosion Resistance for WC-Co by Ion Beam Mixed Silicon Carbide Coating

  • 여순목;김동진;박재원
    • 한국진공학회:학술대회논문집
    • /
    • 한국진공학회 2010년도 제39회 하계학술대회 초록집
    • /
    • pp.101-101
    • /
    • 2010
  • A strong adhesion of a silicon carbide (SiC) coating on a WC-Co substrate was achieved through an ion beam mixing technique and the corrosion resistance of the SiC coated WC-Co was investigated by means of a potentiodynamic electrochemical test. In the case of 1 M NaOH solution, a corrosion current density for a SiC coated WC-Co with a heat treatment at $500^{\circ}C$ displays about 50 times lower than that for the as-received WC-Co. However, in the case of 0.5 M H2SO4 solution, a corrosion current density for a SiC coated WC-Co displays about 3 times lower than that for as-received WC-Co. We discussed the physical reasons for the changes of the corrosion current densities at the different electrolytes.

  • PDF

크롬계 이중도금층 제조 및 특성평가 (Fabrication of Chromium-based Double Layered Deposit)

  • 박상언;김동수;김만;장도연;권식철
    • 연구논문집
    • /
    • 통권31호
    • /
    • pp.127-133
    • /
    • 2001
  • In chromium electrodeposition, crack is inevitably accompanied by chromium layer. Behavior of crack formation and crack density were different from the plating conditions such as current density, temperature, waveform of applied current and so on. And cracks have an influence on the corrosion resistance of chromium deposit, because corrosion occurs through the network of cracks between deposit and substrate. Therefore, many researches have been achieved in order to remove the cracks in chromium deposit. Formation of double layers, Cr/Cr and Ni/Cr were investigated to increase corrosion resistance of chromium deposit in this study. As pretreatment prior to outer chromium coating, acid pickling and current control method were examined. Cracks in cross-section of each sample were observed with SEM and CASS(Copper modified acetic acid salt spray) test was performed to evaluate corrosion resistance. It was found that corrosion resistance of Cr/Cr and Ni/Cr double layers were superior to Cr or Ni single layer from the results of CASS test.

  • PDF

A Study of Optimizing Cathodic Protection in Comparison of Design Methodologies

  • Choi, Young-Kwan;Choi, Sang-Yule;Shin, Myong-Chul
    • 조명전기설비학회논문지
    • /
    • 제24권11호
    • /
    • pp.23-29
    • /
    • 2010
  • The principal factor determining an optimum design method for cathodic protection is finding the protection current for preventing the corrosion of existing, already laid pipe. Some factors currently used to test designs include the sizes and lengths of pipes, soil resistivity, and the coating damage rate. We believe this method and current formulae are not optimum due to the uncertainty of determining the coating damage rate and the corrosion protection current's density. This paper analyzes the amount of protection current obtained by performing a temporary current test using data describing existing laid pipe. We then propose determining the corrosion protection current by using the temporary current test after modifying the formula. In addition, we suggest a way to choose optimized cathodic protection and the process of design by executing the design and taking account of such factors as a site condition of 34km-long non-protected water supply pipe lines (stages I and II) in ${\bigcirc}{\bigcirc}$ region, climate, interferences, and durability.

직류전기철도시스템에서의 누설전류에 의한 전식방지에 대한 연구 (A study of Protection for electrical corrosion by stray current in DC railway system)

  • 이재영
    • 한국철도학회:학술대회논문집
    • /
    • 한국철도학회 2005년도 추계학술대회 논문집
    • /
    • pp.748-753
    • /
    • 2005
  • The stray current(leakage current) in DC railway system like as Metro Subway and LRT system happens electrical corrosion on theses superstructure facilities and also underground facilities that causes the public property losses. we must study and establish on the theoretical concept and concrete phenomena for electrical corrosion, In the construction period we intend to review and find out a lot of solution to minimize theses losses. we must investigate, measure and analysis natural atmosphere of these facilities locations to present a maintenance management guide for the upcoming operation stage.

  • PDF

이온플레팅시 공정조건이 Ti 및 Ni 중간층을 갖는층을 갖는 TiN 박막의 내식성에 미치는 영향에 관한 연구 (A study on the effect of process parameters on the corrosion resistance of ion plated Tin films with Ti and Ni interlayers.)

  • 하희성;이종민;이인행;이정중
    • 한국표면공학회지
    • /
    • 제30권1호
    • /
    • pp.33-43
    • /
    • 1997
  • The effects of process parameters substrate such as substrate current and substrate temperature on the corrosion resistance of ion plated TiN film were investigated. TiN fims were deposited on speed steel on which Ti or Ni hed been previously evaporated. Dense TiN films could be obtained under higher substrate current(1A) and substrate temperature($500^{\circ}C$), whereas TiN films deposited with lower substances current(0.5A) and substrate temperature($300^{\circ}C$) showed porous structure. The corrosion resistances of high speed steel was considerably increased when dense TiN films had been formed on it. The effect of Ti and Ni interlayer on the increase of the corrosion resistance was also significant with dense TiN films, while there was little effect of interlayer on the corrosion resistance when TiN films were porous. the effect of interlayer on the corrosion resistance was more outstanding with Ti then with Ni, because Ti reacts more easily with oxygen to form an oxide layer, and it also shows higher resistance against chlorine containing corrosion media.

  • PDF

Galvanic Corrosion of Zn/Steel Couple in Aqueous MgCl2

  • Tada, E.;Katakami, S.;Nishikata, A.
    • Corrosion Science and Technology
    • /
    • 제16권4호
    • /
    • pp.183-186
    • /
    • 2017
  • Galvanic corrosion tests of Zn/steel couples were conducted in 1 M NaCl and $1M\;MgCl_2$ solutions to investigate the impact of magnesium ion on corrosion behavior of the couples. Two types of Zn/steel couples were used for measurements of open circuit potential (OCP) and galvanic current. From the results of OCP transient of Zn/steel couples, the corrosion potential in $1M\;MgCl_2$ was a more positive value than that in 1 M NaCl during the sacrificial dissolution of Zn. However, earlier increase of OCP of the couples in $1M\;MgCl_2$ solution indicates that the sacrificial dissolution rate of Zn in $1M\;MgCl_2$ was enhanced more than that in 1 M NaCl, agreeing with the results on transients of galvanic current. This result is due to that cathodic reaction on the steel surface of the Zn/steel couple was enhanced in $1M\;MgCl_2$ by the occurrence of hydrogen evolution reaction.