• Title/Summary/Keyword: corrosion behaviour

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A Comparison of Corrosion Performance of Zirconium Grain Refined MEZ and AZ91 Alloys

  • Song, Guangling;StJohn, David
    • Corrosion Science and Technology
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    • v.2 no.1
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    • pp.30-35
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    • 2003
  • In this study, sand cast AZ91E and zirconium grain refined MEZ are representative of two typical groups of magnesium alloys: those containing aluminium and those containing no aluminium but with zirconium as a grain refiner. The corrosion performance of these two alloys was evaluated and compared in 5%wt NaCI solution through measurements of weight loss and polarisation curves and examination of microstructure. Corrosion damage of AZ91E was deeper and more localised than that of MEZ, while MEZ had a lower rate of cathodic hydrogen evolution and a higher rate of anodic dissolution than AZ91E. These differences in behaviour can be related to the differences in microstructure and chemical composition between the two alloys.

A study on the mechanism of stress corrosion cracking of stainless steel (스테인레스 강판의 응력부식균열 전파기구에 관한 연구)

  • 임우조;김영식
    • Journal of Advanced Marine Engineering and Technology
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    • v.9 no.2
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    • pp.153-158
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    • 1985
  • The dependence of the corrosion potential on the stress corrosion cracking of 304 austenitic stainless steel was inspected by using the specimen of constant displacement type under the environment of 42% $MgCl_2$ boiled solution. The relationship of the corrosion potential to the intermittent propagation behaviour in stress corrosion cracking was cleared. As the results, a possible model of stress corrosion cracking of 304 austenitic stainless steel in $MgCl_2$ boiled solution was presented on the basis of the Film Rupture Model. This model is specified by the following process. Rupturing of passive film at notch tip .rarw. Dissolution of metal ion and formation of tunnel .rarw. Initiation of microcrack .rarw. Propagation of main crack .rarw. Recreation of passive film at new crack surface.

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Influence of Retrogression and Re-aging on the Exfoliation Corrosion Behavior of AA 7085 Sheets

  • Krishnan, Ajay;Raja, V.S.;Mukhopadhyay, A.K.
    • Corrosion Science and Technology
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    • v.15 no.4
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    • pp.159-165
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    • 2016
  • An attempt has been made to understand the influence of retrogression and re-aging (RRA) on the exfoliation corrosion behaviour of AA 7085 alloy in comparison with the peak aged condition (PA). Immersion tests using ASTM G34 and studies involving electrochemical impedance spectroscopy showed that the RRA treated alloy provided higher resistance to exfoliation corrosion than the PA treated alloy. The improved resistance was attributed to the enhanced Cu content and the discontinuous nature of the grain boundary precipitate, which was revealed through transmission electron microscopy.

Assessment of the Corrosion Behavior of a Sintered Al-Cu-Mg Alloy in Aeronautical Environments as a Function of the Heat Treatment

  • Sanchez-Majado, S.;Torralba, J. M.;Jimenez-Morales, A.
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09a
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    • pp.549-550
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    • 2006
  • The corrosion performance of a powder metallurgical aluminum alloy in aeronautical environments was studied for both as sintered and heat treated states. Sintered samples were obtained by uniaxial pressing of an Al-Cu-Mg prealloyed powder followed by liquid phase sintering. The heat treatments applied were T4 and T6. Corrosion behaviour was assessed by means of potentiodynamic polarization. Results for the equivalent commercial wrought counterpart, AA2024-T3, are also presented for comparison. Similar corrosion performance was observed for both as sintered and AA2024-T3 samples, while corrosion resistance of the PM materials was improved by the heat treatment, especially in the T4 state.

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Behaviour of the Fretting Wear and Corrosion Characteristics on a Hinge Material (힌지재료의 부식특성 및 찰과마멸 거동)

  • Kwak Nam-In;Lim Uh-Joh;Lee Jong-Rark
    • Journal of the Korean Institute of Gas
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    • v.3 no.3 s.8
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    • pp.39-44
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    • 1999
  • In the study, corrosion characteristics under various corrosion environments(neutral solution, acid solution), for various hinge materials(SM20C, BsC3 and STC4H), were investigated by immersion test, and the behaviour of fretting wear under atmosphere was studied. In immersion test, corrosion potential of those materials showed to be noble in the sequence of $0.5\%HNO_3$> underground water> $0.5\%\;H_2SO_4$ solution, and potential of a sole material, except BsC3, was more noble than these of mixed materials. In same material SM20C, the fretting wear loss of rotary materials increased about 1.9 times to that of moving materials, because of surface hardening by frictional force.

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The influence of EAF dust on resistivity of concrete and corrosion of steel bars embedded in concrete

  • Almutlaq, Fahad M.
    • Advances in concrete construction
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    • v.2 no.3
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    • pp.163-176
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    • 2014
  • Essentially, when electrical current flows easily in concrete that has large pores filled with highly connective pore water, this is an indication of a low resistivity concrete. In concrete, the flow of current between anodic and cathodic sites on a steel reinforcing bar surface is regulated by the concrete electrical resistance. Therefore, deterioration of any existing reinforced concrete structure due to corrosion of reinforcement steel bar is governed, to some extent, by resistivity of concrete. Resistivity of concrete can be improved by using SCMs and thus increases the concrete electrical resistance and the ability of concrete to resist chloride ingress and/or oxygen penetration resulting in prolonging the onset of corrosion. After depassivation it may slow down the corrosion rate of the steel bar. This indicates the need for further study of the effect of electric arc furnace dust (EAFD) addition on the concrete resistivity. In this study, concrete specimens rather than mortars were cast with different additions of EAFD to verify the electrochemical results obtained and to try to understand the role of EAFD addition in influencing the corrosion behaviour of reinforcing steel bar embedded in concrete and its relation to the resistivity of concrete. The results of these investigations indicated that the corrosion resistance of steel bars embedded in concrete containing EAFD was improved, which may link to the high resistivity found in EAFD-concrete. In this paper, potential measurements, corrosion rates, gravimetric corrosion weight results and resistivity measurements will be presented and their relationships will also be discussed in details.

Corrosion Behaviour of Water Pipes (수도관의 부기거동에 관한 연구)

  • 김원만;박영식
    • Journal of environmental and Sanitary engineering
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    • v.7 no.1
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    • pp.1-16
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    • 1992
  • Corrosion of pipes Is one of the most serious problems in the maintenance of water worlds. Corrosion is promoted not only by physical factors such as temperature, but also by electrochemical factors including concentration of soluble metal ions, chlorine ion, pH, DO and microorganisms. Corrosion products also affect corrosion rate. In this research, study results are summarized as follows ; 1) Corrosion test was performed for 4 weeks at $70^{\circ}C$, pH 7.0 with specimens of 4 types of metal materials used as service pipes. Corrosion rate and S.E.M were analyzed. The results were showed that corrosion 1.ate of carbon steel pipe was 4.10~5.22 $mg/\textrm{cm}^2$ . week, galvanized steel pipe 0.98~1.34$mg/\textrm{cm}^2$. week, Copper pipe 0.02~0.04$mg/\textrm{cm}^2$. week, stainless steel pipe 0.05~ 0.10$mg/\textrm{cm}^2$ . week. 2) When corrosion rate was tested for tile types of pipes at pH 7 and both $25^{\circ}C$ and $75^{\circ}C$, avaerage corrosion rate for 6 weeks at $25^{\circ}C$ Ivas 2.26$mg/\textrm{cm}^2$ . week in carbon steel pipe, 1.99$mg/\textrm{cm}^2$. week in galvanized steel pipe, 0.26 $mg/\textrm{cm}^2$. week in stainless steel pipe. At $87^{\circ}C$, average corrosion rate for 4 weeks u.3s 4.56 $mg/\textrm{cm}^2$. week in carbon steel pipe,

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An effective proposal for strength evaluation of steel plates randomly corroded on both sides under uniaxial compression

  • Khedmati, Mohammad Reza;Nouri, Zorareh Hadj Mohammad Esmaeil;Roshanali, Mohammad Mahdi
    • Steel and Composite Structures
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    • v.11 no.3
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    • pp.183-205
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    • 2011
  • This paper presents the results of an investigation into the post-buckling behaviour and ultimate strength of imperfect corroded steel plates used in ship and other marine-related structures. A series of elastic-plastic large deflection finite element analyses is performed on randomly corroded steel plates. The effects of general corrosion on both sides of the plates are introduced into the finite element models using a random thickness surface model. The effects on plate compressive strength as a result of parametric variation of the corroded surface geometry are evaluated. A proposal on the effective thickness is concluded in order to estimate the ultimate strength and explore the post-buckling behaviour of randomly corroded steel plates under uniaxial compression.

Study on Surface Crack Propagation Behaviour of Mild Steel Weldment in Synthetic Sea Water (인공해수중에서 연강 용접부의 표면구열 성장거동)

  • 이종기;정세희
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.14 no.2
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    • pp.492-501
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    • 1990
  • It was known that the fracture incidences of offshore structure were mostly originated from the surface defects. Especially, in the case of the welded structures, since the welded region has some defects and incomplete beads which are apt to behave like the surface cracks, it has been necessary to evaluate the environmental effects on crack growth at HAZ for the design crack growth behaviour at multi-pall HAZ for SWS41 steel under free corrosion and cathodic protection(-0.9V vs Ag/Agcl) conditions. The results are summarized as follows ; (1) Crack growth rate of the as weld in air was faster than that of the parent and PWHT specimens over all .DELTA.K rang. (2) In free corrosion test, surface crack growth rate of the as welded was decreased in comparison with that of the parents. (3) In fatigue test under cathodic protection, cathodic electric potential(-0.9V vs Ag/Agcl) for the SWS41 steel parent was effective, while for the as welded ineffective. (4) There was a tendency that the exponent(m) of the Paris' equation was decreased in order of microhardness magnititude in air and under cathodic protection conditions and vise versa in free corrosion. (5) Fracture surface has dimples and ductile striations in air test, but transgranular cracks and brittle striations under cathodic protection test.

Characteristics of Sulfide Stress Corrosion Cracking of High Strength Pipeline Steel Weld

  • Chang, Woong-Seong;Yoon, Byoung-Hyun;Kweon, Young-Gak
    • Corrosion Science and Technology
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    • v.3 no.2
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    • pp.81-86
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    • 2004
  • The sulfide stress corrosion cracking (SSCC) resistance of API X70 grade steel weldment has been studied using SSCC test in NACE TM-O177 method A. Also, microstructures and hardness distribution of weldment was investigated. The microstructure of SAW joint composed ferrite, pearlite and some MA constituent. Instead of hardening in CGHAZ, softening on the HAZ near base metal occurred. The low carbon TMCP type steel used for SAW showed softening behaviour in the HAZ adjacent to base metal, which was known to be closely related with the SOHIC (stress oriented hydrogen induced cracking). The SSC testing revealed that the API X70 SAW weld was suitable for sour service, satisfying the NACE requirements. By suppressing softening in the ICHAZ region, the SSCC resistance of low carbon TMCP steel welded joints could be more improved.