• Title/Summary/Keyword: corrosion area

Search Result 571, Processing Time 0.03 seconds

A Study on Characteristics of pH Control with Amines in the Secondary Side of Nuclear Power Plants (원전 2차 계통에서 아민의 pH 제어 특성 연구)

  • Rhee, In-H.;Ahn, Hyun-Kyoung;Park, Byung-Gi;Jun, Gwon-Hyuk;Ho, Song-Chan
    • Journal of the Korea Academia-Industrial cooperation Society
    • /
    • v.11 no.8
    • /
    • pp.3112-3118
    • /
    • 2010
  • The pH control agent in PWRs, to insure the integrity of steam generator, was changed from ammonia to ethanolamine(ETA) which decreased pH at condensate system and low pressure feedwater heater drain system, so that several amines were investigated for the selection of the optimum amine. There was no single alternative amine to meet the optimum condition. The more volatile ammonia provides the higher pH in condensate, while the less volatile ETA increases the pH in wet steam area. Thus, the combined amine of ammonia and ETA is able to equally raise the pH in both region so that the flow accelerated corrosion be reduced in the every system of the secondary side and the integrity of steam generator be also improved in pressurized water reactors (PWRs).

A Study on the Evaluation of the Environmental Performance of Salt Damage in Concrete Bridges under Marine Environment (해양 환경하 콘크리트 교량의 염해환경 성능평가 연구)

  • Chai, Won-Kyu;Lee, Myeong-Gu;Son, Young-Hyun;Hong, Sung-Wook
    • Journal of the Korean Society of Safety
    • /
    • v.33 no.5
    • /
    • pp.60-69
    • /
    • 2018
  • This study aims to investigate in the assessment of salt damage conditions in concrete structures under marine environment conditions. It aims also to improve the durability of new concrete bridge through applying the life prediction method of salt damaged bridges. As measuring chloride contents of these bridges on the southwest coastal area, it is shown that the average amount of chloride on these surfaces close to shore is $10.5kg/m^3$. This figure is much higher than that of the Standard Specification for Concrete($1.5kg/m^3{\sim}2.5kg/m^3$). In contrast, it is shown the average amount of chloride on these surfaces in tide zone is $13.1kg/m^3$. Its figure is much lower than that of the Standard Specification for Concrete($20kg/m^3$). And the life of bridges is estimated about 17 years. To improve the durability for salt damage, these bridges are applied to surface treatment method which the replacement rate of furnace slag is 60%. Under this condition, it is expected to be 110 years. Consequently, it is clear that the use of slag replacement rate, surface treatment agent, and anti-corrosion agent to control chloride penetration effects of a submerge-based concrete bridge will be required.

Development of Thermoplastic Carbon Composite Bipolar Plates for High-temperature PEM Fuel Cells (고온 양성자 교환막 연료전지용 열가소성 탄소 복합재료 분리판 개발)

  • Lim, Jun Woo;Kim, Minkook;Lee, Dai Gil
    • Composites Research
    • /
    • v.29 no.5
    • /
    • pp.243-248
    • /
    • 2016
  • Although thermoset carbon fiber composite bipolar plates not only have high mechanical properties but also high corrosion resistance in acid environment, high manufacturing cost and low bulk electrical conductivity are the biggest obstacle to overcome. In this research, thermoplastic polymer is employed for the matrix of carbon composite bipolar plate to increase both the manufacturing productivity and bulk electric conductivity of the bipolar plate. In order to increase the electrical conductivity and strength, plain type carbon fabric rather than chopped or unidirectional fibers is used. Also nano particles are embedded in the thermoplastic matrix to increase the bulk resistance of the bipolar plate. The area specific resistance and the mechanical strength of the developed bipolar plate are measured with respect to the environmental temperature and stack compaction pressure.

Characteristics of Surface Hardening of Dies Steel for Plastic Molding using Continuous Wave Md:YAG Laser (연속파형 Nd:YAG 레이저를 이용한 플라스틱성형용 금형강의 표면경화 특성)

  • Shin, Ho-Jun;Yoo, Young-Tae;Oh, Yong-Seak
    • Journal of the Korean Society for Precision Engineering
    • /
    • v.26 no.1
    • /
    • pp.71-81
    • /
    • 2009
  • Die steel for plastic molding were used as mold material of automobile parts and electronic component industry. The material of this paper has superior to mechanical properties, such as repair weldability, corrosion resistance and high temperature strength, required mold parts for semitransparent. Laser-induced surface hardening technology is widely adopted to improver fatigue life and wear resistance via localized hardening at the surface of mold parts. The objective of this research work is to investigate on the characteristics of surface hardening of the laser process parameters, such as beam travel speed, laser power and defocsued spot position, for the case of die steel for plastic molding. Lens for surface hardening of large area is plano-convex type with elliptical profile to maintain uniform laser irradiation. According to the experimental results, large size of hardened layer at the surface of die steel for plastic molding was achieved, and microstructure of this layer was lath martensite. Optimal surface status and mechanical property of hardened layer could be obtained at 1095Watt, $0.25{\sim}0.3m/min$, 0mm (focal length: 232mm) for laser power, beam travel speed, and focal position. Where, heat input was $0.793{\times}10^{3}J/cm^2$, and width of hardened layer was 27.58mm.

Fabrication of Superconducting Joints between 61 Filaments of BSCCO 2223 Tapes (61심 BSCCO 2223 고온초전도 선재의 접합부 제조)

  • 김철진;박성창;유재무
    • Journal of the Korean Ceramic Society
    • /
    • v.35 no.2
    • /
    • pp.137-144
    • /
    • 1998
  • High-temperature superconducting joints between 61 filaments of Bi-2223 tapes were fabricated by chem-ical corrosion and repeated thermomechanical process. The silver sheath of the superconducting tape was chemically removed using chemical etchant(NH4OH:H2O2=1:1) from one side of each tape without altering the form of lap joint. The joined region was formed by uniaxial pressing and a series of thermomechanical process and then subjected to properties measurement and microstructural analysis. The critical current(Ic) variation and I-V characteristics along the joint were mesured with several configuration of proble points. Ic value of the transition region of the joint inthe multifilament tape which limit the total current carring capacity of the superconducting tape was higher than that of monofilament tape. But the transition ex-ponent n-value of the multi-filament tape was lower than that of monofilament wire due to the interaction of the individual superconducting core of the multi-filament. The critical current through the joint area was improved by respeated press and reaction annealing treatment.

  • PDF

A Study on the Integrity Evaluation Method of Subclad Crack Under Pressurized Thermal Shock (가압열충격 사고시 클래드 하부균열 안전성 평가 방법에 관한 연구)

  • Kim, Yeong-Jin;Kim, Jin-Su;Gu, Bon-Geol;Choe, Jae-Bung;Park, Yun-Won
    • Transactions of the Korean Society of Mechanical Engineers A
    • /
    • v.25 no.7
    • /
    • pp.1139-1146
    • /
    • 2001
  • The reactor pressure vessel(RPV) is usually cladded with stainless steel to prevent corrosion and radiation embrittlement, and a number of subclad cracks have been found during an in-service-inspection. These subclad cracks should be assured for a safe operation under normal conditions and faulted conditions such as pressurized thermal shock(PTS). Currently available integrity assessment procedure for an RPV, ASME Code Sec. XI, are built on the basis of linear fracture mechanics (LEFM). In PTS condition, however, thermal stress and mechanical stress give rise to high tensile stress at the cladding and elastic-plastic behavior is expected in this area. Therfore, ASME Code Sec. XI is overly conservative in assessing the structural integrity under PTS condition. In this paper, the fracture parameter (stress intensity factor, K, and RT(sub)NDT) from elastic analysis using ASME Sec. XI and finite element method were validated against 3-D elastic-plastic finite element analyses. The difference between elastic and elastic-plastic analysis became significant with increasing crack depth. Therfore, it is recommended to perform elastic-plastic analysis for the accurate assessment of subclad cracks under TPS which causes plastic deformation at the cladding.

Study on the tensile restraint crack characteristics in underwater welds of marine steel plates (선용 강판 수중용접부의 인장 구속 균열 특성에 관한 연구)

  • 오세규;강문호;김민남
    • Journal of Advanced Marine Engineering and Technology
    • /
    • v.11 no.3
    • /
    • pp.45-52
    • /
    • 1987
  • Generally the factors affected largely by the cold cracking sensitivity of the weld are the quantity of the diffusible hydrogen, the brittleness and hardness of the bond area and the tensile restraint stress. These factors have relation each other, and if we can reduce one of these factors, it becomes instrumental to the root cracks prevention of weld. This study deals with the gravity type-underwater-welding of KR Grade A-3 marine steel plate using E4303 welding electrode in order to compare wet-underwater-welding with in-air- welding, resulting in obtaining the tensile restraint characteristics, the hardness distribution, the quantity of diffusible hydrogen and the macro- and micro-crack properties in both underwater and in-air welds. The main results obtained are as follows: 1) The quantity of diffusible hydrogen measured for 48 hours is about 18cc/100g-weld-metal for the in-air-weld of one pass and about 48cc/100g-weld-metal for the underwater-weld of one pass which is about 3 times penetration of diffusible hydrogen compairing with the case of the in-air-weld. However, it was experimentally confirmed that, by the multi-pass welding of 2 to 5 passes, the diffusible hydrogen in the underwater weld metal can be reduced as much as 27 to 49%. 2) The hardness of the weld metal indicates the highest value in the heat affected zones of underwater weld for more rapid cooling rate, resulting in the higher sensitivity of cold cracking. So, it is desirable to soften the higher hardness in the HAZ by tempering effect such as the multi-pass welding in the underwater welding. 3) At the bond vicinity of the underwater weld HAZ, micro cracks were found as resulted by both more rapid cooling rate and more diffusible hydrogen and also by the stress corrosion cracking under the tensile restraint stress in the underwater. But this could be prevented by the tempering effect of the following weld bead such as the multi-pass welding.

  • PDF

The Integrity Verification of Tube-end Sleeve by ECT (와전류탐상검사에 의한 튜브엔드 슬리브 건전성 검증)

  • Kim, Su Jin;Kwon, Kyung Joo;Suk, Dong Hwa;Park, Ki Tae
    • Transactions of the Korean Society of Pressure Vessels and Piping
    • /
    • v.11 no.1
    • /
    • pp.20-24
    • /
    • 2015
  • Steam generator(S/G) tubes in pressurized water reactor (PWR's) are subject to several types of degradation. This degradation includes denting, pitting, intergranular attack(IGA), intergranular stress corrosion cracking(IGSCC), fatigue, fretting and wear. Degradation can be derived from either the primary side(inside) or the secondary side(outside) of the tube. Recent issue for tube degradation in domestic steam generator is the tube end cracking on seal weld region. The seal weld region at the tube end and tube itself is regarded as a pressure boundary between the primary side and the secondary side. One of the Westinghouse Model-F S/G has experienced tube end cracking and its number of plugging approximately becomes to the operating limit up to 5% due to tube end cracking which was reported as SAI/MAI(single/multiple axial indication) or SCI/MCI(Single/multiple circumferential indication) from the results of eddy current testing. Eddy current mock-up test was carried out to determine the origin of cracking whether it is from weld zone area or parent tube. This result was helpful to analyze crack location on ECT data. Correct action on this problem was the installation of tube-end sleeve. Last year, after removing 340 installed plugs from tubes, selected 269 tubes took tube-end sleeve installation. Tube-end sleeve brought pressure boundary from parent tube to installed sleeve tube. Tube-end sleeve has the benefit of reducing outage period and increasing more revenue than replacing S/G. This paper is provided to assist interest parties in effectively understanding this issue.

A Study on Development of Automatic Path Tracking Algorithm for LNG Aluminium Plate and Selection of Process Parameters by Using Artificial Intelligence (LNG 알루미늄 판재 가공용 자동 궤적 추적 알고리즘 개발 및 인공지능을 이용한 공정조건 선정에 관한 연구)

  • 문형순;권봉재;정문영;신상룡
    • Journal of the Korean Society for Precision Engineering
    • /
    • v.15 no.8
    • /
    • pp.17-25
    • /
    • 1998
  • Aluminum alloys have low density, relatively high strength and yield strength, good plasticity, good machinability, and high corrosion and acid resistance. Therefore, they are suitable for large containers for the food, chemical and other industries. Large containers are often bodies of revolution consisting of shell courses, stiffening rings, heads and other elements joined by annular welds. Larger containers have longer welds and require greater leak-tightness and higher weld mechanical properties. The LNG tank consists of aluminum plates with various sizes, so its construction should by divided by several sections. Moreover, each section has its own sub-section consisted of several aluminum plates. To guarantee the quality of huge LNG tank, therefore, the precise control of plate dimension should by urgently needed in conjunction with the appropriate selection of process parameters such as cutting speed, depth of cut, rotational speed and so on. In this paper, a manufacturing system was developed to implement automatic circular tracking in height direction and automatic circular interpolation in depth of cut direction. Also, the neural network based on the backpropagation algorithm was used to predict the cutting quality and motor load related with the life time of the developed system. It was revealed that the manufacturing system and the neural network could be effectively applied to the bevelling process and to predict the quality of machined area and the motor load.

  • PDF

Development of Automated Nondestructive Inspection System for BMI Nozzles in Nuclear Vessel (원자로 BMI 노즐 검사를 위한 자동화 비파괴검사 시스템 개발)

  • Park, Joon Soo;Lee, Won Kun;Han, Won Jin;Lee, Sun Ho;Seong, Un Hak
    • Journal of the Korean Society for Nondestructive Testing
    • /
    • v.33 no.1
    • /
    • pp.26-33
    • /
    • 2013
  • BMI nozzles in bottom head of the nuclear vessel are one of major components in nuclear power plants. The BMI nozzles have high possibility to generate PWSCC(primary water stress corrosion crack) according to recent foreign case although operation temperature is lower then the upper head of the nuclear vessel. Thus, nondestructive inspection of the BMI nozzles is required. But, inspection of BMI nozzles is not easy since the BMI nozzles placed in high radiated area and inside the nozzles filled with boric acid. Thus, in this study, a TOFD transducer for inspection of BMI and automated scanner system with water were developed. Also, validation of performance of the developed transducer and system are performed using specimens with artificial defects.