• Title/Summary/Keyword: corrosion area

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A Study on Properties of SiC material Fabricated by Liquid Phase Sintering (액상소결법에 의해 제조된 탄화규소 재료의 특성에 대한 연구)

  • Sang-Pill Lee;Jae-Hwan Kwak;Jin-Kyung Lee
    • Journal of the Korean Society of Industry Convergence
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    • v.26 no.6_2
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    • pp.1019-1024
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    • 2023
  • Ceramic materials have excellent material properties such as stability at high temperatures, chemical stability, corrosion resistance, and wear resistance, so they are applicable even in extreme environments of high temperature and pressure. In particular, silicon carbide can be applied in the field of structural ceramics due to its characteristics of high strength, hardness, corrosion resistance, and heat resistance even at high temperatures. In this study, considering the application of silicon carbide materials to next-generation turbines, silicon carbide materials were manufactured using a liquid phase sintering method. When manufacturing liquid phase sintered silicon carbide, sintering additives were added to lower the sintering temperature and densify the material. In Al2O3-SiO2, it was confirmed that the secondary product of the sintering additive was observed as a slightly dark area and was evenly distributed overall, and the fracture surface of Al2O3-SiO2 was in the form of transgranular fracture in which cracks progressed along the crystal plane, and the flexural strength for Al2O3-SiO2 was about 445.6 MPa.

Susceptibility of Stress Corrosion Crack Initiation of Type 304 SS in Simulated Primary Water Environment of PWR (원전 1차 계통수 모사환경에서 Type 304 스테인리스강의 응력부식균열개시 민감도)

  • Sung-Hwan Cho;Sung-Woo Kim;Jong-Yeon Lee
    • Transactions of the Korean Society of Pressure Vessels and Piping
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    • v.20 no.1
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    • pp.25-31
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    • 2024
  • The core shroud of rector vessel internals (RVI) of OPR1000 and ARP1400 is made of Type 304 stainless steel (SS) by bending and welding process that may induce high deformation and residual stress in manufacturing. This work aims to evaluate the susceptibility of stress corrosion crack (SCC) initiation of bent parts of RVI in high temperature primary water environment. For SCC initiation test, tensile specimens were fabricated from the 90 degree bent plate of Type 304 SS (DT specimen), that is an archived part of a Korean APR1400. After the SCC initiation test, the specimen surface was thoroughly examined by optical and scanning electron microscopy, and compared to the specimen fabricated from the as-received plate of Type 304 SS (AR specimen). The surface observation revealed that SCC initiated on the AR specimen surface in typical intergranular (IG) mode, while SCC on the DT specimen occurred in transgrannular mode as well as IG mode. It was also found that the size and number of SCC on the DT specimen were larger than that on the AR specimen. This was attributable to a strain-hardening during the bending process. To compare the susceptibility of SCC initiation, total crack density (TCD) was calculated from the total crack length divided by the measured area of AR and DT specimens. TCD of DT specimen was 4.6 times higher than AR specimen in average, indicating that higher possibility of degradation of bent parts of RVI for a long-term operation.

Strengthening of Rapidly Solidified and Extruded Mg Alloy Powders (압출공정을 이용한 급속응고 Mg 합금분말의 고강도화)

  • Kim, Taek-Soo
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2008.10a
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    • pp.35-37
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    • 2008
  • The light Mg alloys bearing the remarkably high strength, corrosion resistance and elevated temperature stability stand on the center of interest. The accomplishment so far is, however, only by alloy modification without any consideration on the rapid solidification effect. This work is to report not only the effect of rapid solidification of $MgZn_{4.3}Y_{0.7}$ alloy powders, but the extrusion behavior on the materials properties. The average grain size of the atomized powders was about $3-4{\mu}m$. The extrusion was carried out with the area reduction ratio of 10:1 to 15:1. As the ratio increased, homogeneous microstructure was obtained, and the mechanical properties such as tensile strength and elongation were simultaneously increased.

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Effects of Particle Size and Temperature on the Ammonium Ion Exchange by Natural Zeolite (천연제올라이트의 암모늄이온교환에 미치는 입자 크기 및 온도영향에 관한 연구)

  • Song, Chang Soo;Kim, Hee Jun;Chung, Tai Hak
    • Journal of Korean Society of Water and Wastewater
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    • v.12 no.3
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    • pp.75-80
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    • 1998
  • Ammonium ion is notorious for the adverse effects upon many of the important uses of water such as toxcity to fish, corrosion of metals and concrete, and concern over man's consumption. A clinoptilolite, which is a naturally occurring zeolite selective for ammonium ion exchange, has been used. Batch isotherm experiments were conducted for measuring ammonium ion exchange capacity. The ion exchange capacity was well described either by the Langmuir equation or by the Freundlich equation. As the particle size of the clinoptilolite decreased, exchange capacity was increased. The smaller particle size enhaced the exchange of ammonium ion due to the greater surface area and decreased diffusion to the exchange sites within the zeolite. Ammonium ion exchange capacity tended to decrease when the temperature increased from $20^{\circ}C$ to $35^{\circ}C$, and the temperature correction factor was found to be 0.98 in the Langmuir equation.

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The Comparison of the Heat Distribution and Characteristic between the Laser & SMAW Welds of 9Cr-lMo Steel. (9Cr-lMo강에 대한 Laser 및 SMAW 용접부의 열분포 특성 비교)

  • O Jong In;Bang Han Seo;Kim Yeong Pyo;Park Hyeong Geun
    • Proceedings of the KWS Conference
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    • v.43
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    • pp.118-120
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    • 2004
  • Recently 9Cr-1Mo azzoy is used in the Nuclear power plant due to its special properties. This material has the merit of high-strength resistance and corrosion resistance. Therefore the demand for this alloy is dramatically increased in the Nuclear power, petro-chemical complex etc. Re various research has been conducted to improve the material properties of this alloy. In spite of this circumstance, detail research in the area of welding process of this alloy is yet to be expanded In this study the numerical non-linear heat transfer analysis of laser welding which may possibly replace the conventional SMAW fabrication of 9Cr-1Mo steel has been carried out.

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Finite Element Analysis for Wall Thinned Steam Generator Tubes (감육된 증기발생기 전열관의 유한요소 해석)

  • Seong, K.Y.;Ahn, S.H.;Nam, K.W.
    • Journal of Power System Engineering
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    • v.10 no.3
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    • pp.38-44
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    • 2006
  • Failure assessment of steam generator tube are very important for the integrity of energy plants. In pipes of energy plants, sometimes, the local wall thinning may result from severe erosion-corrosion damage. Recently, the effects of local wall thinning on fracture strength and fracture behavior of piping system have been well studied. In this paper, the elasto-plastic analysis is performed by FE code ANSIS on steam generator tube with wall thinning. We evaluated the failure mode, fracture strength and fracture behavior from FE analysis. It was possible to predict the crack initiation point by estimating true fracture ductility under multi-axial stress conditions at the center of the thinned area.

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High Durability of Stack for Automobile (차량용 스택 고출력 내구성능)

  • Kim, Young-Min;Lee, Jong-Hyun;Yoon, Jong-Jin;Cho, Jang-Ho
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.06a
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    • pp.557-560
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    • 2007
  • The durability of 80 kW class stack module was tested in hydrogen recirculation and non-recirculation systems with the condition of 300Amps (constant current mode) and hydrogen pulse purging (10 seconds close/0.8 seconds open). A localized membrane failure in the interfacial area between membrane and sub-gasket, carbon corrosion in cathode electrode, and Pt dissolution/extraction have been found through the post mortem analysis such as CV, Impedance, SEM, and so on. The main reason of these mechanisms will be discussed in this study.

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The Evaluation of Crack Propagation in Functionally Graded Materials with Coatings (코팅 경사기능 재료의 균열전파에 관한 평가)

  • Kwon, Oh-Heon
    • Journal of the Korean Society of Safety
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    • v.23 no.4
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    • pp.25-29
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    • 2008
  • Recently, new functionally graded material(FGM) that has a spatial variation in composition and properties is developed because of its good quality. This material yields the demands for resistance to corrosion and high temperature in turbine blade, wear resistance as in gears and high strength machine parts. Especially coating treatment in FGM surface brings forth a mechanical weak at the interface due to discontinuous stress resulting from a steep material change. It often, leads cracks or spallation in a coating area around an interface. The behavior of propagation cracks in FGMs was here investigated. The interface stresses were reduced because of graded material properties. Also graded material parameter with exponential equation was founded to influence the stress intensity factor. And the resistance curve with FGM coating was slightly increased.

Structural Deterioration of Educational Buildings in Reinforced Concrete Structure : Area Seoul (철근콘크리트조 교육시설물의 열화성상에 관한 조사 연구 - 서울지역 초.중등교를 중심으로 -)

  • Kwon, Ki-Hyuk
    • Journal of the Korean Institute of Educational Facilities
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    • v.4 no.3
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    • pp.5-14
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    • 1997
  • The purpose of this study is to present basic data in order to improve the efficiency and the objectivity of diagnosing educational structures built with the reinforced concrete. For achieving the purpose, this paper, firstly, researches damage aspects of 22 public educational of facilities in Seoul, and summarizes the results of that research. Through the analysis and the evaluation of damage aspects, this paper shows the conclusions as follows; (1) Main damage to reduce structural capacities of building is the differential settlement. (2) Though the steel corrosion is occurred by several factors, the main cause is the faulty construction. (3) To prevent the damage development, a proper repair strategy is very important.

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Synthesis and Characterization of Crosslinked Hole Transporting Polymers for Organic Light Emitting Diodes

  • Jang, Do-Young;Lim, Youn-Hee;Kim, Joo-Hyun;Kim, Jang-Joo;Shin, Jung-Hyu;Yoon, Do-Y.
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.235-235
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    • 2006
  • Triphenylamine derivatives play important roles as hole transporting materials in organic light emitting devices. However, low molecular weight triphenylamine derivatives show low glass transition temperature and aggregation behavior, and the vapor deposition step of low molecular weight materials is incompatible with large area display fabrication. Conventional polymer PEDOT-PSS HTL has serious drawbacks such as the ITO anode corrosion, poor surface energy match with aromatic EMLs. To solve these problems, we introduced crosslinkable units to triphenylamine-based polymers to make insoluble HTL by thermal curing following spin-coating. Electrochemical and optical properties of the new hole transporting materials were investigated. In addition, the device characteristics obtained with new hole transporting polymers were investigated in details.

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